Due to the abundant sodium reserves and high safety,sodium ion batteries(SIBs)are foreseen a promising future.While,hard carbon materials are very suitable for the anode of SIBs owing to their structure and cost advan...Due to the abundant sodium reserves and high safety,sodium ion batteries(SIBs)are foreseen a promising future.While,hard carbon materials are very suitable for the anode of SIBs owing to their structure and cost advantages.However,the unsatisfactory initial coulombic efficiency(ICE)is one of the crucial blemishes of hard carbon materials and the slow sodium storage kinetics also hinders their wide application.Herein,with spherical nano SiO_(2)as pore-forming agent,gelatin and polytetrafluoroethylene as carbon sources,a multi-porous carbon(MPC)material can be easily obtained via a co-pyrolysis method,by which carbonization and template removal can be achieved synchronously without the assistance of strong acids or strong bases.As a result,the MPC anode exhibited remarkable ICE of 83%and a high rate capability(208 m Ah/g at 5 A/g)when used in sodium-ion half cells.Additionally,coupling with Na3V2(PO4)3as the cathode to assemble full cells,the as-fabricated MPC//NVP full cell delivered a good rate capability(146 m Ah/g at 5 A/g)as well,implying a good application prospect the MPC anode has.展开更多
Today, the time-to-market for plastic products ar e getting shorter, thus the lead-time for making the injection mould is decreasin g. There is potential in timesavings in the mould design stage because the design pro...Today, the time-to-market for plastic products ar e getting shorter, thus the lead-time for making the injection mould is decreasin g. There is potential in timesavings in the mould design stage because the design process that is repeatable for every mould design can be standardized. T he preliminary work of any final plastic injection mould design is to always pro vide an initial design of the mould assembly for product designers (customers) p rior to receiving the final product CAD data. Traditionally and even up till no w, this initial design is always created using 2D CAD packages. The information used for the initial design is based on the technical discussion checklist, in which most mould makers have their own standards. This checklist is also being used as a quotation since the most basic information of the mould in the particu lar project is being recorded in it. The basic information in this checklist in cludes the number of cavities, the type of mould base to be used, the moulding m achine to be used for the moulding, the type of gating system, the type of resin material used and its shrinkage value etc. Information on special requirements such as the number of sliders or lifters to be used is also listed in the check list. At this stage, there is still no information on the cooling and ejection design since they are greatly dependent on the final product CAD data. This res earch focuses on the methodology of providing the initial design in 3D solid bas ed on the technical discussion checklist, which takes the role of the overall st andard template since every sub-design has its own standard template. An examp le of a sub-design that has its own standard template is the cavity layout desi gn. The cavity layout for plastic injection moulds can be designed by controlli ng the geometrical parameters using a standardization template. The standardiza tion template for the cavity layout design consists of configurations for the po ssible layouts. Each configuration of the layout design has its own layout des展开更多
基金financially supported by the Start-up Funding of Jinan University(No.88016105)the Discipline Construction Outstanding Young Backbone Project(No.12819023)+3 种基金the Fundamental Research Funds for the Central Universities(No.21620317)the Guangdong Basic and Applied Basic Research Foundation(Nos.2020A1515110611 and 2021A1515010362)the Guangzhou Basic and Applied Basic Research Foundation(No.202102020995)supported by the Open Fund of Guangdong Provincial Key Laboratory of Functional Supramolecular Coordination Materials and Applications(No.2020B121201005)。
文摘Due to the abundant sodium reserves and high safety,sodium ion batteries(SIBs)are foreseen a promising future.While,hard carbon materials are very suitable for the anode of SIBs owing to their structure and cost advantages.However,the unsatisfactory initial coulombic efficiency(ICE)is one of the crucial blemishes of hard carbon materials and the slow sodium storage kinetics also hinders their wide application.Herein,with spherical nano SiO_(2)as pore-forming agent,gelatin and polytetrafluoroethylene as carbon sources,a multi-porous carbon(MPC)material can be easily obtained via a co-pyrolysis method,by which carbonization and template removal can be achieved synchronously without the assistance of strong acids or strong bases.As a result,the MPC anode exhibited remarkable ICE of 83%and a high rate capability(208 m Ah/g at 5 A/g)when used in sodium-ion half cells.Additionally,coupling with Na3V2(PO4)3as the cathode to assemble full cells,the as-fabricated MPC//NVP full cell delivered a good rate capability(146 m Ah/g at 5 A/g)as well,implying a good application prospect the MPC anode has.
文摘Today, the time-to-market for plastic products ar e getting shorter, thus the lead-time for making the injection mould is decreasin g. There is potential in timesavings in the mould design stage because the design process that is repeatable for every mould design can be standardized. T he preliminary work of any final plastic injection mould design is to always pro vide an initial design of the mould assembly for product designers (customers) p rior to receiving the final product CAD data. Traditionally and even up till no w, this initial design is always created using 2D CAD packages. The information used for the initial design is based on the technical discussion checklist, in which most mould makers have their own standards. This checklist is also being used as a quotation since the most basic information of the mould in the particu lar project is being recorded in it. The basic information in this checklist in cludes the number of cavities, the type of mould base to be used, the moulding m achine to be used for the moulding, the type of gating system, the type of resin material used and its shrinkage value etc. Information on special requirements such as the number of sliders or lifters to be used is also listed in the check list. At this stage, there is still no information on the cooling and ejection design since they are greatly dependent on the final product CAD data. This res earch focuses on the methodology of providing the initial design in 3D solid bas ed on the technical discussion checklist, which takes the role of the overall st andard template since every sub-design has its own standard template. An examp le of a sub-design that has its own standard template is the cavity layout desi gn. The cavity layout for plastic injection moulds can be designed by controlli ng the geometrical parameters using a standardization template. The standardiza tion template for the cavity layout design consists of configurations for the po ssible layouts. Each configuration of the layout design has its own layout des
