A kind of efficient non-doped white organic light-emitting diodes(WOLEDs) were realized by using a bright blue-emitting layer of 4,4-bis(2,2-diphenylvinyl)-1,1-biphenyl(DPVBi) combining with red emitting ultrathin lay...A kind of efficient non-doped white organic light-emitting diodes(WOLEDs) were realized by using a bright blue-emitting layer of 4,4-bis(2,2-diphenylvinyl)-1,1-biphenyl(DPVBi) combining with red emitting ultrathin layer of [2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[ij]quinolizin-9-yl)ethenyl]-4H-pyran-4-ylidene]propane-dinitrile(DCM2) and green emitting ultrathin layer of 10-(2-benzothiazolyl)-2,3,6,7-tetrahydro-1,1,7,7-tetramethyl-1H,5H, 11H(1)-benzopyropyrano(6,7-8-i,j)quinolizin-11-one(C545T) with different thicknesses of 0.05 nm, 0.10 nm and 0.20 nm. For comparing, a doped WOLED was also fabricated, in which C545 T and DCM2 are codoped into DPVBi layer to provide blue, green and red emission for obtaining white emission. The maximum luminance and power efficiency of the doped WOLED are 5 765 cd/m^2 at 16 V and 5.23 lm/W at 5 V, respectively, and its Commission Internationale de l'Eclairage(CIE) coordinate changes from(0.393 7, 0.445 3) at 5 V to(0.300 7, 0.373 8) at 12 V. When the thickness of the ultrathin C545 T layer in non-doped WLEDs increases, the emission luminance increases, but all non-doped devices are in the yellow white region. The device with 0.10-nm-thick C545 T has a maximum efficiency of 15.23 cd/A at 8 V and a maximum power efficiency of 6.51 lm/W at 7 V, and its maximum luminance is 10 620 cd/m^2 at 16 V. CIE coordinates of non-doped WLEDs with C545 T thickness of 0.05 nm, 0.10 nm and 0.20 nm are(0.447 3, 0.455 6),(0.464 0, 0.473 1) and(0.458 4, 0.470 0) at 8 V, respectively.展开更多
基金supported by the Major Project of Science and Technology Office of Fujian Province of China(No.2014H0042)the Natural Science Foundation of Fujian Province of China(No.2015J01664)+1 种基金the Project of Science and Technology Research of Quanzhou in Fujian Province of China(Nos.2013Z125 and 2014Z137)the 2016 Annual National or Ministries of the Quanzhou Normal University Prepare Research Foundation Project(No.2016YYKJ21)
文摘A kind of efficient non-doped white organic light-emitting diodes(WOLEDs) were realized by using a bright blue-emitting layer of 4,4-bis(2,2-diphenylvinyl)-1,1-biphenyl(DPVBi) combining with red emitting ultrathin layer of [2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[ij]quinolizin-9-yl)ethenyl]-4H-pyran-4-ylidene]propane-dinitrile(DCM2) and green emitting ultrathin layer of 10-(2-benzothiazolyl)-2,3,6,7-tetrahydro-1,1,7,7-tetramethyl-1H,5H, 11H(1)-benzopyropyrano(6,7-8-i,j)quinolizin-11-one(C545T) with different thicknesses of 0.05 nm, 0.10 nm and 0.20 nm. For comparing, a doped WOLED was also fabricated, in which C545 T and DCM2 are codoped into DPVBi layer to provide blue, green and red emission for obtaining white emission. The maximum luminance and power efficiency of the doped WOLED are 5 765 cd/m^2 at 16 V and 5.23 lm/W at 5 V, respectively, and its Commission Internationale de l'Eclairage(CIE) coordinate changes from(0.393 7, 0.445 3) at 5 V to(0.300 7, 0.373 8) at 12 V. When the thickness of the ultrathin C545 T layer in non-doped WLEDs increases, the emission luminance increases, but all non-doped devices are in the yellow white region. The device with 0.10-nm-thick C545 T has a maximum efficiency of 15.23 cd/A at 8 V and a maximum power efficiency of 6.51 lm/W at 7 V, and its maximum luminance is 10 620 cd/m^2 at 16 V. CIE coordinates of non-doped WLEDs with C545 T thickness of 0.05 nm, 0.10 nm and 0.20 nm are(0.447 3, 0.455 6),(0.464 0, 0.473 1) and(0.458 4, 0.470 0) at 8 V, respectively.
