BaCe0.45Zr0.45M0.1O3-δ （M=Y, In） and BaCe0.9Y0.1O3-δ were prepared through the conventional solid state reaction route. The chemical stability was investigated in hydrogen, carbon dioxide, and boiling water. Cryst...BaCe0.45Zr0.45M0.1O3-δ （M=Y, In） and BaCe0.9Y0.1O3-δ were prepared through the conventional solid state reaction route. The chemical stability was investigated in hydrogen, carbon dioxide, and boiling water. Crystalline phase and microsa-ucture of the proton conductor before and after stability test were measured with X-ray diffraction （XRD） and scanning electron microscopy （SEM）, respectively. The results showed that all materials were quite stable in H2 atmosphere. In CO2 atmosphere, BaCe0.45Zr0.45M0.1O3-δ（M=Y, In） were relatively stable, while Bafe0.9Y0.1O3-δ decomposed. In boiling water, BaCe0.9Y0.1O3-δ was quickly decomposed into Ba（OH）2 and corresponding oxide. BaCe0.45Zr0.45M0.1O3-δ slightly reacted with boiling water and some amorphous phases were formed. However, BaCe0.45Zr0.45In0.1O3-δ was observed to exhibit better stability than BaCe0.45Zr0.45Y0.1O3-δ in water. The experimental results were interpreted in terms of thermodynamic data and tolerance factor.展开更多
将废气再循环(exhaust gas recirculation,EGR)、可变喷嘴涡轮增压器(variable nozzle turbocharger,VNT)与含氧燃料掺烧技术结合,可拓宽EGR的适用工况,提高空燃比,既有助于解决氮氧化物(nitrogen oxides,NOx)与微粒(particulate matter...将废气再循环(exhaust gas recirculation,EGR)、可变喷嘴涡轮增压器(variable nozzle turbocharger,VNT)与含氧燃料掺烧技术结合,可拓宽EGR的适用工况,提高空燃比,既有助于解决氮氧化物(nitrogen oxides,NOx)与微粒(particulate matter,PM)排放的矛盾,也有利于减小海拔上升导致的柴油机性能恶化的程度。选择EGR与VNT耦合的高压共轨柴油机作为研究机型,将生物柴油和生物乙醇按一定比例与柴油混合成生物乙醇柴油(biodiesel-ethanol-diesel,BED)燃料,利用大气模拟系统,在100和80 k Pa的环境下,试验研究VNT与EGR对含氧燃料柴油机动力性、经济性、排放特性的影响规律。结果表明:含氧燃料柴油机的动力性和经济性随着VNT开度和EGR率的增大以及大气压力的降低而变差,在大气压力为80 k Pa、转速为2 200 r/min工况下,VNT开度从22%增大到28%扭矩平均降低3.8 N·m,比油耗平均增加4.2 g/(k W·h),EGR率每增大5%扭矩平均降低0.8 N·m,比油耗平均增加1.5 g/(k W·h),大气压力从100降低至80 k Pa时扭矩平均降低3.4 N·m,比油耗平均增加4.9 g/(k W·h);VNT开度从22%增大到28%时NOx平均减小15%,EGR率每增大5%时NOx排放平均降低12%,大气压力从80增大到100 k Pa时NOx排放平均增加11%;VNT开度从22%增大到28%烟度的平均增幅为175.3%,EGR率每增大5%烟度的平均增幅为331.9%,大气压力从100降低至80 k Pa时烟度的平均增幅为96.6%。展开更多
At seasonal and intraseasonal time scales, polar motions are mainly excited by angular momentum fluctuations due to mass redistributions and relative motions in the atmosphere, oceans, and continental water, snow, and...At seasonal and intraseasonal time scales, polar motions are mainly excited by angular momentum fluctuations due to mass redistributions and relative motions in the atmosphere, oceans, and continental water, snow, and ice, which are usually provided by various global atmospheric, oceanic, and hydrological models（some with meteorological observations assimilated; e.g., NCEP, ECCO, ECMWF, OMCT and LSDM etc.）. Unfortunately, these model outputs are far from perfect and have notable discrepancies with respect to polar motion observations, due to non-uniform distributions of meteorological observatories,as well as theoretical approximations and non-global mass conservation in these models. In this study,the LDC（Least Difference Combination） method is adopted to obtain some improved atmospheric,oceanic, and hydrological/crospheric angular momentum（AAM, OAM and HAM/CAM, respectively）functions and excitation functions（termed as the LDCgsm solutions）. Various GRACE（Gravity Recovery and Climate Experiment） and SLR（Satellite Laser Ranging） geopotential data are adopted to correct the non-global mass conservation problem, while polar motion data are used as general constraints. The LDCgsm solutions can reveal not only periodic fluctuations but also secular trends in AAM, OAM and HAM/CAM, and are in better agreement with polar motion observations, reducing the unexplained excitation to the level of about 5.5 mas（standard derivation value; about 1/5-1/4 of those corresponding to the original model outputs）.展开更多
基金the National Natural Science Foundation of China (50772030, 50572024)
文摘BaCe0.45Zr0.45M0.1O3-δ （M=Y, In） and BaCe0.9Y0.1O3-δ were prepared through the conventional solid state reaction route. The chemical stability was investigated in hydrogen, carbon dioxide, and boiling water. Crystalline phase and microsa-ucture of the proton conductor before and after stability test were measured with X-ray diffraction （XRD） and scanning electron microscopy （SEM）, respectively. The results showed that all materials were quite stable in H2 atmosphere. In CO2 atmosphere, BaCe0.45Zr0.45M0.1O3-δ（M=Y, In） were relatively stable, while Bafe0.9Y0.1O3-δ decomposed. In boiling water, BaCe0.9Y0.1O3-δ was quickly decomposed into Ba（OH）2 and corresponding oxide. BaCe0.45Zr0.45M0.1O3-δ slightly reacted with boiling water and some amorphous phases were formed. However, BaCe0.45Zr0.45In0.1O3-δ was observed to exhibit better stability than BaCe0.45Zr0.45Y0.1O3-δ in water. The experimental results were interpreted in terms of thermodynamic data and tolerance factor.
文摘将废气再循环(exhaust gas recirculation,EGR)、可变喷嘴涡轮增压器(variable nozzle turbocharger,VNT)与含氧燃料掺烧技术结合,可拓宽EGR的适用工况,提高空燃比,既有助于解决氮氧化物(nitrogen oxides,NOx)与微粒(particulate matter,PM)排放的矛盾,也有利于减小海拔上升导致的柴油机性能恶化的程度。选择EGR与VNT耦合的高压共轨柴油机作为研究机型,将生物柴油和生物乙醇按一定比例与柴油混合成生物乙醇柴油(biodiesel-ethanol-diesel,BED)燃料,利用大气模拟系统,在100和80 k Pa的环境下,试验研究VNT与EGR对含氧燃料柴油机动力性、经济性、排放特性的影响规律。结果表明:含氧燃料柴油机的动力性和经济性随着VNT开度和EGR率的增大以及大气压力的降低而变差,在大气压力为80 k Pa、转速为2 200 r/min工况下,VNT开度从22%增大到28%扭矩平均降低3.8 N·m,比油耗平均增加4.2 g/(k W·h),EGR率每增大5%扭矩平均降低0.8 N·m,比油耗平均增加1.5 g/(k W·h),大气压力从100降低至80 k Pa时扭矩平均降低3.4 N·m,比油耗平均增加4.9 g/(k W·h);VNT开度从22%增大到28%时NOx平均减小15%,EGR率每增大5%时NOx排放平均降低12%,大气压力从80增大到100 k Pa时NOx排放平均增加11%;VNT开度从22%增大到28%烟度的平均增幅为175.3%,EGR率每增大5%烟度的平均增幅为331.9%,大气压力从100降低至80 k Pa时烟度的平均增幅为96.6%。
基金supported in parts by the National 973 Project of China(No.2013CB733301 and 2013CB733305)the National Natural Science Foundation of China(No.41474022,41210006 and 41374022)+2 种基金the R&D Special Fund for Public Welfare Industry(Surveying and Mapping,No.201512001)the Fundamental Research Funds for the Central Universities of China(No.2042016kf0146)the China Postdoctoral Science Foundation(No.2014T70737)
文摘At seasonal and intraseasonal time scales, polar motions are mainly excited by angular momentum fluctuations due to mass redistributions and relative motions in the atmosphere, oceans, and continental water, snow, and ice, which are usually provided by various global atmospheric, oceanic, and hydrological models（some with meteorological observations assimilated; e.g., NCEP, ECCO, ECMWF, OMCT and LSDM etc.）. Unfortunately, these model outputs are far from perfect and have notable discrepancies with respect to polar motion observations, due to non-uniform distributions of meteorological observatories,as well as theoretical approximations and non-global mass conservation in these models. In this study,the LDC（Least Difference Combination） method is adopted to obtain some improved atmospheric,oceanic, and hydrological/crospheric angular momentum（AAM, OAM and HAM/CAM, respectively）functions and excitation functions（termed as the LDCgsm solutions）. Various GRACE（Gravity Recovery and Climate Experiment） and SLR（Satellite Laser Ranging） geopotential data are adopted to correct the non-global mass conservation problem, while polar motion data are used as general constraints. The LDCgsm solutions can reveal not only periodic fluctuations but also secular trends in AAM, OAM and HAM/CAM, and are in better agreement with polar motion observations, reducing the unexplained excitation to the level of about 5.5 mas（standard derivation value; about 1/5-1/4 of those corresponding to the original model outputs）.
