A super-fine compound powder, Ag/SnO_2+La_2O_3+ Bi_2O_3, has been obtainedusing the chemical coprecipitation method. And a new contact material, Ag/SnO_2+La_2O_3+Bi_2O_3, wasproduced by the powder metallurgy method. I...A super-fine compound powder, Ag/SnO_2+La_2O_3+ Bi_2O_3, has been obtainedusing the chemical coprecipitation method. And a new contact material, Ag/SnO_2+La_2O_3+Bi_2O_3, wasproduced by the powder metallurgy method. Its properties are as follows: the density is 9.75-9.93g/cm^3, the resistivity is 2.31-2.55 μΩ ·cm, the hardness is 880-985 MPa. Its mi-crostructureshows that the fine oxides have a uniform distribution in the silver matrix. The results ofmake-break capacity and temperature rise testing show that the new material has better ability ofanti-arc erosion and lower temperature rise than that of commonly used Ag/CdO.展开更多
The ultrafine silver powders were prepared by liquid reduction method using Arabic gum as dispersant.The effects of different dispersants,pH values,and temperature on the morphology and particle size of silver powders...The ultrafine silver powders were prepared by liquid reduction method using Arabic gum as dispersant.The effects of different dispersants,pH values,and temperature on the morphology and particle size of silver powders were investigated.It is found that Arabic gum can better adsorb on silver particles via chemical adsorption,and it shows the best dispersive effect among all the selected dispersants.The particle size of silver powders can be finely tuned from 0.34 to 4.09μm by adjusting pH values,while the morphology of silver powders can be tuned by changing the temperature.The silver powders with high tap density higher than 4.0 g/cm3 were successfully prepared in a wide temperature range of 21.8-70°C.Especially,the tap density is higher than 5.0 g/cm3 when the temperature is optimized to be 50°C.The facile process and high silver concentration of this method make it a promising way to prepare high quality silver powders for electronic paste.展开更多
Silver-tin oxide composite powders and silver powders were synthesized by hydrothermal method using NH3 to complex Ag+, SO 32?to reduce Ag (NH3)+2 and Na2SnO3 as the source of tin. The powders were characterized by XR...Silver-tin oxide composite powders and silver powders were synthesized by hydrothermal method using NH3 to complex Ag+, SO 32?to reduce Ag (NH3)+2 and Na2SnO3 as the source of tin. The powders were characterized by XRD, SEM and EDX. The results show that there are macroscopic and microscopic differences between two kinds of powders. Spherical silver powders are 3 μm in diameter, and silver-tin oxide composite powders are mainly flake of about 0.3 μm in thickness. Silver crystal in silver-tin oxide composite powders is preferentially oriented in the (111) crystallographic direction and its oriented index is 2.581. Crystal lattice parameter of silver crystal of silver tin-oxide composite powders is 0.409 34 nm, larger than 0.408 68 nm of silver powders. The XPS analysis shows that silver in silver-tin oxide composite powders is metallic silver and tin oxide in silver tin-oxide composite powders has the red shift for Sn4+(3d5/2) and O2-(1s).展开更多
基金This project is financially supported by the Science Foundation of Hebei Province (No.502048)
文摘A super-fine compound powder, Ag/SnO_2+La_2O_3+ Bi_2O_3, has been obtainedusing the chemical coprecipitation method. And a new contact material, Ag/SnO_2+La_2O_3+Bi_2O_3, wasproduced by the powder metallurgy method. Its properties are as follows: the density is 9.75-9.93g/cm^3, the resistivity is 2.31-2.55 μΩ ·cm, the hardness is 880-985 MPa. Its mi-crostructureshows that the fine oxides have a uniform distribution in the silver matrix. The results ofmake-break capacity and temperature rise testing show that the new material has better ability ofanti-arc erosion and lower temperature rise than that of commonly used Ag/CdO.
基金Project(2014DFA90520)supported by the International Cooperation Program of Ministry of Science and Technology of ChinaProject(2013A090100003)supported by the Production,Teaching and Research Program of Guangdong Province,ChinaProject(2013DY048)supported by the Science and Technology Cooperation Program of Daye Nonferrous Metals Group,China
文摘The ultrafine silver powders were prepared by liquid reduction method using Arabic gum as dispersant.The effects of different dispersants,pH values,and temperature on the morphology and particle size of silver powders were investigated.It is found that Arabic gum can better adsorb on silver particles via chemical adsorption,and it shows the best dispersive effect among all the selected dispersants.The particle size of silver powders can be finely tuned from 0.34 to 4.09μm by adjusting pH values,while the morphology of silver powders can be tuned by changing the temperature.The silver powders with high tap density higher than 4.0 g/cm3 were successfully prepared in a wide temperature range of 21.8-70°C.Especially,the tap density is higher than 5.0 g/cm3 when the temperature is optimized to be 50°C.The facile process and high silver concentration of this method make it a promising way to prepare high quality silver powders for electronic paste.
文摘Silver-tin oxide composite powders and silver powders were synthesized by hydrothermal method using NH3 to complex Ag+, SO 32?to reduce Ag (NH3)+2 and Na2SnO3 as the source of tin. The powders were characterized by XRD, SEM and EDX. The results show that there are macroscopic and microscopic differences between two kinds of powders. Spherical silver powders are 3 μm in diameter, and silver-tin oxide composite powders are mainly flake of about 0.3 μm in thickness. Silver crystal in silver-tin oxide composite powders is preferentially oriented in the (111) crystallographic direction and its oriented index is 2.581. Crystal lattice parameter of silver crystal of silver tin-oxide composite powders is 0.409 34 nm, larger than 0.408 68 nm of silver powders. The XPS analysis shows that silver in silver-tin oxide composite powders is metallic silver and tin oxide in silver tin-oxide composite powders has the red shift for Sn4+(3d5/2) and O2-(1s).
