Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresea...Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.展开更多
'Living'/controlled radical polymerization of styrene was carried out with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS)/CuCl2/bipyridine (bipy) initiation system at 120 degreesC. The molecular weights of ...'Living'/controlled radical polymerization of styrene was carried out with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS)/CuCl2/bipyridine (bipy) initiation system at 120 degreesC. The molecular weights of resultant PSt increased with the monomer conversion and the polydispersities were in the range of 1.37 similar to1.52. A linear ln([M](o)/[M]) versus time plot was also obtained indicating the constant concentration of growing radicals during the polymerization with this initiation system. End group analysis by H-1-NMR spectroscopic studies showed that the end groups of the polymer obtained is omega -functionalized by a chlorine group from the catalyst and alpha -functionalized by a (carbethoxy-cyano-phenyl)methyl group from the fragments of the initiator. Having CI atom at the chain end, the PSt obtained can be used as a macroinitiator to promote a chain-extension reaction with fresh St and block copolymerization reaction with a second monomer, such as methyl methacrylate, in the presence of CuCl/bipy catalyst via a conventional ATRP process.展开更多
基金Projects(52178371,52108355,52178321)supported by the National Natural Science Foundation of ChinaProject(202305)supported by the Research Project of Engineering Research Centre of Rock-Soil Drilling&Excavation and Protection,Ministry of Education,China。
文摘Square piles of reinforced concrete(RC)in marine environments are susceptible to chloride-inducedcorrosion.A novel reverse-seepage technique(RST)is applied to square piles to block the intrusion of chlorides.Thisresearch introduces a computational model designed to predict the lifespan of corrosion initiation in reinforced concretesquare piles when applied reverse-seepage pressure.The model considers the impacts of chloride binding and the tripletime-dependence property among the permeability,the corrected surface chloride concentration,and the diffusioncoefficient.The proposed numerical model is solved using the alternating direction implicit(ADI)approach,and itsaccuracy and reliability are evaluated by contrasting the computational outcomes with the analytical solution andexperimental results.Furthermore,the primary factors contributing to the corrosion of reinforced concrete square pilesare analyzed.The results indicate that applying RST can decrease the chloride penetration depth and prolong the lifespanof corrosion initiation in square piles.The water-cement ratio and reverse seepage pressure are the most influentialfactors.A water pressure of 0.4 MPa can double the life of concrete,and the durable life of concrete with a water-cementratio of 0.3 can reach 100 years.
文摘'Living'/controlled radical polymerization of styrene was carried out with diethyl 2,3-dicyano-2,3-diphenylsuccinate (DCDPS)/CuCl2/bipyridine (bipy) initiation system at 120 degreesC. The molecular weights of resultant PSt increased with the monomer conversion and the polydispersities were in the range of 1.37 similar to1.52. A linear ln([M](o)/[M]) versus time plot was also obtained indicating the constant concentration of growing radicals during the polymerization with this initiation system. End group analysis by H-1-NMR spectroscopic studies showed that the end groups of the polymer obtained is omega -functionalized by a chlorine group from the catalyst and alpha -functionalized by a (carbethoxy-cyano-phenyl)methyl group from the fragments of the initiator. Having CI atom at the chain end, the PSt obtained can be used as a macroinitiator to promote a chain-extension reaction with fresh St and block copolymerization reaction with a second monomer, such as methyl methacrylate, in the presence of CuCl/bipy catalyst via a conventional ATRP process.
