Microplastics are considered as the carrier to heavy metals in the environment.But the sorption ability of microplastics influenced by photo-aging is remaining unclear.In the present study,the sorption of two kinds of...Microplastics are considered as the carrier to heavy metals in the environment.But the sorption ability of microplastics influenced by photo-aging is remaining unclear.In the present study,the sorption of two kinds of metal ions(Cu^2+ and Zn^2+)in the aqueous solution by both the virgin and aged microplastics was investigated.Polyethylene terephthalate(PET)debris,one of the typical kinds of microplastics was chosen in this study.Photo-aging of microplastics in environment was simulated using UV radiation in the laboratory.Date analysis indicated that the aged microplastics had higher adsorption capacity of heavy metals than original ones.This could be related to the increased surface area and oxygen containing function appeared in the surface of aged microplastics after UV radiation.When prolonging the time of radiation,the enhanced adsorption capacities of microplastics appeared for Cu^2+ and Zn^2+.These results showed a great interaction between the aging degree of plastics and sorption capacity to heavy metals.Meanwhile,external conditions including temperature and pH value were also showed great influence to the adsorption behavior.展开更多
高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触...高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触角法测量和评价硅橡胶材料的憎水性,同时进行了硬度以及扫描电子显微镜(SEM)测试,另外采用image-pro plus 6.0软件对SEM图片进行测试分析。试验结果表明:短时氙灯辐照对高温硫化硅橡胶表面憎水性影响不大,材料硬度有变大趋势,材料表面凹凸不平,粗糙度变大,并有填充物外露的趋势。随着辐照时间增加,欲析出颗粒数目逐渐增多,颗粒大小逐渐变大,总面积增加。展开更多
复合绝缘子具有优异的表面憎水性及防污闪性能,在输电线路尤其是架空线路中得到了广泛应用。大跨度、长距离输电线路中的部分复合绝缘子运行在高原、山地等高海拔地区。该地区大气稀薄,导致紫外线辐射强度极高。高强度紫外线辐射将破坏...复合绝缘子具有优异的表面憎水性及防污闪性能,在输电线路尤其是架空线路中得到了广泛应用。大跨度、长距离输电线路中的部分复合绝缘子运行在高原、山地等高海拔地区。该地区大气稀薄,导致紫外线辐射强度极高。高强度紫外线辐射将破坏复合绝缘子优异的表面憎水性,造成高海拔地区输电线路污闪事故率大幅上升。通过对复合绝缘子样品分别进行持续4000h的UVA、UVB、UVC紫外线辐射试验,结合扫描电镜（scanning electron microscope,SEM）检测、能谱仪（energy dispersive spectrometer,EDS）检测等检测手段,获得了不同波长紫外线对复合绝缘子表面憎水性的影响规律,认为UVC紫外线为造成复合绝缘子表面憎水性丧失的主要因素,并最终提出了具体的影响机制。展开更多
基金supported by the National Nature Science Foundation of China(Nos.5180081612 and 51608002)the University Natural Science Research Key Project of Anhui Province(No.KJ2017A061)
文摘Microplastics are considered as the carrier to heavy metals in the environment.But the sorption ability of microplastics influenced by photo-aging is remaining unclear.In the present study,the sorption of two kinds of metal ions(Cu^2+ and Zn^2+)in the aqueous solution by both the virgin and aged microplastics was investigated.Polyethylene terephthalate(PET)debris,one of the typical kinds of microplastics was chosen in this study.Photo-aging of microplastics in environment was simulated using UV radiation in the laboratory.Date analysis indicated that the aged microplastics had higher adsorption capacity of heavy metals than original ones.This could be related to the increased surface area and oxygen containing function appeared in the surface of aged microplastics after UV radiation.When prolonging the time of radiation,the enhanced adsorption capacities of microplastics appeared for Cu^2+ and Zn^2+.These results showed a great interaction between the aging degree of plastics and sorption capacity to heavy metals.Meanwhile,external conditions including temperature and pH value were also showed great influence to the adsorption behavior.
文摘高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触角法测量和评价硅橡胶材料的憎水性,同时进行了硬度以及扫描电子显微镜(SEM)测试,另外采用image-pro plus 6.0软件对SEM图片进行测试分析。试验结果表明:短时氙灯辐照对高温硫化硅橡胶表面憎水性影响不大,材料硬度有变大趋势,材料表面凹凸不平,粗糙度变大,并有填充物外露的趋势。随着辐照时间增加,欲析出颗粒数目逐渐增多,颗粒大小逐渐变大,总面积增加。
文摘复合绝缘子具有优异的表面憎水性及防污闪性能,在输电线路尤其是架空线路中得到了广泛应用。大跨度、长距离输电线路中的部分复合绝缘子运行在高原、山地等高海拔地区。该地区大气稀薄,导致紫外线辐射强度极高。高强度紫外线辐射将破坏复合绝缘子优异的表面憎水性,造成高海拔地区输电线路污闪事故率大幅上升。通过对复合绝缘子样品分别进行持续4000h的UVA、UVB、UVC紫外线辐射试验,结合扫描电镜（scanning electron microscope,SEM）检测、能谱仪（energy dispersive spectrometer,EDS）检测等检测手段,获得了不同波长紫外线对复合绝缘子表面憎水性的影响规律,认为UVC紫外线为造成复合绝缘子表面憎水性丧失的主要因素,并最终提出了具体的影响机制。
