Two dinuclear organotin complexes C8H14（CO2SnCy3）2（1）（Cy = cyclohexyl group） and C8H14[CO2Sn（CH2CMe2Ph）3]2（2） were synthesized by the reactions of camphoric acid with tricyclohexyltin hydroxide and bis[tri（...Two dinuclear organotin complexes C8H14（CO2SnCy3）2（1）（Cy = cyclohexyl group） and C8H14[CO2Sn（CH2CMe2Ph）3]2（2） were synthesized by the reactions of camphoric acid with tricyclohexyltin hydroxide and bis[tri（2-methyl-2-phenyl）propyltin] oxide under solvothermal conditions, and these complexes were characterized by infrared spectra, elemental analyses, and H NMR spectra. The crystal of 1 belongs to the monoclinic system, space group P21/c with a = 1.83478（19）, b = 1.52707（18）, c = 1.9849（2） nm, β = 122.515（7）°, Z = 4, V = 4.6896（9） nm^3, Dc = 1.324 g/cm^3, μ（MoKα） = 1.103 mm^-1, F（000） = 1952, R = 0.0697 and wR = 0.2040. In addition, thermal stability and quantum chemical calculation of 1 were also studied.展开更多
A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemen...A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.展开更多
A new polymer [Zn2（cam）2（bpmp）]n 1 （H2cam = D-（＋）-camphoric acid, bpmp = bis（4-pyridylmethyl）piperazine） was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, sp...A new polymer [Zn2（cam）2（bpmp）]n 1 （H2cam = D-（＋）-camphoric acid, bpmp = bis（4-pyridylmethyl）piperazine） was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, space group P21/n with a = 12.305（9）, b = 12.945（9）, c = 13.619（10） A, β = 116.833（8）°, V= 1936（2）A3, Z = 4, Mr = 397.76, Dc= 1.365 Mg/m3,μ = 1.292 mm-1, F（000） = 832, the final R = 0.0578 and wR = 0.1678 for 2838 observed reflections with I 〉 2σ（I）. The compound presents a three-dimensional （3D） network extended by homochiral 2D layer and bpmp ligands. From the topology point of view, the structure could be described as a 3D 6-connected mab net with （44.610.8） topology. In addition, infrared spectroscopy, elemental analyses, thermogravimetric analysis and powder X-ray diffraction properties of 1 are also investigated.展开更多
A novel coordination polymer, Mn(H_2O)(CA)(Phen)·H_2O(CA=camphoric acid, Phen=1,10-phenanthroline), was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Six-coordinated {...A novel coordination polymer, Mn(H_2O)(CA)(Phen)·H_2O(CA=camphoric acid, Phen=1,10-phenanthroline), was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Six-coordinated {Mn(Ⅱ)} atoms are linked with carboxyl groups from camphoric acid ligands to form infinite one-dimensional chains. These chains are packed by means of hydrogen bonding and π-π stacking, forming a three-dimensional structure. IR, thermogravimetric analysis and magnetic susceptibility data for Mn(H_2O)(CA)(Phen)·H_2O are given.展开更多
基金Supported by Natural Science Foundation of Hunan Province(No.13JJ3112)Scientific & Technological Projects of Hunan Province(No.2013TZ2025,2014NK3086)+3 种基金Open Foundation of Innovation Platform of Hunan Provincial University(No.13K105,14K014)Scientific & Technological Projects of Hengyang City(No.2012KJ30)Cultivation projects Based on Collaborative Innovation Center of Hengyang Normal University(No.12XT02)the Youth Backbone Teacher Training Program of Hengyang Normal University(2012)
文摘Two dinuclear organotin complexes C8H14（CO2SnCy3）2（1）（Cy = cyclohexyl group） and C8H14[CO2Sn（CH2CMe2Ph）3]2（2） were synthesized by the reactions of camphoric acid with tricyclohexyltin hydroxide and bis[tri（2-methyl-2-phenyl）propyltin] oxide under solvothermal conditions, and these complexes were characterized by infrared spectra, elemental analyses, and H NMR spectra. The crystal of 1 belongs to the monoclinic system, space group P21/c with a = 1.83478（19）, b = 1.52707（18）, c = 1.9849（2） nm, β = 122.515（7）°, Z = 4, V = 4.6896（9） nm^3, Dc = 1.324 g/cm^3, μ（MoKα） = 1.103 mm^-1, F（000） = 1952, R = 0.0697 and wR = 0.2040. In addition, thermal stability and quantum chemical calculation of 1 were also studied.
基金supported by National Natural Science Foundation of China(21401147)Basic Research Program of Natural Science from Shaanxi Provincial Government(2015JQ2032)+2 种基金Scientific Research Program from Education Department of Shaanxi Provincial Government(2013JK0654)Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University(201219)the Program for Distinguished Young Scholars of Xi’an Polytechnic University(201403)
文摘A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.
基金Supported by the National Natural Science Foundation of China(No.21076063)Foundation of Henan Educational Committee(No.13A150244)
文摘A new polymer [Zn2（cam）2（bpmp）]n 1 （H2cam = D-（＋）-camphoric acid, bpmp = bis（4-pyridylmethyl）piperazine） was synthesized under hydrothermal conditions. The compound crystallizes in the monoclinic system, space group P21/n with a = 12.305（9）, b = 12.945（9）, c = 13.619（10） A, β = 116.833（8）°, V= 1936（2）A3, Z = 4, Mr = 397.76, Dc= 1.365 Mg/m3,μ = 1.292 mm-1, F（000） = 832, the final R = 0.0578 and wR = 0.1678 for 2838 observed reflections with I 〉 2σ（I）. The compound presents a three-dimensional （3D） network extended by homochiral 2D layer and bpmp ligands. From the topology point of view, the structure could be described as a 3D 6-connected mab net with （44.610.8） topology. In addition, infrared spectroscopy, elemental analyses, thermogravimetric analysis and powder X-ray diffraction properties of 1 are also investigated.
文摘A novel coordination polymer, Mn(H_2O)(CA)(Phen)·H_2O(CA=camphoric acid, Phen=1,10-phenanthroline), was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Six-coordinated {Mn(Ⅱ)} atoms are linked with carboxyl groups from camphoric acid ligands to form infinite one-dimensional chains. These chains are packed by means of hydrogen bonding and π-π stacking, forming a three-dimensional structure. IR, thermogravimetric analysis and magnetic susceptibility data for Mn(H_2O)(CA)(Phen)·H_2O are given.
