An environmental friendly carbonaceous material- carboresP (one of the Carbores series materials) was investigated for the production of MgO-C refractories in laboratory scale and field tests. The MgO-C specimens we...An environmental friendly carbonaceous material- carboresP (one of the Carbores series materials) was investigated for the production of MgO-C refractories in laboratory scale and field tests. The MgO-C specimens were produced with different CarboresP contents. The bulk density (180℃ × 48h), CCS, apparent porosity (1000℃ ×3h ) and hot modulus of rupture (1400℃ ×0. 5h ) were tested and contrasted. The appropriate amount of carboresP was 1.0%. The amount of metallic additions can be partially substituted (reduced to 1.5% ). The microstructure of resin-carboresP binder is anisotropic structure with high oxidation resistance and good thermal-shock stability. The Stress/strain curve indicates that the characteristic length, (LCH) of MgO-C brick with resin/CarboresP bonding has been improved, which means the MgO-C bricks have good mechanical flexibility and stresses absorbability. Field tests were done in slag line of a 40t LF-VD refining steel ladle using Resin/CarboresP bonded " MT-14A MgO-C bricks. The result shows that the MgO-C bricks by "soft bonding" have good physical properties and excellent workability during production of the bricks . In contrast with traditional MgO-C brick used for secondary refining furnaces, the spalling tendency of the bricks could be reduced significantly. The average lining life of the resin/ CarboresP bricks has increased by 18. 4% comparing with the pure resin-bonded types.展开更多
Photo/electrocatalytic water splitting has been considered as one of the most promising approaches for the clean hydrogen production. Among various photo/electrocatalysts,2D nanomaterials exhibit great potential becau...Photo/electrocatalytic water splitting has been considered as one of the most promising approaches for the clean hydrogen production. Among various photo/electrocatalysts,2D nanomaterials exhibit great potential because of their conspicuous properties. Meanwhile,synchrotron-based soft X-ray absorption spectroscopy(XAS) as a powerful and element-specific technique has been widely used to explore the electronic structure of 2D photo/electrocatalysts to comprehensively understand their working mechanism for the development of high-performance catalysts. In this work, the recent developments of soft XAS techniques applied in 2D photo/electrocatalysts have been reviewed, mainly focusing on identifying the surface active sites,elucidating the location of heteroatoms, and unraveling the interfacial interaction in the composite.The challenges and outlook in this research field have also been emphasized. The present review provides an in-depth understanding on how soft XAS techniques unravel the correlations between structure and performance in 2D photo/electrocatalysts, which could guide the rational design of highly efficient catalysts for photo/electrocatalytic water splitting.展开更多
This study presents a new, simple method for reducing the back-lobe radiation of a microstrip antenna (MSA) by a partially removed ground plane of the antenna. The effect of the partial ground plane removal in differe...This study presents a new, simple method for reducing the back-lobe radiation of a microstrip antenna (MSA) by a partially removed ground plane of the antenna. The effect of the partial ground plane removal in different configurations on the radiation characteristics of a MSA are investigated numerically. The partial ground plane removal reduces the backlobe radiation of the MSA by suppressing the surface wave diffraction from the edges of the antenna ground plane. For further improving the front-to-back (F/B) ratio of the MSA, a new soft-surface configuration consisting of an array of stand-up split ring resonators (SRRs) are placed on a bare dielectric substrate near the two ground plane edges. Compared to the F/B ratio of a conventional MSA with a full ground plane of the same size, an improved F/B ratio of 9.7 dB has been achieved experimentally for our proposed MSA.展开更多
文摘An environmental friendly carbonaceous material- carboresP (one of the Carbores series materials) was investigated for the production of MgO-C refractories in laboratory scale and field tests. The MgO-C specimens were produced with different CarboresP contents. The bulk density (180℃ × 48h), CCS, apparent porosity (1000℃ ×3h ) and hot modulus of rupture (1400℃ ×0. 5h ) were tested and contrasted. The appropriate amount of carboresP was 1.0%. The amount of metallic additions can be partially substituted (reduced to 1.5% ). The microstructure of resin-carboresP binder is anisotropic structure with high oxidation resistance and good thermal-shock stability. The Stress/strain curve indicates that the characteristic length, (LCH) of MgO-C brick with resin/CarboresP bonding has been improved, which means the MgO-C bricks have good mechanical flexibility and stresses absorbability. Field tests were done in slag line of a 40t LF-VD refining steel ladle using Resin/CarboresP bonded " MT-14A MgO-C bricks. The result shows that the MgO-C bricks by "soft bonding" have good physical properties and excellent workability during production of the bricks . In contrast with traditional MgO-C brick used for secondary refining furnaces, the spalling tendency of the bricks could be reduced significantly. The average lining life of the resin/ CarboresP bricks has increased by 18. 4% comparing with the pure resin-bonded types.
基金financially supported by National Key R&D Program of China (2020YFA0406103)China Postdoctoral Science Foundation (2020T130754)National Natural Science Foundation of China (51902139, U1932211)。
文摘Photo/electrocatalytic water splitting has been considered as one of the most promising approaches for the clean hydrogen production. Among various photo/electrocatalysts,2D nanomaterials exhibit great potential because of their conspicuous properties. Meanwhile,synchrotron-based soft X-ray absorption spectroscopy(XAS) as a powerful and element-specific technique has been widely used to explore the electronic structure of 2D photo/electrocatalysts to comprehensively understand their working mechanism for the development of high-performance catalysts. In this work, the recent developments of soft XAS techniques applied in 2D photo/electrocatalysts have been reviewed, mainly focusing on identifying the surface active sites,elucidating the location of heteroatoms, and unraveling the interfacial interaction in the composite.The challenges and outlook in this research field have also been emphasized. The present review provides an in-depth understanding on how soft XAS techniques unravel the correlations between structure and performance in 2D photo/electrocatalysts, which could guide the rational design of highly efficient catalysts for photo/electrocatalytic water splitting.
文摘This study presents a new, simple method for reducing the back-lobe radiation of a microstrip antenna (MSA) by a partially removed ground plane of the antenna. The effect of the partial ground plane removal in different configurations on the radiation characteristics of a MSA are investigated numerically. The partial ground plane removal reduces the backlobe radiation of the MSA by suppressing the surface wave diffraction from the edges of the antenna ground plane. For further improving the front-to-back (F/B) ratio of the MSA, a new soft-surface configuration consisting of an array of stand-up split ring resonators (SRRs) are placed on a bare dielectric substrate near the two ground plane edges. Compared to the F/B ratio of a conventional MSA with a full ground plane of the same size, an improved F/B ratio of 9.7 dB has been achieved experimentally for our proposed MSA.