The complex of [La 2(P MBA) 6(PHEN) 2]2H 2O (P MBA: p methylbenzoate and PHEN: 1,10 phenanthroline) was prepared and characterized by elemental analysis and IR spectroscopy. The thermal behavior of [La 2(P M...The complex of [La 2(P MBA) 6(PHEN) 2]2H 2O (P MBA: p methylbenzoate and PHEN: 1,10 phenanthroline) was prepared and characterized by elemental analysis and IR spectroscopy. The thermal behavior of [La 2(P MBA) 6(PHEN) 2]2H 2O in dynamic nitrogen atmosphere was investigated by TG DTG techniques. The results show that the thermal decomposition process of the [La 2(P MBA) 6(PHEN) 2]2H 2O occurs in five steps. The empirical kinetic model for the first step thermal decomposition obtained by Malek method is SB(m,n). The activation energy E and the pre exponential factor lnA for this step reaction are 76.4 kJ·mol -1 and 24.92, respectively.展开更多
The kaolinite-polyacrylamide inte rcalation compound was prepared fir st by the displacement reaction of th e kaolinite-formamide intercalatio n precursor with 30%acrylamide ethanol solution,and then the polymeriz ati...The kaolinite-polyacrylamide inte rcalation compound was prepared fir st by the displacement reaction of th e kaolinite-formamide intercalatio n precursor with 30%acrylamide ethanol solution,and then the polymeriz ation under 140℃for 15h with the catalysis of dibenzoyl peroxide.The XRD analy ses showed that the basal spacings of kaolinite-acrylamide intercalation compound and kaolinite-polyacry lamide compound were 1.135nm and 1.144nm respectively.The kaolinite-polya crylamide compound was able to resis t to 30-min washing with water,but th e kaolinite-acrylamide compound was unstable during washing.FT-IR proved that the hydrogen bonds were forme d between kaolinite Si-O group and polyacrylamide NH group and between kaolinite inner surface hydroxyl and polyacrylamide C =O group,and that p arts of NH group keyed into the kaolin ite ditrigonal hole.TG and DTG analysis proved that kaolinite-polyacrylamide was stable under 350℃.A net weight loss of 16.63%between 370℃～500℃is due to the removal of interca lated polyacrylamide from the interlamellar space of kaolinite.These results clearly indicate that acrylamide has been intercalated into the layers of kaolinite and was polymerized in-situ.Based on the TG data,the formula of the kaolinite-polyacrylami de intercalation compound,Al 2 Si 2 O 5 (OH) 4 CH 2 CHCONH 2 0.736 ,can be calculated.展开更多
文摘The complex of [La 2(P MBA) 6(PHEN) 2]2H 2O (P MBA: p methylbenzoate and PHEN: 1,10 phenanthroline) was prepared and characterized by elemental analysis and IR spectroscopy. The thermal behavior of [La 2(P MBA) 6(PHEN) 2]2H 2O in dynamic nitrogen atmosphere was investigated by TG DTG techniques. The results show that the thermal decomposition process of the [La 2(P MBA) 6(PHEN) 2]2H 2O occurs in five steps. The empirical kinetic model for the first step thermal decomposition obtained by Malek method is SB(m,n). The activation energy E and the pre exponential factor lnA for this step reaction are 76.4 kJ·mol -1 and 24.92, respectively.
文摘The kaolinite-polyacrylamide inte rcalation compound was prepared fir st by the displacement reaction of th e kaolinite-formamide intercalatio n precursor with 30%acrylamide ethanol solution,and then the polymeriz ation under 140℃for 15h with the catalysis of dibenzoyl peroxide.The XRD analy ses showed that the basal spacings of kaolinite-acrylamide intercalation compound and kaolinite-polyacry lamide compound were 1.135nm and 1.144nm respectively.The kaolinite-polya crylamide compound was able to resis t to 30-min washing with water,but th e kaolinite-acrylamide compound was unstable during washing.FT-IR proved that the hydrogen bonds were forme d between kaolinite Si-O group and polyacrylamide NH group and between kaolinite inner surface hydroxyl and polyacrylamide C =O group,and that p arts of NH group keyed into the kaolin ite ditrigonal hole.TG and DTG analysis proved that kaolinite-polyacrylamide was stable under 350℃.A net weight loss of 16.63%between 370℃～500℃is due to the removal of interca lated polyacrylamide from the interlamellar space of kaolinite.These results clearly indicate that acrylamide has been intercalated into the layers of kaolinite and was polymerized in-situ.Based on the TG data,the formula of the kaolinite-polyacrylami de intercalation compound,Al 2 Si 2 O 5 (OH) 4 CH 2 CHCONH 2 0.736 ,can be calculated.
