为了控制热稳定盐(HSS)对天然气净化装置造成的危害,建立了一种同时检测醇胺脱硫溶液中的乙酸根离子、甲酸根离子、氯离子、硫酸根离子、草酸根离子、硫代硫酸根离子和硫氰酸根离子的离子色谱方法。该方法利用膜过滤、反相固相萃取和稀...为了控制热稳定盐(HSS)对天然气净化装置造成的危害,建立了一种同时检测醇胺脱硫溶液中的乙酸根离子、甲酸根离子、氯离子、硫酸根离子、草酸根离子、硫代硫酸根离子和硫氰酸根离子的离子色谱方法。该方法利用膜过滤、反相固相萃取和稀释3个步骤对工业样品进行前处理,采用氢氧化钾梯度淋洗和电导检测的方式,实现了7种离子的分离与检测。方法的线性范围为0.01～0.5 m m o l/L,检出限(以信噪比(S/N)为3计)小于0.1 m g/L,回收率为80.0%～100.3%。在5个不同添加浓度下分别测定了上述7个离子,色谱峰面积的重复性良好(相对标准偏差(RSD,n=10)为0.94%～3.99%。通过3个实验室比对试验,表明该方法再现性良好,色谱峰面积的RSD小于5%。应用该方法成功地检测了8家天然气净化厂、3家石油炼厂和1家煤制油工厂的脱硫溶液样品中的HSS,并连续监测某天然气净化装置15 d。该方法具有良好的可靠性和实用性。展开更多
In recent years,as a promising option to improve the overall efficiency of energy utilization and absorptive capacity of renewable energies,the integrated energy system(IES)has raised great interest in academies and i...In recent years,as a promising option to improve the overall efficiency of energy utilization and absorptive capacity of renewable energies,the integrated energy system(IES)has raised great interest in academies and industries.Multi-energy flow(MF)calculation,which differs from the traditional power flow calculation,plays a basic role in analyzing IES.MF calculation based on Newton-Raphson method has been proposed in literature,but its calculation efficiency is not high.In this paper,a fast decoupled MF(FDMF)calculation method for IES is proposed.Its main idea is to replace the original Jacobian matrix of MF calculation based on Newton-Raphson method with a diagonal and constant Jacobian matrix by the transformation.The simulations demonstrate that the proposed FDMF method can increase the calculation efficiency by at least 4 times with high calculation accuracy.展开更多
文摘为了控制热稳定盐(HSS)对天然气净化装置造成的危害,建立了一种同时检测醇胺脱硫溶液中的乙酸根离子、甲酸根离子、氯离子、硫酸根离子、草酸根离子、硫代硫酸根离子和硫氰酸根离子的离子色谱方法。该方法利用膜过滤、反相固相萃取和稀释3个步骤对工业样品进行前处理,采用氢氧化钾梯度淋洗和电导检测的方式,实现了7种离子的分离与检测。方法的线性范围为0.01～0.5 m m o l/L,检出限(以信噪比(S/N)为3计)小于0.1 m g/L,回收率为80.0%～100.3%。在5个不同添加浓度下分别测定了上述7个离子,色谱峰面积的重复性良好(相对标准偏差(RSD,n=10)为0.94%～3.99%。通过3个实验室比对试验,表明该方法再现性良好,色谱峰面积的RSD小于5%。应用该方法成功地检测了8家天然气净化厂、3家石油炼厂和1家煤制油工厂的脱硫溶液样品中的HSS,并连续监测某天然气净化装置15 d。该方法具有良好的可靠性和实用性。
基金supported in part by the National Natural Science Foundation of China(No.51777067)the State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources(No.LAPS2019-08)the scientific and technological project of State Grid Corporation of China“State Estimation of Integrated Energy Systems Considering Different Time Scales”(No.52110418002R)
文摘In recent years,as a promising option to improve the overall efficiency of energy utilization and absorptive capacity of renewable energies,the integrated energy system(IES)has raised great interest in academies and industries.Multi-energy flow(MF)calculation,which differs from the traditional power flow calculation,plays a basic role in analyzing IES.MF calculation based on Newton-Raphson method has been proposed in literature,but its calculation efficiency is not high.In this paper,a fast decoupled MF(FDMF)calculation method for IES is proposed.Its main idea is to replace the original Jacobian matrix of MF calculation based on Newton-Raphson method with a diagonal and constant Jacobian matrix by the transformation.The simulations demonstrate that the proposed FDMF method can increase the calculation efficiency by at least 4 times with high calculation accuracy.
