The gaseous penetration of La-Ce into PbTiO3 ceramics is reported. The compounds of La2Ti6O15 and CeTi21O38 are formed and the new La2Ti6O15-CeTi21O38-PbTiO3 ceramics are prepared by the penetration of La and Ce in th...The gaseous penetration of La-Ce into PbTiO3 ceramics is reported. The compounds of La2Ti6O15 and CeTi21O38 are formed and the new La2Ti6O15-CeTi21O38-PbTiO3 ceramics are prepared by the penetration of La and Ce in the gaseous state. The new ceramic materials have a significant change in electric properties. The room temperature resistivity decreases from 2.0×1010 to 0.248 Ω. m, and the grain resistance exhibits an obvious PTCR effect with the change of temperature. However, the grain boundary resistance decreases rapidly with increase in temperature. The change rule of the total resistance is similar to that of the grain boundary, and the PTCR effect disappears and the tendency of transition to a conductive body is manifest. The XPS analysis suggests that the particles that are Pb, Ti, La and Ce in La2Ti6O15-CeTi21O38-PbTiO3 ceramics all change their valence and lead to decreasing resistivity, and the bound energy peak values of elements in La2Ti6O15-CeTi21O38-PbTiO3 ceramics are also reported. The La2Ti6O15-CeTi21O38-PbTiO3 ceramics have a better thermal stability in high temperatures through TG-DTA analysis.展开更多
The properties of PbTiO 3 ceramics are improved by adding a small amount of Nd 2O 3. This improvement is closely related to microstructure and electrical behaviour of Nd 2O 3 modified PbTiO 3 ceramics. In this p...The properties of PbTiO 3 ceramics are improved by adding a small amount of Nd 2O 3. This improvement is closely related to microstructure and electrical behaviour of Nd 2O 3 modified PbTiO 3 ceramics. In this paper, the properties of Nd 2O 3 modified PbTiO 3 ceramics are studied.展开更多
The gaseous Pr-penetration is a new method to modify ceramics, which is expected to be a promising method for producing new conductor ceramic materials. The gaseous penetration of Pr into PbTiO_3 ceramics and their im...The gaseous Pr-penetration is a new method to modify ceramics, which is expected to be a promising method for producing new conductor ceramic materials. The gaseous penetration of Pr into PbTiO_3 ceramics and their improved electric properties were reported. Through XRD, EPMA and SEM analysis,it is confirmed that the gaseous penetration makes Pr enter into PbTiO_3 ceramics, and the new compound of Pr_2Ti_2O_7 is formed by the penetration of Pr in the gaseous state. The formed new Pr_2Ti_2O_7-PbTiO_3 ceramic materials have a significant change in electric properties. The room temperature resistivity decreases from 2.0×10^(10) Ω·m to 9.487 Ω·m. The grain resistance and the grain boundary resistance decrease with increase in temperature, and the PTCR effect disappears. The tendency of transition to a conductive body is manifest.展开更多
MnO_2doped PbTiO_3 ceramics was prepared by means of solgel method, its density and some electric properties were investigated. The results showed that it was feasible to prepare multicomponent PbTiO_3 solgel series ...MnO_2doped PbTiO_3 ceramics was prepared by means of solgel method, its density and some electric properties were investigated. The results showed that it was feasible to prepare multicomponent PbTiO_3 solgel series with the aid of solgel method, the obtained MnO_2doped PbTiO_3 ceramics showed a highpurity, uniform component, better dense structure, hardly crack, and had good dielectric, piezoelectric, ferroelectric and pyroelectric properties.展开更多
文摘The gaseous penetration of La-Ce into PbTiO3 ceramics is reported. The compounds of La2Ti6O15 and CeTi21O38 are formed and the new La2Ti6O15-CeTi21O38-PbTiO3 ceramics are prepared by the penetration of La and Ce in the gaseous state. The new ceramic materials have a significant change in electric properties. The room temperature resistivity decreases from 2.0×1010 to 0.248 Ω. m, and the grain resistance exhibits an obvious PTCR effect with the change of temperature. However, the grain boundary resistance decreases rapidly with increase in temperature. The change rule of the total resistance is similar to that of the grain boundary, and the PTCR effect disappears and the tendency of transition to a conductive body is manifest. The XPS analysis suggests that the particles that are Pb, Ti, La and Ce in La2Ti6O15-CeTi21O38-PbTiO3 ceramics all change their valence and lead to decreasing resistivity, and the bound energy peak values of elements in La2Ti6O15-CeTi21O38-PbTiO3 ceramics are also reported. The La2Ti6O15-CeTi21O38-PbTiO3 ceramics have a better thermal stability in high temperatures through TG-DTA analysis.
文摘The properties of PbTiO 3 ceramics are improved by adding a small amount of Nd 2O 3. This improvement is closely related to microstructure and electrical behaviour of Nd 2O 3 modified PbTiO 3 ceramics. In this paper, the properties of Nd 2O 3 modified PbTiO 3 ceramics are studied.
文摘The gaseous Pr-penetration is a new method to modify ceramics, which is expected to be a promising method for producing new conductor ceramic materials. The gaseous penetration of Pr into PbTiO_3 ceramics and their improved electric properties were reported. Through XRD, EPMA and SEM analysis,it is confirmed that the gaseous penetration makes Pr enter into PbTiO_3 ceramics, and the new compound of Pr_2Ti_2O_7 is formed by the penetration of Pr in the gaseous state. The formed new Pr_2Ti_2O_7-PbTiO_3 ceramic materials have a significant change in electric properties. The room temperature resistivity decreases from 2.0×10^(10) Ω·m to 9.487 Ω·m. The grain resistance and the grain boundary resistance decrease with increase in temperature, and the PTCR effect disappears. The tendency of transition to a conductive body is manifest.
文摘MnO_2doped PbTiO_3 ceramics was prepared by means of solgel method, its density and some electric properties were investigated. The results showed that it was feasible to prepare multicomponent PbTiO_3 solgel series with the aid of solgel method, the obtained MnO_2doped PbTiO_3 ceramics showed a highpurity, uniform component, better dense structure, hardly crack, and had good dielectric, piezoelectric, ferroelectric and pyroelectric properties.
