The solubility of C in Mn melt at different contents of Si at 1350℃ was determined.The sol- ubility of Ca in Mn melts containing C in CaC_2 crucible under sealed condition at 1350℃ was ascertained.With these data,ev...The solubility of C in Mn melt at different contents of Si at 1350℃ was determined.The sol- ubility of Ca in Mn melts containing C in CaC_2 crucible under sealed condition at 1350℃ was ascertained.With these data,evaluation of the activity interaction coefficients e_C^(Si),e_C^C, e_C^(Ca) as well as γ_C^0 was made.The standard free energy of solution of C in liquid Mn based on the 1 wt-% solution standard,formulated in relation to T,was also estimated.Brief dis- cussion was made as to the confiormability of results with those given in the literature.展开更多
应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中...应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的二阶焓相互作用系数均为正值,并随着卤离子半径的变化而相应变化;且同种溶剂中,D-甘露醇的二阶焓相互作用系数要大于D-山梨醇的.结合两分子结构的差异,通过溶质-溶质相互作用和溶剂-溶质相互作用对这一结果进行了讨论.展开更多
文摘The solubility of C in Mn melt at different contents of Si at 1350℃ was determined.The sol- ubility of Ca in Mn melts containing C in CaC_2 crucible under sealed condition at 1350℃ was ascertained.With these data,evaluation of the activity interaction coefficients e_C^(Si),e_C^C, e_C^(Ca) as well as γ_C^0 was made.The standard free energy of solution of C in liquid Mn based on the 1 wt-% solution standard,formulated in relation to T,was also estimated.Brief dis- cussion was made as to the confiormability of results with those given in the literature.
文摘应用等温流动微量热技术测定了298.15 K下D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的稀释焓,利用M cM illan理论计算了D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中焓相互作用系数.结果表明,D-甘露醇和D-山梨醇在纯水和卤化钠水溶液中的二阶焓相互作用系数均为正值,并随着卤离子半径的变化而相应变化;且同种溶剂中,D-甘露醇的二阶焓相互作用系数要大于D-山梨醇的.结合两分子结构的差异,通过溶质-溶质相互作用和溶剂-溶质相互作用对这一结果进行了讨论.
