准噶尔盆地玛湖凹陷下二叠统风城组为盆地西北缘的主力烃源岩,具有较大的页岩油勘探前景。利用场发射电子扫描显微镜以及高压压汞等测试手段,对研究区玛页1井风城组页岩油储层的孔隙结构进行了精细研究和分类评价。研究结果表明:(1)玛...准噶尔盆地玛湖凹陷下二叠统风城组为盆地西北缘的主力烃源岩,具有较大的页岩油勘探前景。利用场发射电子扫描显微镜以及高压压汞等测试手段,对研究区玛页1井风城组页岩油储层的孔隙结构进行了精细研究和分类评价。研究结果表明:(1)玛湖凹陷风城组页岩油储层以薄层状或块状云质、粉砂质、钙质或硅质泥岩为主,且泥岩中常发育大量白云石、方解石、及硅质条带、团块或斑块。(2)研究区风城组页岩油储层孔隙类型主要有粒间孔、基质溶孔、粒内溶孔、晶间孔、晶内溶孔以及微裂缝等,以基质溶孔和晶间孔最为发育。储层物性差,孔隙度为0.4%~17.7%,大多小于3.0%;渗透率最大值为2.90 m D,大多小于0.03 mD,属于低孔特低渗储层。(3)研究区样品孔隙体积普遍较小,平均为0.25 cm3;均值系数平均为13.95;分选系数平均为2.44;偏态平均为0.97;峰态平均为1.25;变异系数平均为0.17;最大进汞饱和度低,平均为37.23%;退汞效率低,平均仅为25.73%。(4)研究区页岩油储层可分为Ⅰ,Ⅱ,Ⅲ等3类,其中物性好且内部孔隙连通性好的Ⅰ类页岩油储层具有好的油气勘探开发前景。展开更多
To study the seepage and deformation characteristics of coal at high temperatures,coal samples from six different regions were selected and subjected to computed tomography(CT)scanning studies.In conjunction with ANSY...To study the seepage and deformation characteristics of coal at high temperatures,coal samples from six different regions were selected and subjected to computed tomography(CT)scanning studies.In conjunction with ANSYS software,3 D reconstruction of CT images was used for the establishment of fluidsolid conjugate heat transfer model and coal thermal deformation model based on the microstructures of coal.In addition,the structure of coal was studied in 2 D and 3 D perspectives,followed by the analysis of seepage and deformation characteristics of coal at high temperatures.The results of this study indicated that porosity positively correlated with the fractal dimension,and the connectivity and seepage performances were roughly identical from 2 D and 3 D perspectives.As the porosity increased,the fractal dimension of coal samples became larger and the pore-fracture structures became more complex.As a result,the permeability of coal samples decreased.In the meantime,fluid was fully heated,generating high-temperature water at outlet.However,when the porosity was low,the outlet temperature was very high.The average deformation of coal skeleton with different pore-fracture structures at high temperatures showed a trend of initial increase and subsequent decrease with the increase of porosity and fractal dimension.The maximum deformation of coal skeleton positively correlated with connectivity but negatively correlated with the fractal dimension.展开更多
Reactive melt infiltration(RMI)is an effective method for fabrication of highly dense carbon fiber reinforced ultra-high temperature ceramic matrix composites(Cf/UHTCs).In this work,C_(f)/SiC-ZrC-ZrB_(2)composites wer...Reactive melt infiltration(RMI)is an effective method for fabrication of highly dense carbon fiber reinforced ultra-high temperature ceramic matrix composites(Cf/UHTCs).In this work,C_(f)/SiC-ZrC-ZrB_(2)composites were fabricated by infiltrating ZrSi_(2)melt into porous C_(f)/B_(4)C-C preforms,where the physical and chemical reactions involved during the RMI process were identified and analyzed.Inhomogeneous infiltration between the inter-and intra-bundle pores was revealed,and was found to be strongly related to the pore structures of the C_(f)/B_(4)C-C preform.It is indicated that the inhomogeneous infiltration can be mitigated remarkably with increasing porosity and pore size of the preform.The effect of pore size on the RMI process was also investigated by a quantitative model,which agrees very well with the experiment results.It further indicates that the inhomogeneous infiltration can also be relieved at elevated RMI temperature.However,excessive infiltration at elevated temperature or more porous preform may cause serious erosion on interphase and fibers,leading to mechanical properties deterioration of the final composites.展开更多
文摘准噶尔盆地玛湖凹陷下二叠统风城组为盆地西北缘的主力烃源岩,具有较大的页岩油勘探前景。利用场发射电子扫描显微镜以及高压压汞等测试手段,对研究区玛页1井风城组页岩油储层的孔隙结构进行了精细研究和分类评价。研究结果表明:(1)玛湖凹陷风城组页岩油储层以薄层状或块状云质、粉砂质、钙质或硅质泥岩为主,且泥岩中常发育大量白云石、方解石、及硅质条带、团块或斑块。(2)研究区风城组页岩油储层孔隙类型主要有粒间孔、基质溶孔、粒内溶孔、晶间孔、晶内溶孔以及微裂缝等,以基质溶孔和晶间孔最为发育。储层物性差,孔隙度为0.4%~17.7%,大多小于3.0%;渗透率最大值为2.90 m D,大多小于0.03 mD,属于低孔特低渗储层。(3)研究区样品孔隙体积普遍较小,平均为0.25 cm3;均值系数平均为13.95;分选系数平均为2.44;偏态平均为0.97;峰态平均为1.25;变异系数平均为0.17;最大进汞饱和度低,平均为37.23%;退汞效率低,平均仅为25.73%。(4)研究区页岩油储层可分为Ⅰ,Ⅱ,Ⅲ等3类,其中物性好且内部孔隙连通性好的Ⅰ类页岩油储层具有好的油气勘探开发前景。
基金supported by the National Natural Science Foundation of China(Project Nos.51934004,51674158,51574158,and 51474106)the Major Program of Shandong Province Natural Science Foundation(ZR2018ZA0602)+2 种基金the Taishan Scholar Talent Team Support Plan for Advantaged&Unique Discipline Areasthe Science and technology support plan for Youth Innovation of colleges and universities in Shandong Province(2019KJH006)the special funds for Taishan scholar project(TS20190935)。
文摘To study the seepage and deformation characteristics of coal at high temperatures,coal samples from six different regions were selected and subjected to computed tomography(CT)scanning studies.In conjunction with ANSYS software,3 D reconstruction of CT images was used for the establishment of fluidsolid conjugate heat transfer model and coal thermal deformation model based on the microstructures of coal.In addition,the structure of coal was studied in 2 D and 3 D perspectives,followed by the analysis of seepage and deformation characteristics of coal at high temperatures.The results of this study indicated that porosity positively correlated with the fractal dimension,and the connectivity and seepage performances were roughly identical from 2 D and 3 D perspectives.As the porosity increased,the fractal dimension of coal samples became larger and the pore-fracture structures became more complex.As a result,the permeability of coal samples decreased.In the meantime,fluid was fully heated,generating high-temperature water at outlet.However,when the porosity was low,the outlet temperature was very high.The average deformation of coal skeleton with different pore-fracture structures at high temperatures showed a trend of initial increase and subsequent decrease with the increase of porosity and fractal dimension.The maximum deformation of coal skeleton positively correlated with connectivity but negatively correlated with the fractal dimension.
基金The financial support from“The National Key Research and Development Program of China”(No.2017YFB0703200)“National Natural Science Foundation of China”(No.51702341)+1 种基金Chinese Academy of Sciences Innovative Funding(CXJJ-17-M169)“CAS Pioneer Hundred Talents Program”are greatly acknowledged.
文摘Reactive melt infiltration(RMI)is an effective method for fabrication of highly dense carbon fiber reinforced ultra-high temperature ceramic matrix composites(Cf/UHTCs).In this work,C_(f)/SiC-ZrC-ZrB_(2)composites were fabricated by infiltrating ZrSi_(2)melt into porous C_(f)/B_(4)C-C preforms,where the physical and chemical reactions involved during the RMI process were identified and analyzed.Inhomogeneous infiltration between the inter-and intra-bundle pores was revealed,and was found to be strongly related to the pore structures of the C_(f)/B_(4)C-C preform.It is indicated that the inhomogeneous infiltration can be mitigated remarkably with increasing porosity and pore size of the preform.The effect of pore size on the RMI process was also investigated by a quantitative model,which agrees very well with the experiment results.It further indicates that the inhomogeneous infiltration can also be relieved at elevated RMI temperature.However,excessive infiltration at elevated temperature or more porous preform may cause serious erosion on interphase and fibers,leading to mechanical properties deterioration of the final composites.
