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辣椒素同系物合成、辣度及海洋生物防污性能研究 被引量:13
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作者 彭必先 王俊莲 +7 位作者 彭争宏 周圣泽 王凤奇 纪永亮 叶章基 周祥凤 林童 张孝彬 《中国科学:化学》 CAS CSCD 北大核心 2011年第10期1646-1654,共9页
合成了十种辣椒碱同系物,用感官评定的方法对其辣度进行了测定,并将它们的结构与辣度进行了对比,探讨了影响辣椒碱同系物辣度的结构因子.选取其中辣度较大的四种辣椒碱同系物作为海洋生物防污涂料的驱赶剂,考察了它们的海洋生物防污性能... 合成了十种辣椒碱同系物,用感官评定的方法对其辣度进行了测定,并将它们的结构与辣度进行了对比,探讨了影响辣椒碱同系物辣度的结构因子.选取其中辣度较大的四种辣椒碱同系物作为海洋生物防污涂料的驱赶剂,考察了它们的海洋生物防污性能.结果表明,辣椒碱和二氢辣椒碱都具有良好的防污性能,二者不相上下.降二氢辣椒碱和壬酸香草胺的防污性能与辣椒碱和二氢辣椒碱有明显区别.仅以辣椒碱或二氢辣椒碱为驱赶剂,且其含量仅为0.1%的情况下,漆膜也表现出较好的防污性能,这为研发新型的、环保的、不含氧化亚铜的防污涂料提供了新思路. 展开更多
关键词 辣椒素同系物 辣度 辣构关系 防污性能
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Studies on the synthesis,pungency and anti-biofouling performance of capsaicin analogues 被引量:4
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作者 PENG BiXian WANG JunLian +7 位作者 PENG ZhengHong ZHOU ShengZe WANG FengQi JI YongLiang YE ZhangJi ZHOU XiangFeng LIN Tong ZHANG XiaoBin 《Science China Chemistry》 SCIE EI CAS 2012年第3期435-442,共8页
Ten capsaicin analogues were synthesized and their pungency degrees were determined through Scoville Organoleptic Test. The relationship between the structure and pungency degree of these capsaicin analogues was discu... Ten capsaicin analogues were synthesized and their pungency degrees were determined through Scoville Organoleptic Test. The relationship between the structure and pungency degree of these capsaicin analogues was discussed. Then four of these capsaicin analogues with higher pungency degree were picked out and added to anti-biofouling paints as repellents to study their anti-biofouling performance by shallow sea buoyant raft hung-plate experimentation. The results showed that capsaicin and dihydrocapsaicin exhibited equally good anti-biofouling performance while nordihydrocapsaicin and N-vanillylnonanamide had poor anti-biofouling performance. Experimental results also showed that the paints with only 0.1% capsaicin or dihydrocapsaicin as repellent without any other biocides had also exhibited good anti-biofouling performance, which provided a new idea for developing novel, more environment-friendly and Cu20-free antifouling paints. 展开更多
关键词 capsaicin analogues PUNGENCY relationship between structure and pungency degree anti-biofouling performance
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