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转炉钢渣中磷的富集与富磷相长大 被引量:8
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作者 武杏荣 安吉南 +1 位作者 陈荣欢 李辽沙 《安徽工业大学学报(自然科学版)》 CAS 2010年第3期233-237,241,共6页
采用扫描电镜、能谱分析和X射线衍射分析现场转炉钢渣中磷元素的分布,通过添加SiO_2改性剂,在1540℃下对钢渣进行重熔后冷凝,研究改性处理后钢渣中P的富集与P富集相的长大。结果表明:现场转炉钢渣中的磷主要存在于硅酸二钙(C_2S)和硅酸... 采用扫描电镜、能谱分析和X射线衍射分析现场转炉钢渣中磷元素的分布,通过添加SiO_2改性剂,在1540℃下对钢渣进行重熔后冷凝,研究改性处理后钢渣中P的富集与P富集相的长大。结果表明:现场转炉钢渣中的磷主要存在于硅酸二钙(C_2S)和硅酸三钙(C_3S)两个相中,尚有少量存在于基质相中;改性处理后钢渣中没有生成C_3S相,P主要富集在一个相C_2S中,该相中P_2O_3质量分数达到6.5%。动力学研究表明:当改性钢渣分别以1,3,5℃/min冷却时,P富集相的平均粒径分别达到87,56,8μm;当冷却速率小于3℃/min能使P富集相长大到50μm以上,为后续磨矿和P富集相的分离打下基础。 展开更多
关键词 转炉钢渣 磷富集相 硅酸二钙
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Design and experiment on concentration of phosphorus in factory converter slags
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作者 WU Xingrong AN Jinan +1 位作者 LI Liaosha CHEN Ronghuan 《Baosteel Technical Research》 CAS 2010年第S1期140-,共1页
The phosphorus-concentrating phase in the converter slags was designed and simulated by synthetic converter slag.The distribution of phosphorus in factory converter slags was also analyzed by scanning electron microsc... The phosphorus-concentrating phase in the converter slags was designed and simulated by synthetic converter slag.The distribution of phosphorus in factory converter slags was also analyzed by scanning electron microscope(SEM) and X-ray diffraction(XRD).Then factory converter slags were modified by addition of SiO_2 and heated to 1540℃and then cooled to room temperature.The results showed that the phosphorus in the factory converter slags was mostly distributed in two phases:dicalcium silicate (C_2S) and tricalcium silicate(C_3S) by formation of solid solution,and with a little in matrix.Whereas,in the synthetic slags with the basicity close to 3,phosphorus was almost concentrated in phase of C_2S(Pconcentrating phase) in which the contents of P_2O_5 reach to 7.74%.This lays a good foundation for grinding and separation of P- concentrating phase. 展开更多
关键词 pHOSpHORUS converter slags p-concentrating phase dicalcium silicate
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