In this study,Mg O was partially used as an alkali source in the peroxide bleaching process of bleached chemi-thermomechanical pulp(BCTMP).The effects of substitution percentage of Mg O for Na OH on the bulk,optical,a...In this study,Mg O was partially used as an alkali source in the peroxide bleaching process of bleached chemi-thermomechanical pulp(BCTMP).The effects of substitution percentage of Mg O for Na OH on the bulk,optical,and physical properties of bleached pulp,and the main effluent characteristics were analyzed.In addition,the influencing mechanism of Mgbased alkali on the strength properties of the BCTMP was further investigated.Strength properties of the BCTMPs were investigated as a function of charge characteristics,fiber morphology,surface lignin content,relative bonding area,and hydrogen bonds of the BCTMP.The results showed that cationic demand(CD) and chemical oxygen demand(COD_(Cr)) of the bleaching effluent decreased as the substitution percentage of Mg O for Na OH increased; meanwhile,the bulk and optical properties of the BCTMP increased.Nevertheless,the strength properties(tensile,tear,and burst indices) of the bleached pulp decreased as the substitution percentage of Mg O for Na OH increased.The decrease in the fiber charge density and increase in the surface lignin content affected the fiber swelling,resulting in a decline in pulp interfibers bonding strength and further loss of the tensile and burst indices.展开更多
基金financially supported by the Natural Science Foundation of China (31070528)Project of China “Twelfth Five-Year” National Science and Technology Supporting Plan (2011BAC11B04)the Foundation of State Key Laboratory of Pulp and Paper Engineering
文摘In this study,Mg O was partially used as an alkali source in the peroxide bleaching process of bleached chemi-thermomechanical pulp(BCTMP).The effects of substitution percentage of Mg O for Na OH on the bulk,optical,and physical properties of bleached pulp,and the main effluent characteristics were analyzed.In addition,the influencing mechanism of Mgbased alkali on the strength properties of the BCTMP was further investigated.Strength properties of the BCTMPs were investigated as a function of charge characteristics,fiber morphology,surface lignin content,relative bonding area,and hydrogen bonds of the BCTMP.The results showed that cationic demand(CD) and chemical oxygen demand(COD_(Cr)) of the bleaching effluent decreased as the substitution percentage of Mg O for Na OH increased; meanwhile,the bulk and optical properties of the BCTMP increased.Nevertheless,the strength properties(tensile,tear,and burst indices) of the bleached pulp decreased as the substitution percentage of Mg O for Na OH increased.The decrease in the fiber charge density and increase in the surface lignin content affected the fiber swelling,resulting in a decline in pulp interfibers bonding strength and further loss of the tensile and burst indices.
