Petroleum exploration targets are extending gradually from the single conventional trap reservoirs to the large-scale unconventional continuous accumulations. Oil and gas reservoirs have been divided into two types ba...Petroleum exploration targets are extending gradually from the single conventional trap reservoirs to the large-scale unconventional continuous accumulations. Oil and gas reservoirs have been divided into two types based on the trapping mechanism and distribution of oil and gas： conven- tional single-trap reservoirs, such as the Daqing oil field in Songliao Basin and the Kela-2 gas field in Tarim Basin; and unconventional continuous petroleum accumulation, such as Upper Paleozoic tight gas and Mesozoic tight oil in Ordos Basin, and Upper Triassic tight gas in Sichuan Basin. Two typical geologic characteristics of continuous petroleum accumulation involve： （1） coexisting source and reser- voir, petroleum pervasive throughout a large area tight reservoirs, and no obvious traps or well-defined water-oil and gas contracts; （2） non-buoyancy accumulation, continuous petroleum charge, and no sig- nificant influence by buoyancy. Continuous petroleum accumulation generally have nm-scale pore throats, and the diameters range of 10-500 nm. The geometry and connectivity of these pore throats has significant impact on the migration and distribution of oil and gas in continuous petroleum accu- mulation. China has numerous continuous petroleum accumulation containing various petroleum de- posits, and the exploration of continuous resources is very promising. Unconventional petroleum geol- ogy will become an important new subject in petroleum geology in future, and the nano-technology will function greatly on research, exploration and development of the hydrocarbon accumulation in nano-pore-throats.展开更多
This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization ...This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method （LBM） can simulate the CO2 displacement processes in a two-dimensional or three-dimensional （3D） pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.展开更多
Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT...Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT aerogel structure shows nano-pore size(30-40 nm),high specific surface area(559 m^(2)g^(−1)),high void fraction(91.7%)and enhanced mechanical property:(1)the nano-pore size is beneficial for efficiently blocking thermal conduction and thermal convection via Knudsen effect(beneficial for infrared(IR)stealth);(2)the heterogeneous interface was beneficial for IR reflection(beneficial for IR stealth)and MWCNT polarization loss(beneficial for electromagnetic wave(EMW)attenuation);(3)the high void fraction was beneficial for enhancing thermal insulation(beneficial for IR stealth)and EMW impedance match(beneficial for EMW attenuation).Guided by the above theoretical design strategy,PVTMS@MWCNT nano-aerogel shows superior EMW absorption property(cover all Ku-band)and thermal IR stealth property(ΔT reached 60.7℃).Followed by a facial combination of the above nano-aerogel with graphene film of high electrical conductivity,an extremely high electromagnetic interference shielding material(66.5 dB,2.06 mm thickness)with superior absorption performance of an average absorption-to-reflection(A/R)coefficient ratio of 25.4 and a low reflection bandwidth of 4.1 GHz(A/R ratio more than 10)was experimentally obtained in this work.展开更多
基金supported by the China Major National Scientific and Technological Project(No.2011ZX05001)
文摘Petroleum exploration targets are extending gradually from the single conventional trap reservoirs to the large-scale unconventional continuous accumulations. Oil and gas reservoirs have been divided into two types based on the trapping mechanism and distribution of oil and gas： conven- tional single-trap reservoirs, such as the Daqing oil field in Songliao Basin and the Kela-2 gas field in Tarim Basin; and unconventional continuous petroleum accumulation, such as Upper Paleozoic tight gas and Mesozoic tight oil in Ordos Basin, and Upper Triassic tight gas in Sichuan Basin. Two typical geologic characteristics of continuous petroleum accumulation involve： （1） coexisting source and reser- voir, petroleum pervasive throughout a large area tight reservoirs, and no obvious traps or well-defined water-oil and gas contracts; （2） non-buoyancy accumulation, continuous petroleum charge, and no sig- nificant influence by buoyancy. Continuous petroleum accumulation generally have nm-scale pore throats, and the diameters range of 10-500 nm. The geometry and connectivity of these pore throats has significant impact on the migration and distribution of oil and gas in continuous petroleum accu- mulation. China has numerous continuous petroleum accumulation containing various petroleum de- posits, and the exploration of continuous resources is very promising. Unconventional petroleum geol- ogy will become an important new subject in petroleum geology in future, and the nano-technology will function greatly on research, exploration and development of the hydrocarbon accumulation in nano-pore-throats.
基金The authors gratefully acknowledge the financial support of the National Natural Science Foundation of China （Grant Nos. 51374213 and 51674251）, the State Key Research Development Program of China （Grant No. 2016YFC0600705）, the National Natural Science Fund for Distinguished Young Scholars of China （Grant No. 51125017）, the Fund for Innovative Research and Development Group Program of Jiangsu Province （Grant No. 2014- 27）, the Science Fund for Creative Research Groups of the National Natural Science Foundation of China （Grant No. 51421003）, and the Priority Academic Program Development of the Jiangsu Higher Education Institutions （PAPD 2014）.
文摘This article reports recent developments and advances in the simulation of the CO2-formation fluid displacement behaviour at the pore scale of subsurface porous media. Roughly, there are three effective visualization approaches to detect and observe the CO2-formation fluid displacement mechanism at the micro-scale, namely, magnetic resonance imaging, X-ray computed tomography and fabricated micromodels, but they are not capable of investigating the dis- placement process at the nano-scale. Though a lab-on-chip approach for the direct visualization of the fluid flow behaviour in nanoscale channels has been developed using an advanced epi-fluorescence microscopy method combined with a nanofluidic chip, it is still a qualitative analysis method. The lattice Boltzmann method （LBM） can simulate the CO2 displacement processes in a two-dimensional or three-dimensional （3D） pore structure, but until now, the CO2 displace- ment mechanisms had not been thoroughly investigated and the 3D pore structure of real rock had not been directly taken into account in the simulation of the CO2 displacement process. The status of research on the applications of CO2 displacement to enhance shale gas recovery is also analyzed in this paper. The coupling of molecular dynamics and LBM in tandem is proposed to simulate the CO2-shale gas displacement process based on the 3D digital model of shale obtained from focused ion beams and scanning electron microscopy.
基金the National Natural Science Foundation(No.52073187)NSAF Foundation(No.U2230202)for their financial support of this project+3 种基金National Natural Science Foundation(No.51721091)Programme of Introducing Talents of Discipline to Universities(No.B13040)State Key Laboratory of Polymer Materials Engineering(No.sklpme2022-2-03)support of China Scholarship Council
文摘Pre-polymerized vinyl trimethoxy silane(PVTMS)@MWCNT nano-aerogel system was constructed via radical polymerization,sol-gel transition and supercritical CO_(2)drying.The fabricated organic-inorganic hybrid PVTMS@MWCNT aerogel structure shows nano-pore size(30-40 nm),high specific surface area(559 m^(2)g^(−1)),high void fraction(91.7%)and enhanced mechanical property:(1)the nano-pore size is beneficial for efficiently blocking thermal conduction and thermal convection via Knudsen effect(beneficial for infrared(IR)stealth);(2)the heterogeneous interface was beneficial for IR reflection(beneficial for IR stealth)and MWCNT polarization loss(beneficial for electromagnetic wave(EMW)attenuation);(3)the high void fraction was beneficial for enhancing thermal insulation(beneficial for IR stealth)and EMW impedance match(beneficial for EMW attenuation).Guided by the above theoretical design strategy,PVTMS@MWCNT nano-aerogel shows superior EMW absorption property(cover all Ku-band)and thermal IR stealth property(ΔT reached 60.7℃).Followed by a facial combination of the above nano-aerogel with graphene film of high electrical conductivity,an extremely high electromagnetic interference shielding material(66.5 dB,2.06 mm thickness)with superior absorption performance of an average absorption-to-reflection(A/R)coefficient ratio of 25.4 and a low reflection bandwidth of 4.1 GHz(A/R ratio more than 10)was experimentally obtained in this work.
