The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction te...The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction tempera ture （170℃-220℃） and reaction time （150-1800 s） during the hydrolysis process of five kinds of crop straw （rice, wheat, cotton, rape and corn）, the shrinking core model was established, and the differential equation of the model and its analytical solution were obtained. With a numerical calculation method, the kinetic equation was estimated, and the degradation of reducing sugar obeyed firstorder kinetics was obtained. The calculated results from the equations agreed well with the original experimental data. The calculation by the model showed that the reducing sugar concentration increases as the size of the particles decrease, and the uniform particles increase.展开更多
文摘The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid （mass fraction 0.05%） was investigated in this paper. By studying the reducing sugar concentration versus reaction tempera ture （170℃-220℃） and reaction time （150-1800 s） during the hydrolysis process of five kinds of crop straw （rice, wheat, cotton, rape and corn）, the shrinking core model was established, and the differential equation of the model and its analytical solution were obtained. With a numerical calculation method, the kinetic equation was estimated, and the degradation of reducing sugar obeyed firstorder kinetics was obtained. The calculated results from the equations agreed well with the original experimental data. The calculation by the model showed that the reducing sugar concentration increases as the size of the particles decrease, and the uniform particles increase.
