A model for topographic correction and land surface reflectance estimation for optical remote sensing data in rugged terrian is presented.Considering a directional-directional reflectance that is used for direct solar...A model for topographic correction and land surface reflectance estimation for optical remote sensing data in rugged terrian is presented.Considering a directional-directional reflectance that is used for direct solar irradiance correction and a hemispheric-directional reflectance that is used for atmospheric diffuse irradiance and terrain background reflected irradiance correction respectively,the directional reflectance-based model for topographic effects removing and land surface reflectance calculation is developed by deducing the directional reflectance with topographic effects and using a radiative transfer model.A canopy reflectance simulated by GOMS model and Landsat/TM raw data covering Jiangxi rugged area were taken to validate the performance of the model presented in the paper.The validation results show that the model presented here has a remarkable ability to correct topography and estimate land surface reflectance and also provides a technique method for sequently quantitative remote sensing application in terrain area.展开更多
V2O5/TiO2-ZrO2 catalysts containing various amounts of WO3 were synthesized.The catalyst morphologies,catalytic performances,and reaction mechanisms in the selective catalytic reduction of NOx by NH3 were investigated...V2O5/TiO2-ZrO2 catalysts containing various amounts of WO3 were synthesized.The catalyst morphologies,catalytic performances,and reaction mechanisms in the selective catalytic reduction of NOx by NH3 were investigated using in situ diffuse-reflectance infrared Fourier-transform spectroscopy,temperature-programmed reduction（TPR）,X-ray diffraction,and the Brunauer-Emmett-Teller（BET） method.The BET surface area of the triple oxides increased with increasing ZrO2 doping but gradually decreased with increasing WO3 loading.Addition of sufficient WO3 helped to stabilize the pore structure and the combination of WO3 and ZrO2 improved dispersion of all the metal oxides.The mechanisms of reactions using V2O5-9%WO3/TiO2-ZrO2 and V2O5-9%WO3/TiO2were compared by using either a single or mixed gas feed and various pretreatments.The results suggest that both reactions followed the Eley-Ridel mechanism;however,the dominant acid sites,which depended on the addition of WO3 or ZrO2,determined the pathways for NOx reduction,and involved[NH4^＋-NO-Bronsted acid site]^＊ and[NH2-NO-Lewis acid site]^＊ intermediates,respectively.NH3-TPR and H2-TPR showed that the metal oxides in the catalysts were not reduced by NH3 and O2did not reoxidize the catalyst surfaces but participated in the formation of H2O and NO2.展开更多
基金the National Natural Science Foundation of China (Grant No.40730525)Knowledge Innovation Engineering Project of Chinese Academy of Sciences (Grant No.KZCX2-YW-313)China's Special Funds for Major State Basic Research Project (Grant No.2007CB714401)
文摘A model for topographic correction and land surface reflectance estimation for optical remote sensing data in rugged terrian is presented.Considering a directional-directional reflectance that is used for direct solar irradiance correction and a hemispheric-directional reflectance that is used for atmospheric diffuse irradiance and terrain background reflected irradiance correction respectively,the directional reflectance-based model for topographic effects removing and land surface reflectance calculation is developed by deducing the directional reflectance with topographic effects and using a radiative transfer model.A canopy reflectance simulated by GOMS model and Landsat/TM raw data covering Jiangxi rugged area were taken to validate the performance of the model presented in the paper.The validation results show that the model presented here has a remarkable ability to correct topography and estimate land surface reflectance and also provides a technique method for sequently quantitative remote sensing application in terrain area.
基金supported by the National Natural Science Foundation of China(51306034)Key Research&Development Projects of Jiangsu Province(BE2015677)the National Basic Research Program of China(2013CB228505)~~
文摘V2O5/TiO2-ZrO2 catalysts containing various amounts of WO3 were synthesized.The catalyst morphologies,catalytic performances,and reaction mechanisms in the selective catalytic reduction of NOx by NH3 were investigated using in situ diffuse-reflectance infrared Fourier-transform spectroscopy,temperature-programmed reduction（TPR）,X-ray diffraction,and the Brunauer-Emmett-Teller（BET） method.The BET surface area of the triple oxides increased with increasing ZrO2 doping but gradually decreased with increasing WO3 loading.Addition of sufficient WO3 helped to stabilize the pore structure and the combination of WO3 and ZrO2 improved dispersion of all the metal oxides.The mechanisms of reactions using V2O5-9%WO3/TiO2-ZrO2 and V2O5-9%WO3/TiO2were compared by using either a single or mixed gas feed and various pretreatments.The results suggest that both reactions followed the Eley-Ridel mechanism;however,the dominant acid sites,which depended on the addition of WO3 or ZrO2,determined the pathways for NOx reduction,and involved[NH4^＋-NO-Bronsted acid site]^＊ and[NH2-NO-Lewis acid site]^＊ intermediates,respectively.NH3-TPR and H2-TPR showed that the metal oxides in the catalysts were not reduced by NH3 and O2did not reoxidize the catalyst surfaces but participated in the formation of H2O and NO2.
