Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to imp...Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to improve the anti-wear performance of PEEK for aqueous boundary lubrication,PEEK/MoS_(2)composites were prepared by ball-milling and spark plasma sintering processes.A competitive MoS_(2)mechanism between the low shear strength property and the role of promoting wear debris generation influences the anti-wear performance of PEEK/MoS_(2)composites.Experiments demonstrated that the coefficients of friction(COF)and wear rate of PEEK composite with 0.25 wt%MoS_(2)were significantly reduced 68%and 94%,respectively.Furthermore,this was the first time that a PEEK composite could achieve a COF of less than 0.05 in aqueous boundary lubrication.Its anti-wear performance was verified to be better than that of PEEK/carbon fiber(CF)and Thordon composites.The PEEK/MoS_(2)composite may be a potential material for underwater equipment because of its outstanding anti-wear performance in aqueous boundary lubrication.展开更多
Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and t...Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and tribological process,the anti-friction and anti-wear mechanisms are unclear,and the subsequent tribological performance prediction and design of MMNCs are not easily possible:A critical up-to-date review is needed for MMNCs in tribology.This review systematically summarized the fabrication,manufacturing,and processing techniques for high-quality MMNC bulk and surface coating materials in tribology.Then,important factors determining the tribological performance(mainly anti-friction evaluation by the coefficient of friction(CoF)and anti-wear assessment with wear rate)in MMNCs have been investigated thoroughly,and the correlations have been analyzed to reveal their potential coupling/synergetic roles of tuning tribological behavior of MMNCs.Most importantly,this review combined the classical metal/alloy friction and wear theories and adapted them to give a(semi-)quantitative description of the detailed mechanisms of improved anti-friction and anti-wear performance in MMNCs.To guarantee the universal applications of these mechanisms,their links with the analyzed influencing factors(e.g.,loading forces)and characteristic features like tribo-film have been clarified.This approach forms a solid basis for understanding,predicting,and engineering MMNCs’tribological behavior,instead of pure phenomenology and experimental observation.Later,the pathway to achieve a broader application for MMNCs in tribo-related fields like smart materials,biomedical devices,energy storage,and electronics has been concisely discussed,with the focus on the potential development of modeling,experimental,and theoretical techniques in MMNCs’tribological processes.In general,this review tries to elucidate the complex tribo-performances of MMNCs in a fundamentally universal yet straightforward way,and the discussion and summary in t展开更多
基金This work was financially supported by the National Natural Science Foundation of China(Grant No.51425502).
文摘Polyether-etherketone(PEEK)is a corrosion-resistant material that has been widely used in aqueous lubrication.However,its anti-wear performance must be improved for its application in the industry.In this study,to improve the anti-wear performance of PEEK for aqueous boundary lubrication,PEEK/MoS_(2)composites were prepared by ball-milling and spark plasma sintering processes.A competitive MoS_(2)mechanism between the low shear strength property and the role of promoting wear debris generation influences the anti-wear performance of PEEK/MoS_(2)composites.Experiments demonstrated that the coefficients of friction(COF)and wear rate of PEEK composite with 0.25 wt%MoS_(2)were significantly reduced 68%and 94%,respectively.Furthermore,this was the first time that a PEEK composite could achieve a COF of less than 0.05 in aqueous boundary lubrication.Its anti-wear performance was verified to be better than that of PEEK/carbon fiber(CF)and Thordon composites.The PEEK/MoS_(2)composite may be a potential material for underwater equipment because of its outstanding anti-wear performance in aqueous boundary lubrication.
基金This work is financially supported by the National Natural Science Foundation of China(Nos.51875343 and 12072191)the Key Fund Project of Equipment Pre-Research(No.61409230607)the State Key Laboratory of Mechanical System and Vibration Project(No.MSVZD202108).
文摘Metal matrix nanocomposites(MMNCs)become irreplaceable in tribology industries,due to their supreme mechanical properties and satisfactory tribological behavior.However,due to the dual complexity of MMNC systems and tribological process,the anti-friction and anti-wear mechanisms are unclear,and the subsequent tribological performance prediction and design of MMNCs are not easily possible:A critical up-to-date review is needed for MMNCs in tribology.This review systematically summarized the fabrication,manufacturing,and processing techniques for high-quality MMNC bulk and surface coating materials in tribology.Then,important factors determining the tribological performance(mainly anti-friction evaluation by the coefficient of friction(CoF)and anti-wear assessment with wear rate)in MMNCs have been investigated thoroughly,and the correlations have been analyzed to reveal their potential coupling/synergetic roles of tuning tribological behavior of MMNCs.Most importantly,this review combined the classical metal/alloy friction and wear theories and adapted them to give a(semi-)quantitative description of the detailed mechanisms of improved anti-friction and anti-wear performance in MMNCs.To guarantee the universal applications of these mechanisms,their links with the analyzed influencing factors(e.g.,loading forces)and characteristic features like tribo-film have been clarified.This approach forms a solid basis for understanding,predicting,and engineering MMNCs’tribological behavior,instead of pure phenomenology and experimental observation.Later,the pathway to achieve a broader application for MMNCs in tribo-related fields like smart materials,biomedical devices,energy storage,and electronics has been concisely discussed,with the focus on the potential development of modeling,experimental,and theoretical techniques in MMNCs’tribological processes.In general,this review tries to elucidate the complex tribo-performances of MMNCs in a fundamentally universal yet straightforward way,and the discussion and summary in t