沥青与集料间的黏附作用是形成沥青混合料结构的重要影响因素,且直接关系到沥青混合料的结构强度、水稳性等主要性能,也对沥青混凝土路面的使用寿命有较大影响。因此,对沥青与集料间黏附作用方面的研究十分必要。典型的黏附作用评价方...沥青与集料间的黏附作用是形成沥青混合料结构的重要影响因素,且直接关系到沥青混合料的结构强度、水稳性等主要性能,也对沥青混凝土路面的使用寿命有较大影响。因此,对沥青与集料间黏附作用方面的研究十分必要。典型的黏附作用评价方法可分为如下三类:(1)在石质基材(或其他材料)表面涂抹沥青层,对沥青层与基材界面施加垂直拉力或剪切应力,以沥青从基材表面剥离所需力的大小(或剪切强度)间接表征两者之间的黏附作用;(2)表面涂覆沥青的集料放入水中,水的作用使得沥青从集料表面剥落,以沥青从集料表面剥落的程度评价沥青与集料之间的黏附作用;(3)基于表面能理论,测试沥青与集料的表面能参数,从能量角度评价沥青-集料的黏附作用。我国《公路工程沥青及沥青混合料试验规程》(JTG E20-2011)中规定使用水煮法和水浸法来评价沥青-集料黏附性能,试验方法简单快捷,但测试结果受人为判断影响,缺乏定量评价指标。随着科学技术的进步,研究者逐渐将各种新技术运用到沥青-集料黏附性能检测中,如超声波模拟动水压力对传统水煮法进行改进,并应用高质量的图形处理系统使得沥青剥落程度指标得到更精准的量化;基于原子力显微镜技术(Atomic force microscope,AFM),在不同测试模式下进行微纳观尺度沥青-集料黏附作用评价,国外研究人员还依托神经网络模型,实现黏附性能的量化。随着原子力显微镜技术(AFM)的不断成熟,将该技术应用于对沥青-集料黏附作用的评价中已成为近年来的研究热点。同时,在研究人员的努力下,使用AFM新发展起来的测试模式测量沥青、集料的表面能及黏附功已取得突破性进展。随着对黏附作用研究的不断深入,一些研究新思路也开始出现,研究人员为了探讨在不同荷载作用下沥青与集料黏附性能的变化,针对“三明治”柱�展开更多
Materials with appropriate adhesive properties are suitable for the fabrication of bionic adhesive pads. In this study, a novel polydimethylsiloxane （PDMS） material enhanced with two types of crosslinkers, carbon na...Materials with appropriate adhesive properties are suitable for the fabrication of bionic adhesive pads. In this study, a novel polydimethylsiloxane （PDMS） material enhanced with two types of crosslinkers, carbon nanotubes and graphene sheets, was fabricated. The Contact Angle （CA） and cross-sectional morphology of the new material were investigated and observed using a CA meter and Scanning Electron Microscopy （SEM）, respectively. CA measurements indicate that the surface energy of the novel material is twice that of the common PDMS material. SEM observations show that carbon nanotubes and graphene sheets are well dispersed in the polymer, a feature that improves the mechanical properties of the new material. The adhesive performance of this novel composite was tested on an in-house fabricated friction machine. Results show that at a preload of only 50 mN, the adhesion of the novel PDMS material is up to -3.7 times that of common PDMS. The maximum macroscale shear strength and normal adhesion reach 4 N·cm^-2 and 1 N·cm^-2, respectively. The adhesive capability of the material is maintained even after hundreds of times of repeated use. This novel material exhibits excellent adhesion, sufficiently high elastic modulus and high repeatability at low preloads.展开更多
文摘沥青与集料间的黏附作用是形成沥青混合料结构的重要影响因素,且直接关系到沥青混合料的结构强度、水稳性等主要性能,也对沥青混凝土路面的使用寿命有较大影响。因此,对沥青与集料间黏附作用方面的研究十分必要。典型的黏附作用评价方法可分为如下三类:(1)在石质基材(或其他材料)表面涂抹沥青层,对沥青层与基材界面施加垂直拉力或剪切应力,以沥青从基材表面剥离所需力的大小(或剪切强度)间接表征两者之间的黏附作用;(2)表面涂覆沥青的集料放入水中,水的作用使得沥青从集料表面剥落,以沥青从集料表面剥落的程度评价沥青与集料之间的黏附作用;(3)基于表面能理论,测试沥青与集料的表面能参数,从能量角度评价沥青-集料的黏附作用。我国《公路工程沥青及沥青混合料试验规程》(JTG E20-2011)中规定使用水煮法和水浸法来评价沥青-集料黏附性能,试验方法简单快捷,但测试结果受人为判断影响,缺乏定量评价指标。随着科学技术的进步,研究者逐渐将各种新技术运用到沥青-集料黏附性能检测中,如超声波模拟动水压力对传统水煮法进行改进,并应用高质量的图形处理系统使得沥青剥落程度指标得到更精准的量化;基于原子力显微镜技术(Atomic force microscope,AFM),在不同测试模式下进行微纳观尺度沥青-集料黏附作用评价,国外研究人员还依托神经网络模型,实现黏附性能的量化。随着原子力显微镜技术(AFM)的不断成熟,将该技术应用于对沥青-集料黏附作用的评价中已成为近年来的研究热点。同时,在研究人员的努力下,使用AFM新发展起来的测试模式测量沥青、集料的表面能及黏附功已取得突破性进展。随着对黏附作用研究的不断深入,一些研究新思路也开始出现,研究人员为了探讨在不同荷载作用下沥青与集料黏附性能的变化,针对“三明治”柱�
基金Acknowledgments The authors would like to thank Mr Y. J. Xue for his help with the SEM measurements, Miss H. H. Zhao for her help in fabricating the graphene sheets, and Mr. X. D Sun for his help in measuring the elastic moduli of tile NPWC and NPWOC materials. This work was supported in part by the National Natural Science Foundation of China （Grant Nos. 51175251, 51275237 and 61161120323）, by the Natural Science Foundation of Jiangsu Province （Grant No. BK2011734）, by the Funding for Outstanding Doctoral Dissertation in NUAA （Grant No. BCXJ11-06）, by the Funding of Jiangsu Innovation Program for Graduate Education （Grant No. CXLX11_0178）, and by the Fundamental Research Funds for Central Universities.
文摘Materials with appropriate adhesive properties are suitable for the fabrication of bionic adhesive pads. In this study, a novel polydimethylsiloxane （PDMS） material enhanced with two types of crosslinkers, carbon nanotubes and graphene sheets, was fabricated. The Contact Angle （CA） and cross-sectional morphology of the new material were investigated and observed using a CA meter and Scanning Electron Microscopy （SEM）, respectively. CA measurements indicate that the surface energy of the novel material is twice that of the common PDMS material. SEM observations show that carbon nanotubes and graphene sheets are well dispersed in the polymer, a feature that improves the mechanical properties of the new material. The adhesive performance of this novel composite was tested on an in-house fabricated friction machine. Results show that at a preload of only 50 mN, the adhesion of the novel PDMS material is up to -3.7 times that of common PDMS. The maximum macroscale shear strength and normal adhesion reach 4 N·cm^-2 and 1 N·cm^-2, respectively. The adhesive capability of the material is maintained even after hundreds of times of repeated use. This novel material exhibits excellent adhesion, sufficiently high elastic modulus and high repeatability at low preloads.
