通过测定纳米锑掺杂氧化锡(Antimony doped Tin Oxide,ATO)水分散液的纳米粒子粒径分布、沉降性能、黏度、以及Zeta电位等,探讨了黏度、纳米ATO粒子的粒径分布、粒子Zeta电位、分散剂的类型对悬液分散稳定性的影响.结果表明,悬液的黏度...通过测定纳米锑掺杂氧化锡(Antimony doped Tin Oxide,ATO)水分散液的纳米粒子粒径分布、沉降性能、黏度、以及Zeta电位等,探讨了黏度、纳米ATO粒子的粒径分布、粒子Zeta电位、分散剂的类型对悬液分散稳定性的影响.结果表明,悬液的黏度、粒子粒径分布以及Zeta电位间具有良好的相关性;同时发现以聚乙烯吡咯烷酮/十六烷基三甲基溴化铵(Poly(vinylpyrrolidine)/cetyltrimethyl-ammonium bromine,PVP/CTAB)作为复合分散剂时,在pH<3.0时也能得到黏度低、粒径小、分散稳定的纳米ATO悬液.展开更多
Antimony-doped tin oxide(ATO) nanoparticles with an average size of ～ 6 nm were prepared by co-precipitation and subsequent heat treatment. Graphitic carbon nitride(g-CN)/ATO hybrid nanocomposite was designed by the ...Antimony-doped tin oxide(ATO) nanoparticles with an average size of ～ 6 nm were prepared by co-precipitation and subsequent heat treatment. Graphitic carbon nitride(g-CN)/ATO hybrid nanocomposite was designed by the combination of thermally synthesized g-CN and ATO nanoparticles by ultrasonication. The materials were characterized using N2 adsorption/desorption(BET), X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), transmission electron microscopy(TEM) and Fourier transform infrared spectroscopy(FTIR). A mixture of five volatile organic compounds(VOCs, chloroform, benzene, toluene, xylene and styrene) was used to compare the adsorption capacity of the samples. The adsorption capacity of ATO nanoparticles was improved by the addition of g-CN. Experimental data showed that, among the five VOCs,chloroform was the least adsorbed, regardless of the samples. The g-CN/ATO showed nearly three times greater adsorption capacity for the VOC mixture than pure ATO. The unchanged efficiency of VOC adsorption during cyclic use demonstrated the completely reversible adsorption and desorption behavior of the nanocomposite at room conditions. This economically and environmentally friendly material can be a practical solution for outdoor and indoor VOC removal.展开更多
文摘通过测定纳米锑掺杂氧化锡(Antimony doped Tin Oxide,ATO)水分散液的纳米粒子粒径分布、沉降性能、黏度、以及Zeta电位等,探讨了黏度、纳米ATO粒子的粒径分布、粒子Zeta电位、分散剂的类型对悬液分散稳定性的影响.结果表明,悬液的黏度、粒子粒径分布以及Zeta电位间具有良好的相关性;同时发现以聚乙烯吡咯烷酮/十六烷基三甲基溴化铵(Poly(vinylpyrrolidine)/cetyltrimethyl-ammonium bromine,PVP/CTAB)作为复合分散剂时,在pH<3.0时也能得到黏度低、粒径小、分散稳定的纳米ATO悬液.
基金supported by a grant from the Korean Ministry of Education, Science, and Technology (MEST)Republic of Korea through the National Research Foundation (NRF) (No. 2017-R1C1B2011968)
文摘Antimony-doped tin oxide(ATO) nanoparticles with an average size of ～ 6 nm were prepared by co-precipitation and subsequent heat treatment. Graphitic carbon nitride(g-CN)/ATO hybrid nanocomposite was designed by the combination of thermally synthesized g-CN and ATO nanoparticles by ultrasonication. The materials were characterized using N2 adsorption/desorption(BET), X-ray diffraction(XRD), scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS), transmission electron microscopy(TEM) and Fourier transform infrared spectroscopy(FTIR). A mixture of five volatile organic compounds(VOCs, chloroform, benzene, toluene, xylene and styrene) was used to compare the adsorption capacity of the samples. The adsorption capacity of ATO nanoparticles was improved by the addition of g-CN. Experimental data showed that, among the five VOCs,chloroform was the least adsorbed, regardless of the samples. The g-CN/ATO showed nearly three times greater adsorption capacity for the VOC mixture than pure ATO. The unchanged efficiency of VOC adsorption during cyclic use demonstrated the completely reversible adsorption and desorption behavior of the nanocomposite at room conditions. This economically and environmentally friendly material can be a practical solution for outdoor and indoor VOC removal.
