Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporatio...Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporation was structurally characterized by the X-ray crystallography. The crystal is monoclinic, space group C2, with a = 1.8534(4) nm, b=0.5234(1) nm, c = 0.7212(1) nm, β=103.722°, V = 0.67965(3) nm3, Z = 4, F(000) = 144.0, Dclac = 1.763 g·cm-3, μ (MoKa) = 1.06 mm-1, T = 293(2) K.R = 0.0379, wR = 0.0835 for 660 observed reflections (I】2σ(I)). The structural formula of the crystal compound is (CH2CH(NH2)NO2)ClFe (Mr = 180.38u). Products of heavy ion beam irradiation were purified and it was directly confirmed that the implanted Fe+ ions had been deposited in the novel molecules. The same doses of Fe+ ion beams of the same energy were implanted into films of L(+)-cysteine hydrochloride monohydrate. FTIR spectroscopy of the implanted samples proved that some of the original molecules were展开更多
Capillarin was isolated from Artemisia Ordosica Kraschen and characterized by IR, 1H-NMR, 13C-NMR, 1H-1HCOSY, HMQC, HMBC and EIMS, and its crystal structure was determined by single-crystal X-ray diffraction analysis ...Capillarin was isolated from Artemisia Ordosica Kraschen and characterized by IR, 1H-NMR, 13C-NMR, 1H-1HCOSY, HMQC, HMBC and EIMS, and its crystal structure was determined by single-crystal X-ray diffraction analysis with the following data: triclinic, space group P1, Z = 2, a = 7.226(6), b = 7.297(6), c = 11.042(8) ?, α = 74.695(12), β = 78.479(12), γ = 62.063(10)°, V = 494.2(6) ?3, Mr = 198.21, Dc = 1.332 g/cm3, F(000) = 208, μ = 0.089 mm-1, S = 1.023, (?/σ)max = 0.000, the final R = 0.0408 and wR = 0.1110. The largest peak and deepest hole on the final difference Fourier map are 0.219 and –0.161 e/?3, respectively. The bond lengths and bond angles of the molecule are also given.展开更多
Two new triterpenoid saponins named notoginsenoside-Ng3(1) and notoginsenoside-Ng4(2) along with three known saponins (3-5), were isolated from a water extract of the leaves of Panax notoginseng. Their structures were...Two new triterpenoid saponins named notoginsenoside-Ng3(1) and notoginsenoside-Ng4(2) along with three known saponins (3-5), were isolated from a water extract of the leaves of Panax notoginseng. Their structures were elucidated by HRESIMS, NMR, X-ray techniques and acid hydrolysis. Moreover,compound 2 was characterized with the conjugated double bonds side-chain, which was rarely found in this plant. The absolute configuration of notoginsenoside Fa (3) with five sugars was confirmed by the single-crystal X-ray diffraction for the first time. Acetylcholinesterase inhibitory activity experiments were also conducted, all the isolated saponins showed weak inhibitory activities in the final concentration of 0.16 mmol/L.展开更多
Pentaerythritol（PET） crystal has been grown rapidly from the solution with sulfuric acid as the additive. The growth rate of PET crystal in prismatic shape exceeds 1.5 mm/day and crystallization size is 55×55&#...Pentaerythritol（PET） crystal has been grown rapidly from the solution with sulfuric acid as the additive. The growth rate of PET crystal in prismatic shape exceeds 1.5 mm/day and crystallization size is 55×55×50 mm^3. X-ray diffraction analysis was used to confirm the structure integrity. The diffraction efficiency of rapid-grown crystal was characterized as effective as that of normal growth.展开更多
The response of materials after microscale laser shock peening (μLSP) was experimentally characterized and compared with the theoretical prediction from the finite element method (FEM) analysis in microlength level...The response of materials after microscale laser shock peening (μLSP) was experimentally characterized and compared with the theoretical prediction from the finite element method (FEM) analysis in microlength level. X-ray micro-diffraction technique was applied to the post-peened single crystal aluminum of (001) and (110) orientations, and X-ray profile was analyzed by sub-profiling and Fourier analysis method. Spatially resolved residual stress and strain deviation was quantified and explained in terms of the hetero- geneous dislocation cell structure. In-plane crystal lattice rotation induced by μLSP was measured by elec- tron backscatter diffraction (EBSD) and compared with the FEM simulation. Average mosaic size was evaluated from X-ray profile Fourier analysis and compared with the result from EBSD. Surface strength in- crease and dislocation cell structure formation were studied. The systematical characterization will lay the ground work for better understanding the effect of μLSP in microlength level and developing more realistic simulations.展开更多
基金This work was supported by the National Natural Science Foundation of China (Grant No.19975060)the Scientific Foundation of "95" Fundamental Research from the Chinese Academy of Sciences (Grant No. KJ952-S1-424).
文摘Fe+ ion beams with the energy of 110 keV were implanted into films of L(+)-cysteine (HSCH2CH(NH2)COOH). One of the single crystals grown in hydrochloric acid solution with the implanted samples through slow evaporation was structurally characterized by the X-ray crystallography. The crystal is monoclinic, space group C2, with a = 1.8534(4) nm, b=0.5234(1) nm, c = 0.7212(1) nm, β=103.722°, V = 0.67965(3) nm3, Z = 4, F(000) = 144.0, Dclac = 1.763 g·cm-3, μ (MoKa) = 1.06 mm-1, T = 293(2) K.R = 0.0379, wR = 0.0835 for 660 observed reflections (I】2σ(I)). The structural formula of the crystal compound is (CH2CH(NH2)NO2)ClFe (Mr = 180.38u). Products of heavy ion beam irradiation were purified and it was directly confirmed that the implanted Fe+ ions had been deposited in the novel molecules. The same doses of Fe+ ion beams of the same energy were implanted into films of L(+)-cysteine hydrochloride monohydrate. FTIR spectroscopy of the implanted samples proved that some of the original molecules were
基金The project was supported by Henan Innovation Project for University Prominent Research Talents (2004)
文摘Capillarin was isolated from Artemisia Ordosica Kraschen and characterized by IR, 1H-NMR, 13C-NMR, 1H-1HCOSY, HMQC, HMBC and EIMS, and its crystal structure was determined by single-crystal X-ray diffraction analysis with the following data: triclinic, space group P1, Z = 2, a = 7.226(6), b = 7.297(6), c = 11.042(8) ?, α = 74.695(12), β = 78.479(12), γ = 62.063(10)°, V = 494.2(6) ?3, Mr = 198.21, Dc = 1.332 g/cm3, F(000) = 208, μ = 0.089 mm-1, S = 1.023, (?/σ)max = 0.000, the final R = 0.0408 and wR = 0.1110. The largest peak and deepest hole on the final difference Fourier map are 0.219 and –0.161 e/?3, respectively. The bond lengths and bond angles of the molecule are also given.
基金financially supported by the National Natural Science Foundation of China(Nos. 81630094and 81730093)CAMS Innovation Fund for Medical Sciences (CIFMS)(No. 2016-I2M-2-003)
文摘Two new triterpenoid saponins named notoginsenoside-Ng3(1) and notoginsenoside-Ng4(2) along with three known saponins (3-5), were isolated from a water extract of the leaves of Panax notoginseng. Their structures were elucidated by HRESIMS, NMR, X-ray techniques and acid hydrolysis. Moreover,compound 2 was characterized with the conjugated double bonds side-chain, which was rarely found in this plant. The absolute configuration of notoginsenoside Fa (3) with five sugars was confirmed by the single-crystal X-ray diffraction for the first time. Acetylcholinesterase inhibitory activity experiments were also conducted, all the isolated saponins showed weak inhibitory activities in the final concentration of 0.16 mmol/L.
基金supported by Key Laboratory of Optoelectronic Materials Chemistry and Physics,Chinese Academy of Sciences (2009KL007)
文摘Pentaerythritol（PET） crystal has been grown rapidly from the solution with sulfuric acid as the additive. The growth rate of PET crystal in prismatic shape exceeds 1.5 mm/day and crystallization size is 55×55×50 mm^3. X-ray diffraction analysis was used to confirm the structure integrity. The diffraction efficiency of rapid-grown crystal was characterized as effective as that of normal growth.
基金Supported by the National Science Foundation of USA (No. DMI-02-00334) and the National Science Foundation of USA under the Faculty Early Career Development (CAREER) Program (No. CMS-0134226)
文摘The response of materials after microscale laser shock peening (μLSP) was experimentally characterized and compared with the theoretical prediction from the finite element method (FEM) analysis in microlength level. X-ray micro-diffraction technique was applied to the post-peened single crystal aluminum of (001) and (110) orientations, and X-ray profile was analyzed by sub-profiling and Fourier analysis method. Spatially resolved residual stress and strain deviation was quantified and explained in terms of the hetero- geneous dislocation cell structure. In-plane crystal lattice rotation induced by μLSP was measured by elec- tron backscatter diffraction (EBSD) and compared with the FEM simulation. Average mosaic size was evaluated from X-ray profile Fourier analysis and compared with the result from EBSD. Surface strength in- crease and dislocation cell structure formation were studied. The systematical characterization will lay the ground work for better understanding the effect of μLSP in microlength level and developing more realistic simulations.
