After the oxidation of river and marine sediments with CuO under alkaline conditions, the phenolic compounds in the oxidation products are determined gas chromatographically and compared to that of lignin oxidation pr...After the oxidation of river and marine sediments with CuO under alkaline conditions, the phenolic compounds in the oxidation products are determined gas chromatographically and compared to that of lignin oxidation products. The method of CuO oxidation is compared to that of nitrobenzen. The quantitative determination of produced phenolic compounds by capillary gas chromatography is examined and the blank and repetibility of the method are tested.展开更多
A facile preparation method of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes（HNTs）, was developed. The characterizations of XRD, TEM, SEM, BET, XRF and FT-IR were used to analyze the s...A facile preparation method of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes（HNTs）, was developed. The characterizations of XRD, TEM, SEM, BET, XRF and FT-IR were used to analyze the structure and properties of the nano-CuO/HNT loaded catalyst. The XRD patterns indicated that the CuO nanoparticles on HNTs were monoclinic phase. The TEM-EDX and SEM images confirmed that most of nano-CuO catalysts with the crystal size of ca. 20 nm were assembled into the hollow nanotube of HNTs. The catalytic performance of the nano-CuO/HNT catalysts was evaluated by using selective oxidation of cyclohexene. The reaction temperature and recycling times were investigated. The results reveal that the nano-CuO/HNT catalysts exhibit an excellent catalytic oxidation performance for selective oxidation of cyclohexene to 2-cyclohexene-1-one.展开更多
基金Funded by the State Key Laboratory of Organic Geochemistry,OGL-9026 November 10,1992
文摘After the oxidation of river and marine sediments with CuO under alkaline conditions, the phenolic compounds in the oxidation products are determined gas chromatographically and compared to that of lignin oxidation products. The method of CuO oxidation is compared to that of nitrobenzen. The quantitative determination of produced phenolic compounds by capillary gas chromatography is examined and the blank and repetibility of the method are tested.
基金supported by the Talent Introduction Fund of Yangzhou University, Jiangsu Social Development Project (No. BE2014613)Six Talent Peaks of Jiangsu Province (No. 2014XCL-013)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘A facile preparation method of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes（HNTs）, was developed. The characterizations of XRD, TEM, SEM, BET, XRF and FT-IR were used to analyze the structure and properties of the nano-CuO/HNT loaded catalyst. The XRD patterns indicated that the CuO nanoparticles on HNTs were monoclinic phase. The TEM-EDX and SEM images confirmed that most of nano-CuO catalysts with the crystal size of ca. 20 nm were assembled into the hollow nanotube of HNTs. The catalytic performance of the nano-CuO/HNT catalysts was evaluated by using selective oxidation of cyclohexene. The reaction temperature and recycling times were investigated. The results reveal that the nano-CuO/HNT catalysts exhibit an excellent catalytic oxidation performance for selective oxidation of cyclohexene to 2-cyclohexene-1-one.
