The double-doped La2/3＋4x/3Sr1/3-4x/3Mn1-xMgxO3 samples with fixed Mn^3＋/Mn^4＋ ratio equal to 2/1 are investigated by means of magnetism and transport measurements. Phase separation is observed at temperature highe...The double-doped La2/3＋4x/3Sr1/3-4x/3Mn1-xMgxO3 samples with fixed Mn^3＋/Mn^4＋ ratio equal to 2/1 are investigated by means of magnetism and transport measurements. Phase separation is observed at temperature higher than T^onset c for x = 0.10 and 0.15. For x = 0.10, rather strong phase separation induces drastic magnetic random potential and results in the localization of carriers. Thus, the varlable-range hopping process dominates. For other samples, there is no or only weak phase separation above T^onset c. Thus, thermal activation mechanism is responsible for the high temperature transport behaviour. For x = 0.20 and 0.25, unexpected AFM behaviour is observed at low temperature. All these results are well understood by considering the special role of the ＂double-doping＂.展开更多
To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase...To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase separation of SMG dispersion migrating in pores was simulated by using the microfluidic technology. Theoretically guided by the tree fork concentration distribution of red cells in biological fluid mechanics, the concentration distribution mathematical model of SMG in different pores is established. Furthermore, the micro and macro physical simulation experiments of continuous and dispersed phase flooding agents were carried out. The results show that the continuous flooding agent enters all the swept zones and increases the flow resistance in both larger and small pores. On the contrary, the particle phase separation phenomenon occurs during the injection process of dispersed flooding agent. The SMG particles gather in the larger pore to form bridge blinding, and the carrier fluid displace oil in the small pore. Working in cooperation, the SMG particle and carrier fluid drive the residual oil in the low permeability layers step by step and achieve the goal of enhanced oil recovery. The laboratory experimental results indicate that, the oil increment and water reduction effect of dispersed flooding agent is much better than that of continuous flooding agent, which is consistent with the field test results.展开更多
The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, comp...The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, compressive deformation promotes the development of nucleation and suppresses the coarsening of nanocrystallites at high temperatures.展开更多
Polyethersulfone (PES)-modified epoxy systems with stepwise reaction were studied throughout the entire curing process by using optical microscopes, time-resolved light scattering (TRLS), and a rheolometry instrument ...Polyethersulfone (PES)-modified epoxy systems with stepwise reaction were studied throughout the entire curing process by using optical microscopes, time-resolved light scattering (TRLS), and a rheolometry instrument compared with that of chainwise polymerization. The results suggested that the phase separation process is mainly controlled by the diffusion of epoxy oligomers for stepwise mechanism system and by that of epoxy monomers for chainwise mechanism system. In case of high PES content (SPES-20%) light-scattering results showed a viscoelastic phase separation and the characteristic relaxation time of phase separation can be described well by the WLF equation. However, in the case of low PES content (SPES-14%) secondary phase separation phenomenon was observed by Optical Microscope and further demonstrated by rheological study.展开更多
In the pharmaceutical industry, the analysis of atropisomers is of considerable interest from both scientific and regulatory perspectives. The compound of interest contains two stereogenic axes due to the hindered rot...In the pharmaceutical industry, the analysis of atropisomers is of considerable interest from both scientific and regulatory perspectives. The compound of interest contains two stereogenic axes due to the hindered rotation around the single bonds connecting the aryl groups, which results in four potential configurational isomers(atropisomers). The separation of the four atropisomers was achieved on a derivatized β-cyclodextrin bonded stationary phase. Further investigation showed that low temperature conditions, including sample preparation(-70 °C), sample storage(-70 °C), and chromatographic separation(6 °C), were critical to preventing interconversion. LC-UV-laser polarimetric analysis identified peaks 1 and 2 as a pair of enantiomers and peaks3 and 4 as another. Thermodynamic analysis of the retention data indicated that the separation of the pairs of enantiomers is primarily enthalpy controlled as indicated by the positive slope of the van't Huff plot. The difference in absolute Δ(Δ H), ranged from 2.20 k J/mol to 2.42 k J/mol.展开更多
The present paper covers the actional mechanism of trifluoroacetic acid for the separation of biopolymers investigated by using the parameters of stoichiometric displacement model for retention(SDM-R) in reversed-phas...The present paper covers the actional mechanism of trifluoroacetic acid for the separation of biopolymers investigated by using the parameters of stoichiometric displacement model for retention(SDM-R) in reversed-phase liquid chromatography. It was found that the trifluoroacetic acid(TFA) may participate in, or stimulate the association among displacing agent molecules in mobile phase, and decrease the affinity of both the associate molecules of the displacing agent and the TFA-protein ion-pairing. The former dominates over the separation selectivity of biopolymers as the concentration of TFA is lower than a given value, and the two contrary functions partly offset to each other and the latter dominates as its concentration is greater than the given value.展开更多
基金Project supported by the National Natural Science Foundation of China （Grant Nos 10504029 and 10334090）, and the State Key Project of Fundamental Research, China （Grant No 001CB610604）.
文摘The double-doped La2/3＋4x/3Sr1/3-4x/3Mn1-xMgxO3 samples with fixed Mn^3＋/Mn^4＋ ratio equal to 2/1 are investigated by means of magnetism and transport measurements. Phase separation is observed at temperature higher than T^onset c for x = 0.10 and 0.15. For x = 0.10, rather strong phase separation induces drastic magnetic random potential and results in the localization of carriers. Thus, the varlable-range hopping process dominates. For other samples, there is no or only weak phase separation above T^onset c. Thus, thermal activation mechanism is responsible for the high temperature transport behaviour. For x = 0.20 and 0.25, unexpected AFM behaviour is observed at low temperature. All these results are well understood by considering the special role of the ＂double-doping＂.
基金Supported by the China Postdoctoral Science Foundation(Grant No.2018M641610)China National Science and Technology Major Project(2016ZX05025-003)
文摘To compare the oil displacement mechanisms and performances of continuous phase flooding agent(traditional polymer solution) and dispersed phase flooding agent(particle-type polymer SMG dispersion), the particle phase separation of SMG dispersion migrating in pores was simulated by using the microfluidic technology. Theoretically guided by the tree fork concentration distribution of red cells in biological fluid mechanics, the concentration distribution mathematical model of SMG in different pores is established. Furthermore, the micro and macro physical simulation experiments of continuous and dispersed phase flooding agents were carried out. The results show that the continuous flooding agent enters all the swept zones and increases the flow resistance in both larger and small pores. On the contrary, the particle phase separation phenomenon occurs during the injection process of dispersed flooding agent. The SMG particles gather in the larger pore to form bridge blinding, and the carrier fluid displace oil in the small pore. Working in cooperation, the SMG particle and carrier fluid drive the residual oil in the low permeability layers step by step and achieve the goal of enhanced oil recovery. The laboratory experimental results indicate that, the oil increment and water reduction effect of dispersed flooding agent is much better than that of continuous flooding agent, which is consistent with the field test results.
基金Supported by the Science Foundation for Excellent Young Scholars of Heilongjiang Province under Grant No JC-05-11, the Program for New Century Excellent Talents in University of China under Grant No NCET-04-0322, and the Specialized Research Fund for the Doctoral Programme of Higher Education of China under Grant No 20040213049）
文摘The nanocrystallization behaviour of a bulk Zr-based metallic glass subjected to compressive stress is investigated in the supercooled liquid region. Compared with annealing treatments without compressive stress, compressive deformation promotes the development of nucleation and suppresses the coarsening of nanocrystallites at high temperatures.
基金Supported by the National Natural Science Foundation of China (Grant No. 50273007)
文摘Polyethersulfone (PES)-modified epoxy systems with stepwise reaction were studied throughout the entire curing process by using optical microscopes, time-resolved light scattering (TRLS), and a rheolometry instrument compared with that of chainwise polymerization. The results suggested that the phase separation process is mainly controlled by the diffusion of epoxy oligomers for stepwise mechanism system and by that of epoxy monomers for chainwise mechanism system. In case of high PES content (SPES-20%) light-scattering results showed a viscoelastic phase separation and the characteristic relaxation time of phase separation can be described well by the WLF equation. However, in the case of low PES content (SPES-14%) secondary phase separation phenomenon was observed by Optical Microscope and further demonstrated by rheological study.
文摘In the pharmaceutical industry, the analysis of atropisomers is of considerable interest from both scientific and regulatory perspectives. The compound of interest contains two stereogenic axes due to the hindered rotation around the single bonds connecting the aryl groups, which results in four potential configurational isomers(atropisomers). The separation of the four atropisomers was achieved on a derivatized β-cyclodextrin bonded stationary phase. Further investigation showed that low temperature conditions, including sample preparation(-70 °C), sample storage(-70 °C), and chromatographic separation(6 °C), were critical to preventing interconversion. LC-UV-laser polarimetric analysis identified peaks 1 and 2 as a pair of enantiomers and peaks3 and 4 as another. Thermodynamic analysis of the retention data indicated that the separation of the pairs of enantiomers is primarily enthalpy controlled as indicated by the positive slope of the van't Huff plot. The difference in absolute Δ(Δ H), ranged from 2.20 k J/mol to 2.42 k J/mol.
基金Supported by the National Natrual Science Foundation of China
文摘The present paper covers the actional mechanism of trifluoroacetic acid for the separation of biopolymers investigated by using the parameters of stoichiometric displacement model for retention(SDM-R) in reversed-phase liquid chromatography. It was found that the trifluoroacetic acid(TFA) may participate in, or stimulate the association among displacing agent molecules in mobile phase, and decrease the affinity of both the associate molecules of the displacing agent and the TFA-protein ion-pairing. The former dominates over the separation selectivity of biopolymers as the concentration of TFA is lower than a given value, and the two contrary functions partly offset to each other and the latter dominates as its concentration is greater than the given value.
