In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, ...In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.展开更多
In this paper,a comprehensive understanding of stable and metastable phase equilibria in binary Mg-Gd system was conducted with an aid of the CALculation of PHAse Diagram(CALPHAD)modeling.Firstly,thermodynamic descrip...In this paper,a comprehensive understanding of stable and metastable phase equilibria in binary Mg-Gd system was conducted with an aid of the CALculation of PHAse Diagram(CALPHAD)modeling.Firstly,thermodynamic descriptions of all the stable phases in the Mg-Gd system were re-assessed by considering all the experimental data in the literature.The discrepancy between the phase equilibria and thermochemical properties existing in the previous assessments was eliminated,and the better agreement with the experimental data was achieved in the present assessment.Secondly,the Gibbs energies for metastable β"-Mg3Gd and β"-Mg7Gd were constructed based on the first-principles and CALPHAD computed results as well as their correlation,and then incorporated into the CALPHAD descriptions.The model-predicted solvuses of(Mg)in equilibrium with the metastable β"-Mg7Gd and β'-Mg7Gd compounds showed very good agreement with the limited experimental data.Finally,the presently obtained thermodynamic descriptions of both stable and metastable phases in the binary Mg-Gd system were further validated by realizing the quantitative Scheil-Gulliver solidification simulations of 5 as-cast Mg-Gd alloys,and the successful prediction of the precipitation sequences in Mg-15Gd and Mg-12Gd alloys during the aging process.展开更多
Feng Fengyi , Zhang Pin , He Youjian 1, Li Yuhong1 , Zhou Meizhen2 , Chen Gang2 and Li Lin2 The Cancer Hospital of the CAMS & PUMC, Beijing 1000211 The Cancer Hospital of Sun Yat Sen University of Medical Science...Feng Fengyi , Zhang Pin , He Youjian 1, Li Yuhong1 , Zhou Meizhen2 , Chen Gang2 and Li Lin2 The Cancer Hospital of the CAMS & PUMC, Beijing 1000211 The Cancer Hospital of Sun Yat Sen University of Medical Sciences, Guangzhou 5100602Beijing Hospital of the Ministry of Health, Beijing 100730展开更多
Escherichia coli strain K-12 MG1655 has been proposed as an appropriate host strain for industrial production.However,the direct application of this strain suffers from the transformation inefficiency and plasmid inst...Escherichia coli strain K-12 MG1655 has been proposed as an appropriate host strain for industrial production.However,the direct application of this strain suffers from the transformation inefficiency and plasmid instability.Herein,we conducted genetic modifications at a serial of loci of MG1655 genome,generating a robust and universal host strain JW128 with higher transformation efficiency and plasmid stability that can be used to efficiently produce desired chemicals after introducing the corresponding synthetic pathways.Using JW128 as the host,the titer of isobutanol reached 5.76 g/L in shake-flask fermentation,and the titer of lycopene reached 1.91 g/L in test-tube fermentation,40-fold and 5-fold higher than that of original MG1655,respectively.These results demonstrated JW128 is a promising chassis for high-level production of value-added chemicals.展开更多
Due to positive mixing heat between Fe and Mg,it is difficult to diffuse for Fe-Mg at the interface of steel/Mg laminated composites,resulting in the inability to achieve high-strength metallurgical bonding.In this pa...Due to positive mixing heat between Fe and Mg,it is difficult to diffuse for Fe-Mg at the interface of steel/Mg laminated composites,resulting in the inability to achieve high-strength metallurgical bonding.In this paper,20#steel/Mg laminated composites were prepared by large deformation rolling and subse-quent diffusion heat treatment process.The interfacial bonding strength was improved by constructing high-density crystal defects at the interface to promote element diffusion.The mechanisms of interface morphology evolution and element diffusion were analyzed by finite element simulation and theoretical calculation.The results show after diffusion heat treatment,the bond strength of the large deformation rolled interface was increased from 14 to 30 MPa.Fe-Mg transition layer with about 80 nm thickness as well as high-density vacancies,dislocations and grain boundaries were formed in the large deforma-tion rolled interface region.During diffusion heat treatment,Mg elements diffused into grain interior and grain boundary regions of 20#steel under the effect of heat-force coupling,and the thickness of Fe-Mg transition layer increased to 150 nm,forming an Fe-based supersaturated solid solution.The in-terface with high-density defects constituted a non-equilibrium interface.The 20#steel internal energy in the non-equilibrium interface is able to overcome positive mixing heat of immiscible Fe-Mg system and provide the driving force for Mg elements diffusion.Promoting elemental diffusion by constructing high-density defects can be a new concept to achieve metallurgical bonding at the interface of immiscible metal laminated composites.展开更多
In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluat...In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluation of all available experimental data from the published literature.The solution phases,including liquid,hcp(Mg) and orthorhombic(Ga),were described by the substitutional solution model,of which the excess Gibbs energies were expressed with the Redlich-Kister polynomial.Meanwhile,all intermetallic compounds,Mg5Ga2,Mg2Ga,MgGa,MgGa2 and Mg2Ga5,were modeled as stoichiometric compounds.A set of self-consistent thermodynamic parameters formulating the Gibbs energies of various phases in the Mg-Ga binary system were obtained finally.The much better agreement is achieved between the calculated results and the reported experimental data.展开更多
Magnetic tunnel junctions(MTJs) based on MgO barrier have been fabricated by sputtering single crystal MgO target and metal Mg target, respectively, using magnetic sputtering system Nordiko 2000. MgO barriers have bee...Magnetic tunnel junctions(MTJs) based on MgO barrier have been fabricated by sputtering single crystal MgO target and metal Mg target, respectively, using magnetic sputtering system Nordiko 2000. MgO barriers have been formed by a multi-step deposition and natural oxidization of Mg layer. Mg layer thickness,oxygen flow rate and oxidization time were adjusted and the tunnel magnetoresistance(TMR) ratio of optimal MTJs is over 60% at annealing temperature 385. The(001) MgO crystal structure was obtained when the separation distance between MgO target and substrate is less than 6 cm. The TMR ratio of most MgO based MTJs are over 100% at the separation distance of 5 cm and annealing temperature 340. The TMR ratios of MTJs are almost zero when the separation distance ranges from 6 to 10 cm, due to the amorphous nature of the MgO film.展开更多
The Ga-Hg binary system was thermodynamically assessed by the CALPHAD method, but only configuration contributions were considered to the entropy of the liquid. The Mg-Hg binary system has not been assessed yet. In th...The Ga-Hg binary system was thermodynamically assessed by the CALPHAD method, but only configuration contributions were considered to the entropy of the liquid. The Mg-Hg binary system has not been assessed yet. In the assessments of the Ga-Hg and Mg-Hg binary systems, solutions including liquid and hcp (Mg) were treated as substitution solutions, of which the excess Gibbs energies were formulated with the Relich-Kister polynomial. The intermetallic phases in the Mg-Hg binary system, Mg3Hg, Mg5Hg2, Mg2Hg, Mg5Hg3, MgHg, and MgHg2, were described as stoichiometric compounds. Based on the reported experimental data and thermodynamic properties of the phase diagram, sets of self-consistent parameters describing all phases in the Ga-Hg and the Mg-Hg binary systems were obtained.展开更多
Two types of Mg-Cu composition system graded density impactors used for complex loading （shock loading and quasi-isentropic compression） are designed by the elastic-plastic hydrodynamic method in this paper. Mixture...Two types of Mg-Cu composition system graded density impactors used for complex loading （shock loading and quasi-isentropic compression） are designed by the elastic-plastic hydrodynamic method in this paper. Mixtures of metal powders in the Mg-Cu system are cast into a series of 17 and 25 uniform compositions ranging from 100% Mg to 100% Cu. The graded den- sity impactors are launched to the stationary 10 Ixm aluminum film and 12 mm LiF window targets by a two-stage light-gas gun in the National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, and the resulting wave profiles are measured with the DISAR system. Hydrodynamic simulation results are perfectly consistent with the experiments. Our work in this paper will set up a foundation for further research of controllable loading/releasing routes and rate experiments in the future.展开更多
A microgrid(MG)refers to a set of loads,generation resources and energy storage systems acting as a controllable load or a generator to supply power and heating to a local area.The MG-generated power management is a c...A microgrid(MG)refers to a set of loads,generation resources and energy storage systems acting as a controllable load or a generator to supply power and heating to a local area.The MG-generated power management is a central topic for MG design and operation.The existence of dispersed generation(DG)resources has faced MG management with new issues.Depending on the level of exchanges between an MG and the main grid,the MG operation states can be divided into independent or grid-connected ones.Energy management in MGs aims to supply power at the lowest cost for optimal load response.This study examines MG energy management in two operational modes of islanded and grid-connected,and proposes a structure with two control layers(primary and secondary)for energy management.At the principal level of control,the energy management system is determined individually for all MG by taking into consideration the probability constraints and RES uncertainty by the Weibull the probability density function(PDF),generation resources’power as well as the generation surplus and deficit of each MG.Then,the information of the power surplus and deficit of each MG must be sent to the central energy management system.To confirm the proposed structure,a case system with two MGs and a condensive load is simulated by using a multi-time harmony search algorithm.Several scenarios are applied to evaluate the performance of this algorithm.The findings clearly show the effectiveness of the proposed system in the energy management of several MGs,leading to the optimal performance of the resources per MG.Moreover,the proposed control scheme properly controls the MG and grid’s performance in their interactions and offers a high level of robustness,stable behavior under different conditions and high quality of power supply.展开更多
基金supported by the Foundation for Development of Geological Science and Technology of the former Ministry of Geology and Mineral Resources of China grant HY979830
文摘In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.
基金The financial support from the National Key Research and Development Program of China(Grant no.2016YFB0301101)the Hunan Provincial Science and Technology Program of China(Grant no.2017RS3002)-Huxiang Youth Talent Plan+2 种基金the Youth Talent Project of Innovation-driven Plan at Central South University(Grant no.2019XZ027)the Hebei Provincial Science and Technology Program of China(Grant no.BJ2018026)-Outstanding Young Talents Plan is acknowledgedYing Tang acknowledges the financial support from the Yuanguang fellowship released by Hebei University of Technology.
文摘In this paper,a comprehensive understanding of stable and metastable phase equilibria in binary Mg-Gd system was conducted with an aid of the CALculation of PHAse Diagram(CALPHAD)modeling.Firstly,thermodynamic descriptions of all the stable phases in the Mg-Gd system were re-assessed by considering all the experimental data in the literature.The discrepancy between the phase equilibria and thermochemical properties existing in the previous assessments was eliminated,and the better agreement with the experimental data was achieved in the present assessment.Secondly,the Gibbs energies for metastable β"-Mg3Gd and β"-Mg7Gd were constructed based on the first-principles and CALPHAD computed results as well as their correlation,and then incorporated into the CALPHAD descriptions.The model-predicted solvuses of(Mg)in equilibrium with the metastable β"-Mg7Gd and β'-Mg7Gd compounds showed very good agreement with the limited experimental data.Finally,the presently obtained thermodynamic descriptions of both stable and metastable phases in the binary Mg-Gd system were further validated by realizing the quantitative Scheil-Gulliver solidification simulations of 5 as-cast Mg-Gd alloys,and the successful prediction of the precipitation sequences in Mg-15Gd and Mg-12Gd alloys during the aging process.
文摘Feng Fengyi , Zhang Pin , He Youjian 1, Li Yuhong1 , Zhou Meizhen2 , Chen Gang2 and Li Lin2 The Cancer Hospital of the CAMS & PUMC, Beijing 1000211 The Cancer Hospital of Sun Yat Sen University of Medical Sciences, Guangzhou 5100602Beijing Hospital of the Ministry of Health, Beijing 100730
基金The work finished in Beijing Institute of Technology was supported by the National Key R&D Program of China(grant No.2019YFA0904104)the National Natural Science Foundation of China(Grant No.21676026)the Fundamental Research Funds for the Central Universities.
文摘Escherichia coli strain K-12 MG1655 has been proposed as an appropriate host strain for industrial production.However,the direct application of this strain suffers from the transformation inefficiency and plasmid instability.Herein,we conducted genetic modifications at a serial of loci of MG1655 genome,generating a robust and universal host strain JW128 with higher transformation efficiency and plasmid stability that can be used to efficiently produce desired chemicals after introducing the corresponding synthetic pathways.Using JW128 as the host,the titer of isobutanol reached 5.76 g/L in shake-flask fermentation,and the titer of lycopene reached 1.91 g/L in test-tube fermentation,40-fold and 5-fold higher than that of original MG1655,respectively.These results demonstrated JW128 is a promising chassis for high-level production of value-added chemicals.
基金supported by the National Key R&D Program of China (No.2018YFA0707300).
文摘Due to positive mixing heat between Fe and Mg,it is difficult to diffuse for Fe-Mg at the interface of steel/Mg laminated composites,resulting in the inability to achieve high-strength metallurgical bonding.In this paper,20#steel/Mg laminated composites were prepared by large deformation rolling and subse-quent diffusion heat treatment process.The interfacial bonding strength was improved by constructing high-density crystal defects at the interface to promote element diffusion.The mechanisms of interface morphology evolution and element diffusion were analyzed by finite element simulation and theoretical calculation.The results show after diffusion heat treatment,the bond strength of the large deformation rolled interface was increased from 14 to 30 MPa.Fe-Mg transition layer with about 80 nm thickness as well as high-density vacancies,dislocations and grain boundaries were formed in the large deforma-tion rolled interface region.During diffusion heat treatment,Mg elements diffused into grain interior and grain boundary regions of 20#steel under the effect of heat-force coupling,and the thickness of Fe-Mg transition layer increased to 150 nm,forming an Fe-based supersaturated solid solution.The in-terface with high-density defects constituted a non-equilibrium interface.The 20#steel internal energy in the non-equilibrium interface is able to overcome positive mixing heat of immiscible Fe-Mg system and provide the driving force for Mg elements diffusion.Promoting elemental diffusion by constructing high-density defects can be a new concept to achieve metallurgical bonding at the interface of immiscible metal laminated composites.
基金Project supported by Scientific Research Foundation for Advanced Talents in Central South University of Forestry and Technology,ChinaProject(50731002) supported by the National Natural Science Foundation of China
文摘In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluation of all available experimental data from the published literature.The solution phases,including liquid,hcp(Mg) and orthorhombic(Ga),were described by the substitutional solution model,of which the excess Gibbs energies were expressed with the Redlich-Kister polynomial.Meanwhile,all intermetallic compounds,Mg5Ga2,Mg2Ga,MgGa,MgGa2 and Mg2Ga5,were modeled as stoichiometric compounds.A set of self-consistent thermodynamic parameters formulating the Gibbs energies of various phases in the Mg-Ga binary system were obtained finally.The much better agreement is achieved between the calculated results and the reported experimental data.
基金Natural Science Foundation of Shanghai Science and Technology Commission (grant No. 11ZR1411300)Pujiang Talent Program of Shanghai Science and Technology Commission (grant No. 11PJ1402700) for the financial support
文摘Magnetic tunnel junctions(MTJs) based on MgO barrier have been fabricated by sputtering single crystal MgO target and metal Mg target, respectively, using magnetic sputtering system Nordiko 2000. MgO barriers have been formed by a multi-step deposition and natural oxidization of Mg layer. Mg layer thickness,oxygen flow rate and oxidization time were adjusted and the tunnel magnetoresistance(TMR) ratio of optimal MTJs is over 60% at annealing temperature 385. The(001) MgO crystal structure was obtained when the separation distance between MgO target and substrate is less than 6 cm. The TMR ratio of most MgO based MTJs are over 100% at the separation distance of 5 cm and annealing temperature 340. The TMR ratios of MTJs are almost zero when the separation distance ranges from 6 to 10 cm, due to the amorphous nature of the MgO film.
文摘The Ga-Hg binary system was thermodynamically assessed by the CALPHAD method, but only configuration contributions were considered to the entropy of the liquid. The Mg-Hg binary system has not been assessed yet. In the assessments of the Ga-Hg and Mg-Hg binary systems, solutions including liquid and hcp (Mg) were treated as substitution solutions, of which the excess Gibbs energies were formulated with the Relich-Kister polynomial. The intermetallic phases in the Mg-Hg binary system, Mg3Hg, Mg5Hg2, Mg2Hg, Mg5Hg3, MgHg, and MgHg2, were described as stoichiometric compounds. Based on the reported experimental data and thermodynamic properties of the phase diagram, sets of self-consistent parameters describing all phases in the Ga-Hg and the Mg-Hg binary systems were obtained.
基金supported by the National Natural Science Foundation of China (Grant No. 11072228, 11002129)the Science Foundation of China Academy of Engineering Physics (Grant No. 2011B0202005)+1 种基金the Open Foundation of State Key Laboratory of Explosion Science and Technology(Grant No. KFJJ09-06)the Open Foundation of State Key Laboratory of Advanced Technology for Materials Synthesis and Process-ing, Wuhan University of Technology
文摘Two types of Mg-Cu composition system graded density impactors used for complex loading （shock loading and quasi-isentropic compression） are designed by the elastic-plastic hydrodynamic method in this paper. Mixtures of metal powders in the Mg-Cu system are cast into a series of 17 and 25 uniform compositions ranging from 100% Mg to 100% Cu. The graded den- sity impactors are launched to the stationary 10 Ixm aluminum film and 12 mm LiF window targets by a two-stage light-gas gun in the National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, and the resulting wave profiles are measured with the DISAR system. Hydrodynamic simulation results are perfectly consistent with the experiments. Our work in this paper will set up a foundation for further research of controllable loading/releasing routes and rate experiments in the future.
文摘A microgrid(MG)refers to a set of loads,generation resources and energy storage systems acting as a controllable load or a generator to supply power and heating to a local area.The MG-generated power management is a central topic for MG design and operation.The existence of dispersed generation(DG)resources has faced MG management with new issues.Depending on the level of exchanges between an MG and the main grid,the MG operation states can be divided into independent or grid-connected ones.Energy management in MGs aims to supply power at the lowest cost for optimal load response.This study examines MG energy management in two operational modes of islanded and grid-connected,and proposes a structure with two control layers(primary and secondary)for energy management.At the principal level of control,the energy management system is determined individually for all MG by taking into consideration the probability constraints and RES uncertainty by the Weibull the probability density function(PDF),generation resources’power as well as the generation surplus and deficit of each MG.Then,the information of the power surplus and deficit of each MG must be sent to the central energy management system.To confirm the proposed structure,a case system with two MGs and a condensive load is simulated by using a multi-time harmony search algorithm.Several scenarios are applied to evaluate the performance of this algorithm.The findings clearly show the effectiveness of the proposed system in the energy management of several MGs,leading to the optimal performance of the resources per MG.Moreover,the proposed control scheme properly controls the MG and grid’s performance in their interactions and offers a high level of robustness,stable behavior under different conditions and high quality of power supply.
