This paper described a new method for preparation of ethyl lactate from ammonium lactate directly by means of reactive distillation in the presence of anhydrous aluminium chloride as catalyst and benzene as dehydratin...This paper described a new method for preparation of ethyl lactate from ammonium lactate directly by means of reactive distillation in the presence of anhydrous aluminium chloride as catalyst and benzene as dehydrating agent.The result showed this method had the advantages of high pure,easy operation,and no pollution.The yield of ethyl lactate reached up to 28.14%,which was 50% higher 50% than that in ordinary reactive device.展开更多
L-(+)-Lactic acid production from corncob hydrolysate as a cheap carbohydrate source by fed-batch fermentation of Rhizopus oryzaeHZS6 was studied. After 96 h of fermentation in a 5 L fermentor, the final concentration...L-(+)-Lactic acid production from corncob hydrolysate as a cheap carbohydrate source by fed-batch fermentation of Rhizopus oryzaeHZS6 was studied. After 96 h of fermentation in a 5 L fermentor, the final concentration of ammonium L-(+)-lactate, average productivity(based on initial xylose concentration) and maximum dry cell weight were 132.4 g/L, 1.38 g/(L·h), and 8.9 g/L respectively. The optical purity of L-(+)-lactate was 98.8%.展开更多
Phosphate mineral fertilisers are manufactured from non-renewable resources. Soil fertilisation with composts is considered a good source of reuse nutrients such as phosphorus (P). The aim of this work was to evaluate...Phosphate mineral fertilisers are manufactured from non-renewable resources. Soil fertilisation with composts is considered a good source of reuse nutrients such as phosphorus (P). The aim of this work was to evaluate the effect of compost fertilisation on soil P sorption and consequently on P availability. It was done an incubation experiment followed by a sorption experiment in a low-P acid soil fertilised with compost (CP) or single superphosphate (SSP). The P application rates were: 0, 6.5, 13, 26 and 52 (kg•P•ha−1). In CP treatments, the rates 26 and 52 kg•P•ha−1 were achieved by adding SSP to CP since it was not allowed to incorporate into soil more than 170 kg•N•ha−1?from organic amendments. Although SSP has a higher proportion of easily available P than CP (86% vs 50%), the results showed that after 140 days of soil incubation, the available P was higher in CP treatments compared with SSP at the same rate of P application. The sorption experiment showed that after incubation of the fertilised soils, the P sorption maximum had lower values in treatments with CP in combination with SSP compared with only SSP fertilisation and the bonding energy had a deeper decrease in the same treatments. Also, the Standard Phosphate Requirement decreased in the CP in combination with SSP treatments. The reduction of soil P sorption capacity after compost addition to soil highlights the need of reducing P fertilisation rates to achieve similar levels of available P compared with only SSP fertilisation.展开更多
文摘This paper described a new method for preparation of ethyl lactate from ammonium lactate directly by means of reactive distillation in the presence of anhydrous aluminium chloride as catalyst and benzene as dehydrating agent.The result showed this method had the advantages of high pure,easy operation,and no pollution.The yield of ethyl lactate reached up to 28.14%,which was 50% higher 50% than that in ordinary reactive device.
基金Partially suppored by a grant for the U K DTI- China MOST Collaborative Research
文摘L-(+)-Lactic acid production from corncob hydrolysate as a cheap carbohydrate source by fed-batch fermentation of Rhizopus oryzaeHZS6 was studied. After 96 h of fermentation in a 5 L fermentor, the final concentration of ammonium L-(+)-lactate, average productivity(based on initial xylose concentration) and maximum dry cell weight were 132.4 g/L, 1.38 g/(L·h), and 8.9 g/L respectively. The optical purity of L-(+)-lactate was 98.8%.
文摘Phosphate mineral fertilisers are manufactured from non-renewable resources. Soil fertilisation with composts is considered a good source of reuse nutrients such as phosphorus (P). The aim of this work was to evaluate the effect of compost fertilisation on soil P sorption and consequently on P availability. It was done an incubation experiment followed by a sorption experiment in a low-P acid soil fertilised with compost (CP) or single superphosphate (SSP). The P application rates were: 0, 6.5, 13, 26 and 52 (kg•P•ha−1). In CP treatments, the rates 26 and 52 kg•P•ha−1 were achieved by adding SSP to CP since it was not allowed to incorporate into soil more than 170 kg•N•ha−1?from organic amendments. Although SSP has a higher proportion of easily available P than CP (86% vs 50%), the results showed that after 140 days of soil incubation, the available P was higher in CP treatments compared with SSP at the same rate of P application. The sorption experiment showed that after incubation of the fertilised soils, the P sorption maximum had lower values in treatments with CP in combination with SSP compared with only SSP fertilisation and the bonding energy had a deeper decrease in the same treatments. Also, the Standard Phosphate Requirement decreased in the CP in combination with SSP treatments. The reduction of soil P sorption capacity after compost addition to soil highlights the need of reducing P fertilisation rates to achieve similar levels of available P compared with only SSP fertilisation.
