The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province...The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO4^2--K^+ type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl^--Na^+/Ca^2+ type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS^- complex in the HTFS, and Au-Cl^- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.展开更多
The Damoqujia gold deposit,discovered recently and located in the north of Zhaoping fault zone,is a large altered rock type deposit.In this paper,we report the preliminary research results of the fluid inclusions and ...The Damoqujia gold deposit,discovered recently and located in the north of Zhaoping fault zone,is a large altered rock type deposit.In this paper,we report the preliminary research results of the fluid inclusions and discuss its metallogenic implications. The homogenization temperatures of fluid inclusions fall into four ranges:310~350℃,230~270℃,160~200℃and 110~150℃; corresponding to the four stages of hydrothermal ore-forming processes:coarse grain pyrite-milk white quartz stage(Ⅰ),smoky gray Au-bearing quartz-fine grain pyrite stage(Ⅱ),Au-bearing polymetallic sulfide-quartz stage(Ⅲ),and quartz-carbonate stage(Ⅳ). Ore-forming fluid is with low salinity and low density,ranging from 1.4 Wt_(NaCl)% to 13.6 Wt_(NaCl)% and from 0.48g/cm^3 to 1.03g/cm^3 respectively.The inclusions are dominated by H_2O and CO_2 in gaseous compositions,and Na^+ and K^+ in positive ions,SO_4^(2-)and Cl^- in negative ions of liquid compositions.Au-S complex is the major form for transportation of gold.The pressure varied from 260MPa to 340MPa during the formation of CO_2-bearing inclusions at the early mineralization;the fluids are rich in SO_4^(2-)and Na^+.The pressure is 26-49×10~5 Pa during the formation of the aqueous salt inclusions in late mineralization,the inclusions are rich in CI^-(F^-), Na^+.δ^(18)O_(qurrtz)is 10.64~12.68%o,and the correspondingδ^(18)O_(H_2)O andδD is-5.44~6.47‰and-95.52~-106.48‰respectively.Based on the studies about compositions and hydrogen and oxygen isotopes of inclusions,it is evidenced that ore-forming fluid is magmatic hydrothermal fluid in early period,but affected by meteoric water in late.展开更多
基金supported by the National Natural Science Foundation of China (Nos. 40672064, 40572063)the 973-Project (No. 2006CB403506)Changjiang Scholars and Innovative Research Team in University and 111 Project of the Ministry of Education, China (No. B07011)
文摘The recently discovered Damoqujia (大磨曲家) gold deposit is a large shear zone-hosted gold deposit of disseminated sulphides located in the north of the Zhaoping (招平) fault zone, Jiaodong (胶东) gold province, China. In order to distinguish the temperature range of cluster inclusions from different mineralization stages and measure their compositions, 16 fluid inclusions and 5 isotopic geochemistry samples were collected for this study. Corresponding to different mineralization stages, the multirange peaks of quartz decrepitation temperature (250-270, 310-360 and 380-430℃) indicate that the activity of ore-forming fluids is characterized by multistage. The ore-forming fluids were predominantly of high-temperature fluid system (HTFS) by CO2-rich, and SO4^2--K^+ type magmatic fluid during the early stage of mineralization and were subsequently affected by low-temperature fluid system (LTFS) of CH4-rich, and Cl^--Na^+/Ca^2+ type meteoric fluid during the late stage of mineralization. Gold is transferred by Au-HS^- complex in the HTFS, and Au-Cl^- complex can be more important in the LTFS. The transition of fluids from deeper to shallow environments results in mixing between the HTFS and LTFS, which might be one of the most key reasons for gold precipitation and large-scale mineralization. The ore-forming fluids are characterized by high-temperature, strong-activity, and superimposed mineralization, so that there is a great probability of forming large and rich ore deposit in the Damoqujia gold deposit. The main bodies are preserved and extend toward deeper parts, thereby suggesting a great potential in future.
基金the National Natural Science Foundation of China (No.40572063 ) the Fostering Plan Fund for Beyond-Century Excellent Talent and the Key Project of Science and Technology Research of the Ministry of Education ( No. 03178) Fund of State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences (No. GPMR0529).
文摘The Damoqujia gold deposit,discovered recently and located in the north of Zhaoping fault zone,is a large altered rock type deposit.In this paper,we report the preliminary research results of the fluid inclusions and discuss its metallogenic implications. The homogenization temperatures of fluid inclusions fall into four ranges:310~350℃,230~270℃,160~200℃and 110~150℃; corresponding to the four stages of hydrothermal ore-forming processes:coarse grain pyrite-milk white quartz stage(Ⅰ),smoky gray Au-bearing quartz-fine grain pyrite stage(Ⅱ),Au-bearing polymetallic sulfide-quartz stage(Ⅲ),and quartz-carbonate stage(Ⅳ). Ore-forming fluid is with low salinity and low density,ranging from 1.4 Wt_(NaCl)% to 13.6 Wt_(NaCl)% and from 0.48g/cm^3 to 1.03g/cm^3 respectively.The inclusions are dominated by H_2O and CO_2 in gaseous compositions,and Na^+ and K^+ in positive ions,SO_4^(2-)and Cl^- in negative ions of liquid compositions.Au-S complex is the major form for transportation of gold.The pressure varied from 260MPa to 340MPa during the formation of CO_2-bearing inclusions at the early mineralization;the fluids are rich in SO_4^(2-)and Na^+.The pressure is 26-49×10~5 Pa during the formation of the aqueous salt inclusions in late mineralization,the inclusions are rich in CI^-(F^-), Na^+.δ^(18)O_(qurrtz)is 10.64~12.68%o,and the correspondingδ^(18)O_(H_2)O andδD is-5.44~6.47‰and-95.52~-106.48‰respectively.Based on the studies about compositions and hydrogen and oxygen isotopes of inclusions,it is evidenced that ore-forming fluid is magmatic hydrothermal fluid in early period,but affected by meteoric water in late.