In this paper, Ti（C,N）-based nano cermets were prepared by nano particles, and the effect of VC addition on the micmstructure and properties of Ti（C,N）-based nano cermets was investigated. The results showed that ...In this paper, Ti（C,N）-based nano cermets were prepared by nano particles, and the effect of VC addition on the micmstructure and properties of Ti（C,N）-based nano cermets was investigated. The results showed that there existed black-core grayish-rim strucmre as well as gray-core grayish-rim structure in VC-doped Ti（C,N）-based nano cermets. With the increase of VC addition, the number of gray cores in- creased, the lattice parameter of Ti（C,N） phase increased, the grain size decreased, the hardness and fracture toughness of Ti（C,N）-based nano cermets were enhanced, and nearly full densification could be achieved. However, excessive addition of VC to 1 wt% resulted in slight decrease in hardness and fracture toughness. Some deep dimples were found in the fracture surface of cermets with VC addition, which corresponded to ductile fracture.展开更多
For ultra-low-carbon(ULC)steel production,the higher oxygen content before Ruhrstahl-Heraeus(RH)decarburization(de-C)treatment could shorten the de-C time in the RH degasser.However,this would lead to oxidation rates ...For ultra-low-carbon(ULC)steel production,the higher oxygen content before Ruhrstahl-Heraeus(RH)decarburization(de-C)treatment could shorten the de-C time in the RH degasser.However,this would lead to oxidation rates being exceeded by molten steel production,affecting ULC steel surface quality.In this work,a carbon powder addition(CPA)process was proposed to reduce the dissolved oxygen content at the end of RH de-C through addition of carbon powder to molten steel in the vacuum vessel.Carbon and oxygen behavior during the CPA and conventional process was then studied.The results demonstrated that the de-C rate with CPA was lower compared to the conventional process,but the carbon content at the end of de-C presented no difference.The de-C reaction for CPA process took place in the four reaction sites:(1)within the bulk steel where the spontaneous CO bubbles form;(2)splashing area on the liquid steel surface;(3)Ar bubble surface;(4)molten steel surface.The CPA process could significantly reduce the dissolved oxygen content at the end of de-C,the sum content of FeO and MnO in the slag,the aluminum consumption,and the defect rate of rolled products.This was beneficial in improving ULC steel cleanliness.展开更多
基金financially supported by National Natural Science Foundation of China (No.50874076 and No.51074110)the Scientist Serving Enterprise Action Plan from Ministry of Science and Technology (No.2009GJF00030)
文摘In this paper, Ti（C,N）-based nano cermets were prepared by nano particles, and the effect of VC addition on the micmstructure and properties of Ti（C,N）-based nano cermets was investigated. The results showed that there existed black-core grayish-rim strucmre as well as gray-core grayish-rim structure in VC-doped Ti（C,N）-based nano cermets. With the increase of VC addition, the number of gray cores in- creased, the lattice parameter of Ti（C,N） phase increased, the grain size decreased, the hardness and fracture toughness of Ti（C,N）-based nano cermets were enhanced, and nearly full densification could be achieved. However, excessive addition of VC to 1 wt% resulted in slight decrease in hardness and fracture toughness. Some deep dimples were found in the fracture surface of cermets with VC addition, which corresponded to ductile fracture.
基金financially supported by the National Natural Science Foundation of China(No.51874021)Fundamental Research Funds for the Central Universities of China(No.FRF-IC-18-002)State Key Laboratory of Advanced Metallurgy Foundation of China(No.41618019)
文摘For ultra-low-carbon(ULC)steel production,the higher oxygen content before Ruhrstahl-Heraeus(RH)decarburization(de-C)treatment could shorten the de-C time in the RH degasser.However,this would lead to oxidation rates being exceeded by molten steel production,affecting ULC steel surface quality.In this work,a carbon powder addition(CPA)process was proposed to reduce the dissolved oxygen content at the end of RH de-C through addition of carbon powder to molten steel in the vacuum vessel.Carbon and oxygen behavior during the CPA and conventional process was then studied.The results demonstrated that the de-C rate with CPA was lower compared to the conventional process,but the carbon content at the end of de-C presented no difference.The de-C reaction for CPA process took place in the four reaction sites:(1)within the bulk steel where the spontaneous CO bubbles form;(2)splashing area on the liquid steel surface;(3)Ar bubble surface;(4)molten steel surface.The CPA process could significantly reduce the dissolved oxygen content at the end of de-C,the sum content of FeO and MnO in the slag,the aluminum consumption,and the defect rate of rolled products.This was beneficial in improving ULC steel cleanliness.
