Suppression of the inner energy dissipation,related to the lattice phonons and inner defects,in lanthanide doped upco nversion luminescent materials remains a formidable challenge.Herein,we reveal an energy cycling st...Suppression of the inner energy dissipation,related to the lattice phonons and inner defects,in lanthanide doped upco nversion luminescent materials remains a formidable challenge.Herein,we reveal an energy cycling strategy capable of suppressing the inner energy dissipation in lanthanide doped upconversion nanocrystals.Yb^(3+)ions were introduced in Er^(3+)heavily doped nanocrystals as an energy reservoir to compete with the inner energy dissipation.The detailed energy cycling processes between Er^(3+)activator and Yb^(3+)reservoir,responsible for the enhancement of Er^(3+)upconversion intensity,are proposed and further verified on the basis of spectral observations.The energy cycling strategy,with unique merits like facile and cost-effective preparation as well as broad scope of application,is highly valuable in lanthanide luminescent nano materials.展开更多
Introduction:Low energy balance closure(EBC)at a particular eddy-covariance flux site has increased the uncertainties of carbon,water,and energy measurements and has thus hampered the urgent research of scaling up and...Introduction:Low energy balance closure(EBC)at a particular eddy-covariance flux site has increased the uncertainties of carbon,water,and energy measurements and has thus hampered the urgent research of scaling up and modeling analyses through site combinations in regional or global flux networks.Methods:A series of manipulative experiments were conducted in this study to explore the role of net radiation(Rn)in the EBC in relation to spatial variability of vegetation characteristics,source area,and sensor type in three sites of the Inner Mongolian grassland of northern China.Results:At all three sites,the residual fluxes of EBC peaked consistently at 110 W m^(-2).The spatial variability in net radiation was 19 W m^(-2)(5%of R_(n))during the day and 7 W m^(-2)(16%)at night,with an average of 13 W m^(-2)(11%)from eight plot measurements across the three sites.Large area measurements of Rn significantly increased by 9 W m^(-2)during the day and decreased by 4 W m^(-2)at night in the unclipped treatments.Net radiation decreased by 25 W m^(-2)(6%of Rn)at midday and 81 MJ m^(-2)(6%)during a growing season with heavier regular clipping than that in unclipped treatments.The Rn was lower by 11–21 W m^(-2)(~20–40%of Rn)measured by CNR1 than by Q7.1 at night,while there was only 6 W m^(-2)(~1–2%of Rn)difference during the daytime between these two types of commonly used net radiometers.Conclusions:Overall,the inclusion of the uncertainty in available energy accounted for 65%of the~110 W m^(-2)shortfalls in the lack of closure.Clearly,the unclosed energy balance at these three grassland sites remains significant,with unexplored mechanisms for future research.展开更多
基金Project supported by Fundamental Research Funds for the Central Universities(3072021CF2502)Natural Science Foundation of Heilongjiang Province(LH2020A008)+1 种基金Science and Technology Research Program of Chongqing Education Commission of China(KJQN202001420)National College Student Innovation and Entrepreneurship Training Program(202110217224)。
文摘Suppression of the inner energy dissipation,related to the lattice phonons and inner defects,in lanthanide doped upco nversion luminescent materials remains a formidable challenge.Herein,we reveal an energy cycling strategy capable of suppressing the inner energy dissipation in lanthanide doped upconversion nanocrystals.Yb^(3+)ions were introduced in Er^(3+)heavily doped nanocrystals as an energy reservoir to compete with the inner energy dissipation.The detailed energy cycling processes between Er^(3+)activator and Yb^(3+)reservoir,responsible for the enhancement of Er^(3+)upconversion intensity,are proposed and further verified on the basis of spectral observations.The energy cycling strategy,with unique merits like facile and cost-effective preparation as well as broad scope of application,is highly valuable in lanthanide luminescent nano materials.
基金This study was supported by the Natural Science Foundation of China(31170454,31229001,31130202)the State Key Basic Research Development Program of China(2013CB956600)the NASA-NEWS Program(NN-H-04-Z-YS-005-N),and the USCCC。
文摘Introduction:Low energy balance closure(EBC)at a particular eddy-covariance flux site has increased the uncertainties of carbon,water,and energy measurements and has thus hampered the urgent research of scaling up and modeling analyses through site combinations in regional or global flux networks.Methods:A series of manipulative experiments were conducted in this study to explore the role of net radiation(Rn)in the EBC in relation to spatial variability of vegetation characteristics,source area,and sensor type in three sites of the Inner Mongolian grassland of northern China.Results:At all three sites,the residual fluxes of EBC peaked consistently at 110 W m^(-2).The spatial variability in net radiation was 19 W m^(-2)(5%of R_(n))during the day and 7 W m^(-2)(16%)at night,with an average of 13 W m^(-2)(11%)from eight plot measurements across the three sites.Large area measurements of Rn significantly increased by 9 W m^(-2)during the day and decreased by 4 W m^(-2)at night in the unclipped treatments.Net radiation decreased by 25 W m^(-2)(6%of Rn)at midday and 81 MJ m^(-2)(6%)during a growing season with heavier regular clipping than that in unclipped treatments.The Rn was lower by 11–21 W m^(-2)(~20–40%of Rn)measured by CNR1 than by Q7.1 at night,while there was only 6 W m^(-2)(~1–2%of Rn)difference during the daytime between these two types of commonly used net radiometers.Conclusions:Overall,the inclusion of the uncertainty in available energy accounted for 65%of the~110 W m^(-2)shortfalls in the lack of closure.Clearly,the unclosed energy balance at these three grassland sites remains significant,with unexplored mechanisms for future research.