Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of ...Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of these catalysts were characterized by X-Ray Diffraction （XRD）, N2 absorption-desorption, Pyridine-Fourier Transform Infrared （Py-FTIR）, Transmission Electron Microscopy （TEM）, X-Ray Fluorescence （XRF）, Scanning Electron Microscopy （SEM） and NH3- Temperature Programmed Desorption （NH3-TPD）, and the performance of these catalysts in n-dodecane hydroisomerization was evaluated in a continuous down-flow fixed bed with a stainless steel tubular reactor. The characterization results indicated that the intergrowth zeolite ZSM-22/ZSM-23 possessed the dual structure of ZSM-22 and ZSM-23, and the catalyst Pt/ZSM-22/ZSM-23 had similar pores and weak acidity to Pt/ZSM-22 and Pt/ZSM-23 catalysts. Moreover, Pt/ZSM-22/ZSM-23 catalyst showed a high selectivity in hydroisomerization of long chain n-alkanes to mono-branched isomers. The evaluation results for n-dodecane hydroisomerization indicated that the activity of Pt/ZSM-22/ZSM-23 was the lowest, while the hydroisomerization selectivity was the highest among the three catalysts. The maximum yield of i-dodecane product was 68.3% over Pt/ZSM-22/ZSM-23 at 320 ℃.展开更多
Two borate-carbonates Ba4M(CO3)2(BO3)2(M =Ba, Sr) have been successfully synthesized in the open air representing the first examples of borate-carbnate complex.Their structures were determined by single crystal X-ray ...Two borate-carbonates Ba4M(CO3)2(BO3)2(M =Ba, Sr) have been successfully synthesized in the open air representing the first examples of borate-carbnate complex.Their structures were determined by single crystal X-ray diffraction and they both crystallize in same space group, Pnma.Their structures feature a Ba/Sr-based three dimensional framework composed of the BaO8 polyhedra(the SrO8 polyhedra), isolated BO3 and CO3 triangles. Detailed structure analysis shows that the intergrowth of [Ba3(BO3)2]/[Ba2Sr(BO3)2] and [BaCO3] layers favors the formation of these two borate-carbonates. In addition, their syntheses, spectroscopic properties and thermal behaviors were investigated.展开更多
Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin...Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.展开更多
基金the financial supports form Petrochina(050508-04-02)the National Natural Science Foundation of China(No.21073235,and 20833011)
文摘Hydroisomerization catalysts Pt/ZSM-22, Pt/ZSM-23, and Pt/ZSM-22/ZSM-23 were prepared by supporting Pt on ZSM-22, ZSM-23, and intergrowth zeolite ZSM-22/ZSM-23, respectively. The typical physicochemical properties of these catalysts were characterized by X-Ray Diffraction （XRD）, N2 absorption-desorption, Pyridine-Fourier Transform Infrared （Py-FTIR）, Transmission Electron Microscopy （TEM）, X-Ray Fluorescence （XRF）, Scanning Electron Microscopy （SEM） and NH3- Temperature Programmed Desorption （NH3-TPD）, and the performance of these catalysts in n-dodecane hydroisomerization was evaluated in a continuous down-flow fixed bed with a stainless steel tubular reactor. The characterization results indicated that the intergrowth zeolite ZSM-22/ZSM-23 possessed the dual structure of ZSM-22 and ZSM-23, and the catalyst Pt/ZSM-22/ZSM-23 had similar pores and weak acidity to Pt/ZSM-22 and Pt/ZSM-23 catalysts. Moreover, Pt/ZSM-22/ZSM-23 catalyst showed a high selectivity in hydroisomerization of long chain n-alkanes to mono-branched isomers. The evaluation results for n-dodecane hydroisomerization indicated that the activity of Pt/ZSM-22/ZSM-23 was the lowest, while the hydroisomerization selectivity was the highest among the three catalysts. The maximum yield of i-dodecane product was 68.3% over Pt/ZSM-22/ZSM-23 at 320 ℃.
基金supported by the Key Research Project of Frontier Science of CAS (QYZDB-SSW-JSC049)the Western Light Foundation of CAS (2016-QNXZ-A-2)Xinjiang International Science & Technology Cooperation Program (2017E01014)
文摘Two borate-carbonates Ba4M(CO3)2(BO3)2(M =Ba, Sr) have been successfully synthesized in the open air representing the first examples of borate-carbnate complex.Their structures were determined by single crystal X-ray diffraction and they both crystallize in same space group, Pnma.Their structures feature a Ba/Sr-based three dimensional framework composed of the BaO8 polyhedra(the SrO8 polyhedra), isolated BO3 and CO3 triangles. Detailed structure analysis shows that the intergrowth of [Ba3(BO3)2]/[Ba2Sr(BO3)2] and [BaCO3] layers favors the formation of these two borate-carbonates. In addition, their syntheses, spectroscopic properties and thermal behaviors were investigated.
文摘Ore textures and electron microprobe analyses show that in addition to highly scattered blebs in sphalerite grains, intergrown chalcopyrite also occurs as reds, myrrmekites andlamellae aligned along cleavages and twin boundaries of the host sphalerite. The majority of theintergrowths could have been formed by replacement of sphalerite by chalcopyrite, albeit part ofthem may have resulted from exsolution. Not only copper, but also iron were introduced intothe sphalerite by replacive fluids.While the front of the replacing fluid was moving forward through a sulphide orebody, Znand Pb were dissolved and Cu was precipitated, resulting in zonal refining of the sulphide ores.The remobilized zinc and lead were precipitated at favourable sites with changed physiccrchemical conditions. This is a Possible mechanism for the formation of copper-poor zinc and lead oresabove or lateral to the copper orebodies in some of the massive sulphide deceits reworked andoverprinted by late-stage granites and their hydrothermal fluids.
