Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument...Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument for IEERG measurement was developed.Compared with previous setups,the new one which is equipped with three convergent nozzles and quick-release mechanism gets improved in data acquisition and gas sealing and releasing performance.To comprehensively know the effect of gas pressure,particle size,and nozzle area on IEERG,a series of experiments were carried out with this new setup.The variable control test results indicated that the gas pressure-IEERG curves remain the linear trend and the particle size-IEERG curves maintain the negative exponential trend for nozzle areas at 1.13,2.26,and3.39 mm2,respectively.The increase in nozzle area leads to deceases in value of IEERG and absolute value of slope of fitting curves in each test.In addition,the orthogonal experiment showed that the influence of gas pressure,nozzle area,and particle size on IEERG decreases in turn.Only gas pressure had a marked impact on IEERG.This work offers great importance in improving the accuracy of prediction of coal and gas outburst.展开更多
The research purpose is to accurately reveal the temporal and spatial law of the urban expansion of Changsha-Zhuzhou-Xiangtan, one of the seven major urban agglomeration areas in China, and provide decision-making bas...The research purpose is to accurately reveal the temporal and spatial law of the urban expansion of Changsha-Zhuzhou-Xiangtan, one of the seven major urban agglomeration areas in China, and provide decision-making basis for the future urban construction land layout and regional development policy-making. Based on the night lighting data (DMSP/OLS), this paper extracts the boundary of the urban construction land of Changsha-Zhuzhou-Xiangtan urban agglomeration from 1993 to 2017, and quantitatively studies the spatial and temporal characteristics of the expansion of the metropolitan area in the past 25 years according to the methods of spatial expansion analysis, center of gravity migration measurement, landscape pattern index, spatial autocorrelation, etc. The results show that: 1) it is scientific and feasible to extract urban agglomeration construction land by the method of auxiliary data comparison for the study of urban expansion;2) the expansion of regional space in Changsha-Zhuzhou-Xiangtan metropolitan area shows a trend of “weakening first and strengthening later”. The construction land keeps increasing, and the expansion form gradually changes from extensive type to intensive type;3) the center of gravity of the metropolitan area fluctuated and repeated in part during the past 25 years, but it was always located in the municipal district of Changsha city. The eastern region, mainly Changsha city, was still the core area of urban agglomeration expansion;4) strengthening the territorial space protection and control of ecological green core in the metropolitan area is a key measure for the high-quality development of urban agglomeration.展开更多
Electrocatalytic n-valeraldehyde oxidation reaction was an inexpensive and eco-friendly method to control n-valeraldehyde contamination and produce high value-added octane.However,low-cost and readily available electr...Electrocatalytic n-valeraldehyde oxidation reaction was an inexpensive and eco-friendly method to control n-valeraldehyde contamination and produce high value-added octane.However,low-cost and readily available electrocatalysts with high current efficiency were urgently needed.Herein,two-dimensional porous carbon derived from pollen with enlarged interlayer distance was built by alkali activation method,applying in electrocatalytic n-valeraldehyde oxidation reaction.The enlarged interlayer distance was verified by X-ray diffraction(XRD)and high-angle annular dark-field scanning transmission electron microscope(HAADF-STEM).Electrocatalytic experiments consequences showed activated biomass derived carbon possessed a higher electrocatalytic activity and octane selectivity than unactivated catalyst.Systematic tests and in situ infrared experiments demonstrated that enlarged interlayer distance was positively correlated with specific surface area of catalysts,large specific surface area provided abundant absorption sites,facilitated the adsorption for n-valeraldehyde,and further promoted the transformation of n-valeraldehyde to octane.This work also provides a new avenue for creating high-performance electrocatalysts in terms of lattice engineering.展开更多
基金supported by the National Key Scientific Instruments and Equipment Development Projects of China(No.51427804)the National Science Foundation of Shandong Province(No.ZR2017MEE023)。
文摘Coal and gas outburst is a violent disaster driven by released energy from gas desorption.The initial expansion energy of released gas(IEERG)is a new method to predict coal and gas outburst.In this paper,an instrument for IEERG measurement was developed.Compared with previous setups,the new one which is equipped with three convergent nozzles and quick-release mechanism gets improved in data acquisition and gas sealing and releasing performance.To comprehensively know the effect of gas pressure,particle size,and nozzle area on IEERG,a series of experiments were carried out with this new setup.The variable control test results indicated that the gas pressure-IEERG curves remain the linear trend and the particle size-IEERG curves maintain the negative exponential trend for nozzle areas at 1.13,2.26,and3.39 mm2,respectively.The increase in nozzle area leads to deceases in value of IEERG and absolute value of slope of fitting curves in each test.In addition,the orthogonal experiment showed that the influence of gas pressure,nozzle area,and particle size on IEERG decreases in turn.Only gas pressure had a marked impact on IEERG.This work offers great importance in improving the accuracy of prediction of coal and gas outburst.
文摘The research purpose is to accurately reveal the temporal and spatial law of the urban expansion of Changsha-Zhuzhou-Xiangtan, one of the seven major urban agglomeration areas in China, and provide decision-making basis for the future urban construction land layout and regional development policy-making. Based on the night lighting data (DMSP/OLS), this paper extracts the boundary of the urban construction land of Changsha-Zhuzhou-Xiangtan urban agglomeration from 1993 to 2017, and quantitatively studies the spatial and temporal characteristics of the expansion of the metropolitan area in the past 25 years according to the methods of spatial expansion analysis, center of gravity migration measurement, landscape pattern index, spatial autocorrelation, etc. The results show that: 1) it is scientific and feasible to extract urban agglomeration construction land by the method of auxiliary data comparison for the study of urban expansion;2) the expansion of regional space in Changsha-Zhuzhou-Xiangtan metropolitan area shows a trend of “weakening first and strengthening later”. The construction land keeps increasing, and the expansion form gradually changes from extensive type to intensive type;3) the center of gravity of the metropolitan area fluctuated and repeated in part during the past 25 years, but it was always located in the municipal district of Changsha city. The eastern region, mainly Changsha city, was still the core area of urban agglomeration expansion;4) strengthening the territorial space protection and control of ecological green core in the metropolitan area is a key measure for the high-quality development of urban agglomeration.
基金supported by Liaoning Technical Innovation Center of Industrial Ecology and Environmental Engineering,Shandong Provincial Natural Science Foundation(No.ZR2021QB048)Qingdao Postdoctoral Application Research Funded Project(Nos.QDBSH20220201046,QDBSH20230202062)+3 种基金Scientific Research Foundation for Youth Scholars from Qingdao University,National Natural Science Foundation of China(Nos.51473082,51878361)State Key Project of International Cooperation Research(No.2023YFE0201100)the Program for Introducing Talents of Discipline to Universities(“111”plan)the double hundred foreign expert project of Shandong Province,and the high-level discipline program of Materials Science of Shandong Province,China.
文摘Electrocatalytic n-valeraldehyde oxidation reaction was an inexpensive and eco-friendly method to control n-valeraldehyde contamination and produce high value-added octane.However,low-cost and readily available electrocatalysts with high current efficiency were urgently needed.Herein,two-dimensional porous carbon derived from pollen with enlarged interlayer distance was built by alkali activation method,applying in electrocatalytic n-valeraldehyde oxidation reaction.The enlarged interlayer distance was verified by X-ray diffraction(XRD)and high-angle annular dark-field scanning transmission electron microscope(HAADF-STEM).Electrocatalytic experiments consequences showed activated biomass derived carbon possessed a higher electrocatalytic activity and octane selectivity than unactivated catalyst.Systematic tests and in situ infrared experiments demonstrated that enlarged interlayer distance was positively correlated with specific surface area of catalysts,large specific surface area provided abundant absorption sites,facilitated the adsorption for n-valeraldehyde,and further promoted the transformation of n-valeraldehyde to octane.This work also provides a new avenue for creating high-performance electrocatalysts in terms of lattice engineering.
