An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies tha...An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement.展开更多
The Eastern Kunlun Orogenic Belt(EKOB)has a complex geological structure and diverse magmatic activities,which are closely related to the Qaidam Basin and the Tethys tectonic evolution.There are at least 3 stages mafi...The Eastern Kunlun Orogenic Belt(EKOB)has a complex geological structure and diverse magmatic activities,which are closely related to the Qaidam Basin and the Tethys tectonic evolution.There are at least 3 stages mafic-ultramafic rocks occurred in the Early Paleozoic in EKOB.The first stage is the Later-Silurian to Early Devonian,represented by the giant Xiarihamu super large magmatic Cu-Ni deposit,containing about 1.18 million metric tons(Mt)of nickel with average grades of 0.65%Ni,and its age of ore-forming pyroxene peridotite is 411 Ma;The second stage is the Early Carboniferous,represented by the large Shitoukengde magmatic Cu-Ni sulfide deposit,and its ore-forming age of the olivine websterite is 334 Ma;The third stage of mafic-ultramafic rocks occurred mainly during the Middle-Late Triassic,represented by Xiaojianshan,Lalinggaoli,and Kaimuqi complexes,and no economical ore bodies have been found in this period.The authors summarized the difference between the ore-bearing and the nonmineralized mafic-ultramafic rocks in the EKOB.The olivine of the ore-bearing complexes contains higher MgO and SiO2 content but lower FeO and CaO contents,and the clinopyroxene of ore-bearing complexes contains lower FeO and CaO contents.Crustal sulfur contamination is key to the formation of the giant Xiarihamu Ni deposit,and crustal sulfur contamination degree of the giant magmatic Ni deposit is higher than that of large Ni deposit.The above indicators could guide the exploration and evaluation of similar deposits in the EKOB.展开更多
The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the thirdlargest magmatic sulfide Ni-Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and ...The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the thirdlargest magmatic sulfide Ni-Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and the border of the deposit becomes more and more important. The ore body, ore and geochemistry characteristics of the concealed Cu-rich ore body are researched. Through spatial analysis and comparison with the neighboring II1 main ore body, the mineralization rule of the concealed Cu-rich ore body is summed up. It is also implied that Cu-rich magma may exist between Nirich magma and ore pulp during liquation differentiation in deep-stage chambers, which derives from deep-mantle Hi-MgO basalt magma. It is concluded that the type of ore body has features of both magmatic liquation and late reconstruction action. It has experienced three stages： deep liquation and pulsatory injection of the Cu- and PPGE-rich magma, concentration of tectonic activation, and the later magma hydrothermal superimposition. In addition, the Pb and S isotopes indicate the magma of I6 concealed Cu-rich ore body originates predominantly from mantle; however, it is interfused by minute crust material. Finally, it is inferred that the genesis of the Cu-Ni sulfide deposit is complex and diverse, and the prospect of seeking new deep ore bodies within similar deposits is promising, especially Cu-rich ore bodies.展开更多
On the basis of the study on the REE geochemistry of the ore minerals and host rocks of the Kalatongke Cu-Ni deposit, Xinjiang, it is indicated that the major ore minerals, sulfides, were sourced from the host mafic-u...On the basis of the study on the REE geochemistry of the ore minerals and host rocks of the Kalatongke Cu-Ni deposit, Xinjiang, it is indicated that the major ore minerals, sulfides, were sourced from the host mafic-ultramafic magma. Characterized by low REE content of sulfide, such a Cu-Ni sulfide deposit occurring in the orogen is obviously different from that on the margin of the craton. Because the mafic-ultramafic rocks from the Cu-Ni sulfide deposit occurring in the orogen is water-rich and the REEs of some sulfides show a particular 'multiple-bending' pattern, which suggests coexistence of multiple liquid phases (fluid and melt), the sulfide melt possibly contains a great deal of hydrothermal fluids and increasingly developed gases and liquid-rich ore-forming fluids after the main metallogenic epoch (magmatic segregation stage).展开更多
Cu-30Ni-xRE （x = 0-0.213） alloys were prepared by a metal mould casting method. The effect of RE on the microstructure and mechanical properties of the alloys was investigated using optical microscope, scanning elec...Cu-30Ni-xRE （x = 0-0.213） alloys were prepared by a metal mould casting method. The effect of RE on the microstructure and mechanical properties of the alloys was investigated using optical microscope, scanning electronic microscope with energy-dispersive spectrometer, X-ray diffraction, and mechanical test. The results show that RE has obvious effect on refining dendrite structure and grain size, as well as on purifying the melting of Cu-30Ni alloy. With the increase of RE content, the ultimate tensile strength, yield strength, and elongation increase at first and then decrease after adding RE more than 0.095 wt.%. Cu-30Ni-0.095RE alloy possesses preferable mechanical properties, i.e., the ultimate tensile strength, yield strength, and elongation are 308 MPa, 125 MPa, and 51.2%, respectively. The microstructure and mechanical properties are worsened with increasing RE content more than 0.095 wt.%. The improvement of mechanical properties of Cu-30Ni-0.095RE alloy is attributed to RE refining microstructure and purifying the matrix.展开更多
There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province （LIP）; namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element （PG...There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province （LIP）; namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element （PGE）-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis （Q-PI-OI-Opx-Cpx system） has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts （including high-Ti, low-Ti and alkali basalts）, respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and low-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limahe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basalts. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.展开更多
Nano- sized and well- dispersed Cu- Ni/La2O3 can be obtained by reduction of LaCu0.2Ni0.8O3 with the structure of perovskite. Using Cu- Ni/La2O3 as cata lyst and C2H2 as carbon source, carbon nanotubes with a high yie...Nano- sized and well- dispersed Cu- Ni/La2O3 can be obtained by reduction of LaCu0.2Ni0.8O3 with the structure of perovskite. Using Cu- Ni/La2O3 as cata lyst and C2H2 as carbon source, carbon nanotubes with a high yield and narrow di ameter distribution can be obtained in the reaction temperature range of 650～ 7 00℃ . Outer diameter of carbon nanotubes rangs from 9nm to 14nm. TG, Raman and XPS analysis indicate that carbon nanotubes prepared by Cu- Ni/La2O3 are relati vely higher in graphitic degree.展开更多
Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effect...Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effective and convenient support for the fabrication of Cu-Ni/GNS bimetal catalyst.展开更多
The 0.4 nm molecular sieve supported Cu-Ni bimetal catalysts for direct synthesis of dimethyl carbonate (DMC) from CO 2 and CH 3 OH were prepared and investigated. The synthesized catalysts were fully characterized by...The 0.4 nm molecular sieve supported Cu-Ni bimetal catalysts for direct synthesis of dimethyl carbonate (DMC) from CO 2 and CH 3 OH were prepared and investigated. The synthesized catalysts were fully characterized by BET, XRD (X-ray diffraction), TPR (temperature programmed reduction), IR (infra-red adsorption), NH 3-TPD (temperature programmed desorption) and CO 2-TPD (temperature programmed desorption) techniques. The results showed that the surface area of catalysts decreased with increasing metal content, and the metals as well as Cu-Ni alloy co-existed on the reduced catalyst surface. There existed interaction between metal and carrier, and moreover, metal particles affected obviously the acidity and basicity of carrier. The large amount of basic sites facilitated the activation of methanol to methoxyl species and their subsequent reaction with activated carbon dioxide. The catalysts were evaluated in a continuous tubular fixed-bed micro-gaseous reactor and the catalyst with bimetal loading of 20% (by mass) had best catalytic activities. Under the conditions of 393 K, 1.1 MPa, 5 h and gas space velocity of 510 h 1 , the selectivity and yield of DMC were higher than 86.0 % and 5.0 %, respectively.展开更多
Cu-Ni alloy nanoparticles were prepared by a microwave combustion method with the molar ratios of CU2＋ to Ni2＋ as 3：7, 4：6, 5：5, 6：4 and 7：3. The as-prepared samples were characterized by XRD, HR-SEM, EDX and V...Cu-Ni alloy nanoparticles were prepared by a microwave combustion method with the molar ratios of CU2＋ to Ni2＋ as 3：7, 4：6, 5：5, 6：4 and 7：3. The as-prepared samples were characterized by XRD, HR-SEM, EDX and VSM. XRD and EDX analyses suggest the formation of pure alloy powders. The average crystallite sizes were found to be in the range of 21.56-33.25 nm. HR-SEM images show the clustered/agglomerated particle-like morphology structure. VSM results reveal that for low Ni content （CusNis, Cu6Ni4 and Cu7Ni3）, the system shows paramagnetic behaviors, whereas for high Ni content （Cu3Ni7 and Cu4Ni6）, it becomes ferromagnetic.展开更多
The most common and serious defect in Cu-Ni alloy casting is porosity. To solve the problem, accurate casting design and proper design of gating system are necessary. It can be predicted and designed by means of compu...The most common and serious defect in Cu-Ni alloy casting is porosity. To solve the problem, accurate casting design and proper design of gating system are necessary. It can be predicted and designed by means of computer simulation of casting solidification. Based on the casting process of the Cu-Ni alloy, the simulation software of diathermanous—flowing—stress coupling ProCAST was used to simulate the Cu-Ni alloy solidification process about the defects and temperature field. By combining experimental results with the simulation results, the quality of casting on some cooling conditions were analyzed. Furthermore, a better cooling condition for solidification process of the Cu-Ni alloy was chosen to improve the quality of the casting. The simulation results indicate that the quality of Cu-Ni alloy casting is the best when it is on the cooling condition of the permanent mold with the insulated riser system.展开更多
Electrochemical studies of the effect of hydrodynamic conditions on corrosion inhibition of Cu-Ni （90/10） alloy in synthetic seawater and sulphide containing synthetic seawater by 1,2,3-benzotriazole （BTAH） are pr...Electrochemical studies of the effect of hydrodynamic conditions on corrosion inhibition of Cu-Ni （90/10） alloy in synthetic seawater and sulphide containing synthetic seawater by 1,2,3-benzotriazole （BTAH） are presented. Impedance, potentiodynamic polarization and cyclic voltammetric （CV） studies are employed in the present investigation. The studies are carried out by using Cu-Ni （90/10） alloy rotating disc electrode at different rotation speeds and at different immersion periods. Reynolds numbers at each rotation speed infer that the flow of seawater is laminar. With increasing rotation speed of the electrode immersed in seawater without sulphide and BTAH, both the charge transfer resistance （Rot） and film resistance （Rf^lm） are increased. However, in the presence of sulphide ions and without BTAH, both the Rot and Rf,m are found to decrease with increasing rotation speed at identical immersion periods. Interestingly, when BTAH is added to seawater or seawater containing sulphide, both the Rot and Rf,m are increased to such a great extent that an inhibition efficiency of 99.99% is obtained. In the presence of BTAH, the phase angle Bode plots are more broadened and the maximum values of phase angle are increased to a value close to 90~ as the rotation speed is increased. The BTAH film is highly protective even under hydrodynamic condition also. Potentiodynamic polarization studies infer that BTAH functions as a mixed inhibitor under hydrodynamic conditions also. CV studies reveal that the protective BTAH film is stable even at anodic potentials of ＋850 mV vs Ag/AgCI.展开更多
A novel solid-liquid interdiffusion(SLID)bonding method with the assistance of temperature gradient(TG)was carried out to bonding Cu and Ni substrates with Sn as interlayer.The element distribution and grain morpholog...A novel solid-liquid interdiffusion(SLID)bonding method with the assistance of temperature gradient(TG)was carried out to bonding Cu and Ni substrates with Sn as interlayer.The element distribution and grain morphology of interfacial intermetallic compound(IMC)in Cu/Sn/Ni micro-joints during both SLID and TG-SLID bonding and in the final Cu/(Cu,Ni)_(6)Sn_(5)/Ni full IMC micro-joints were analyzed.Under the effect of Cu-Ni cross-interaction,interfacial(Cu,Ni)_(6)Sn_(5) dominated the IMC growth at all the interfaces.The morphology of the(Cu,Ni)_(6)Sn_(5) grains was closely related to Ni content with three levels of low,medium and high.The full IMC micro-joints consisted of L-(Cu,Ni)_(6) Sn_(5),M-(Cu,Ni)_(6)Sn_(5) and H-(Cu,Ni)_(6)Sn_(5) grains after SLID bonding or TG-SLID bonding with Ni as hot end,while only L-(Cu,Ni)_(6)Sn_(5) grains after TG-SLID bonding with Cu as hot end,showing that the direction of TG had a remarkably effect on the growth and morphology of the interfacial(Cu,Ni)_(6)Sn_(5) during TG-SLID bonding.Thermodynamic analysis revealed the key molar latent heat and critical Ni content between fine-rounded-like(Cu,Ni)_(6)Sn_(5) and block-like(Cu,Ni)_(6)Sn_(5) were 17,725.4 J and 11.0 at.%at 260℃,respectively.Moreover,the growth kinetic of the interfacial IMC was analyzed in detail during bonding with and without TG.Under the combination of TG and Cu-Ni cross-interaction,void-free full IMC micro-joints were fast formed by TG-SLID bonding with Cu as hot end.This bonding method may present a feasible solution to solve the problems of low formation efficiency and inevitable Cu_(3) Sn growth of full IMC joints for 3 D packaging applications.展开更多
Objective The East Tianshan mafic-ultramafic rocks belt mainly produced in the eastern Jueluotage belt is an important part of the Central Asia Orogenic Belt （CAOB）. The well- known deposits including Huangshan, Hu...Objective The East Tianshan mafic-ultramafic rocks belt mainly produced in the eastern Jueluotage belt is an important part of the Central Asia Orogenic Belt （CAOB）. The well- known deposits including Huangshan, Huangshandong, Tulaergen, Hulu, Xiangshan were have been consecutively discovered in this belt （Duan Xingxing et al., 2016）. The new discovery of the Lubei Cu-Ni sulfide deposit in recent years, which locates in the west of Jueluotage belt, has great significance to the westward extension of the East Tianshan Cu-Ni metallogenic belt. To determine whether the mineralization age of the Lubei Cu-Ni sulfide deposit is consistent with other typical deposits, this study conducted zircon U-Pb geochronology on the diorite from the Lubei Cu-Ni sulfide deposit in order to provide new information for further exploring direction of Cu-Ni prospecting in East Tianshan.展开更多
基金the National Natural Science Foundation of China(No.40172021)the Major State Basic Research Program of the People’s Republic of China(No.G1999043211)the New Round Geological Survey Project (DKD9902001,2001BA609A-07-04).
文摘An isochron age of 282±20 (95% conf. limit) Ma of the sulfide ores in the Huangshandong Cu-Ni sulfide deposit, the East Tianshan Mountains has been obtained through Re-Os isotopic measurement. The age implies that the Cu-Ni sulfide deposit and other related deposits in the same area occurred in a Permian extensional environment of post-collision instead of Devonian-Early Carboniferous ophiolite-related oceanic or island arc environments inferred before. It shares the same ages with the orogenic and epithermal gold deposit systems in the same area. An initial 187Os/188Os ratio of 0.25±0.04 (1σ) and a γos value of 99 on average display the participation of large quantities of crustal components into the rock-forming and ore-forming system during mineralization and magmatic emplacement.
基金This study was financially supported by the Special Fund for Land and Resources Scientific Research of Public Interest(201511020)the Natural Science Foundation of Shaanxi Province(2017JM4002)Natural Science Foundation of China(41873053).
文摘The Eastern Kunlun Orogenic Belt(EKOB)has a complex geological structure and diverse magmatic activities,which are closely related to the Qaidam Basin and the Tethys tectonic evolution.There are at least 3 stages mafic-ultramafic rocks occurred in the Early Paleozoic in EKOB.The first stage is the Later-Silurian to Early Devonian,represented by the giant Xiarihamu super large magmatic Cu-Ni deposit,containing about 1.18 million metric tons(Mt)of nickel with average grades of 0.65%Ni,and its age of ore-forming pyroxene peridotite is 411 Ma;The second stage is the Early Carboniferous,represented by the large Shitoukengde magmatic Cu-Ni sulfide deposit,and its ore-forming age of the olivine websterite is 334 Ma;The third stage of mafic-ultramafic rocks occurred mainly during the Middle-Late Triassic,represented by Xiaojianshan,Lalinggaoli,and Kaimuqi complexes,and no economical ore bodies have been found in this period.The authors summarized the difference between the ore-bearing and the nonmineralized mafic-ultramafic rocks in the EKOB.The olivine of the ore-bearing complexes contains higher MgO and SiO2 content but lower FeO and CaO contents,and the clinopyroxene of ore-bearing complexes contains lower FeO and CaO contents.Crustal sulfur contamination is key to the formation of the giant Xiarihamu Ni deposit,and crustal sulfur contamination degree of the giant magmatic Ni deposit is higher than that of large Ni deposit.The above indicators could guide the exploration and evaluation of similar deposits in the EKOB.
基金supported by the National Science and Technology Support Project of China (No.2006BAB01B08)
文摘The Jinchuan deposit is hosted by the olivine-rich ultramafic rock body, which is the thirdlargest magmatic sulfide Ni-Cu deposit in the world currently being exploited. Seeking new relaying resources in the deep and the border of the deposit becomes more and more important. The ore body, ore and geochemistry characteristics of the concealed Cu-rich ore body are researched. Through spatial analysis and comparison with the neighboring II1 main ore body, the mineralization rule of the concealed Cu-rich ore body is summed up. It is also implied that Cu-rich magma may exist between Nirich magma and ore pulp during liquation differentiation in deep-stage chambers, which derives from deep-mantle Hi-MgO basalt magma. It is concluded that the type of ore body has features of both magmatic liquation and late reconstruction action. It has experienced three stages： deep liquation and pulsatory injection of the Cu- and PPGE-rich magma, concentration of tectonic activation, and the later magma hydrothermal superimposition. In addition, the Pb and S isotopes indicate the magma of I6 concealed Cu-rich ore body originates predominantly from mantle; however, it is interfused by minute crust material. Finally, it is inferred that the genesis of the Cu-Ni sulfide deposit is complex and diverse, and the prospect of seeking new deep ore bodies within similar deposits is promising, especially Cu-rich ore bodies.
基金the National Key Basic Research Program of China(No.2001CB409806).
文摘On the basis of the study on the REE geochemistry of the ore minerals and host rocks of the Kalatongke Cu-Ni deposit, Xinjiang, it is indicated that the major ore minerals, sulfides, were sourced from the host mafic-ultramafic magma. Characterized by low REE content of sulfide, such a Cu-Ni sulfide deposit occurring in the orogen is obviously different from that on the margin of the craton. Because the mafic-ultramafic rocks from the Cu-Ni sulfide deposit occurring in the orogen is water-rich and the REEs of some sulfides show a particular 'multiple-bending' pattern, which suggests coexistence of multiple liquid phases (fluid and melt), the sulfide melt possibly contains a great deal of hydrothermal fluids and increasingly developed gases and liquid-rich ore-forming fluids after the main metallogenic epoch (magmatic segregation stage).
基金supported by the Major State Basic Research Development Program of China (No.2007CB616903)the Cultivation fund of the Key Scientific and Technical Innovation Project+1 种基金the Ministry of Education of China (No.707029)the National Natural Science Foundation of Jiangsu Province,China (No.BK2008317)
文摘Cu-30Ni-xRE （x = 0-0.213） alloys were prepared by a metal mould casting method. The effect of RE on the microstructure and mechanical properties of the alloys was investigated using optical microscope, scanning electronic microscope with energy-dispersive spectrometer, X-ray diffraction, and mechanical test. The results show that RE has obvious effect on refining dendrite structure and grain size, as well as on purifying the melting of Cu-30Ni alloy. With the increase of RE content, the ultimate tensile strength, yield strength, and elongation increase at first and then decrease after adding RE more than 0.095 wt.%. Cu-30Ni-0.095RE alloy possesses preferable mechanical properties, i.e., the ultimate tensile strength, yield strength, and elongation are 308 MPa, 125 MPa, and 51.2%, respectively. The microstructure and mechanical properties are worsened with increasing RE content more than 0.095 wt.%. The improvement of mechanical properties of Cu-30Ni-0.095RE alloy is attributed to RE refining microstructure and purifying the matrix.
基金supported by the National Basic Research Program of China(2009CB421002)National Natural Science Foundation of China(Grant No.40473008,40273020,40572036)+1 种基金Program for New Century Excellent Talents in University(Grant No.NCET-04-0728)Project(B07011)and PCSIRT.
文摘There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province （LIP）; namely, small ultramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element （PGE）-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis （Q-PI-OI-Opx-Cpx system） has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts （including high-Ti, low-Ti and alkali basalts）, respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and low-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limahe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basalts. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.
文摘Nano- sized and well- dispersed Cu- Ni/La2O3 can be obtained by reduction of LaCu0.2Ni0.8O3 with the structure of perovskite. Using Cu- Ni/La2O3 as cata lyst and C2H2 as carbon source, carbon nanotubes with a high yield and narrow di ameter distribution can be obtained in the reaction temperature range of 650～ 7 00℃ . Outer diameter of carbon nanotubes rangs from 9nm to 14nm. TG, Raman and XPS analysis indicate that carbon nanotubes prepared by Cu- Ni/La2O3 are relati vely higher in graphitic degree.
基金The authors would like to thank the Key Research Fund Program of Xihua University(No.Z0910109)for financial support of this researchZ.Guan.thanks National University of Singapore for financial support
文摘Novel graphene nanosheet （GNS） supported Cu-Ni bimetal catalysts were firstly synthesized and used for the direct synthesis of dimethyl carbonate （DMC）. The experimental results demonstrated that GNS was an effective and convenient support for the fabrication of Cu-Ni/GNS bimetal catalyst.
基金Supported by the National High Technology Research and Development Program of China (2008AA03Z3472294,2009AA302410)the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme (2010)+1 种基金the Guangdong Province Sci & Tech Bureau (2006B12401006, 2008A080800024)the Chinese Universities Basic Research Founding
文摘The 0.4 nm molecular sieve supported Cu-Ni bimetal catalysts for direct synthesis of dimethyl carbonate (DMC) from CO 2 and CH 3 OH were prepared and investigated. The synthesized catalysts were fully characterized by BET, XRD (X-ray diffraction), TPR (temperature programmed reduction), IR (infra-red adsorption), NH 3-TPD (temperature programmed desorption) and CO 2-TPD (temperature programmed desorption) techniques. The results showed that the surface area of catalysts decreased with increasing metal content, and the metals as well as Cu-Ni alloy co-existed on the reduced catalyst surface. There existed interaction between metal and carrier, and moreover, metal particles affected obviously the acidity and basicity of carrier. The large amount of basic sites facilitated the activation of methanol to methoxyl species and their subsequent reaction with activated carbon dioxide. The catalysts were evaluated in a continuous tubular fixed-bed micro-gaseous reactor and the catalyst with bimetal loading of 20% (by mass) had best catalytic activities. Under the conditions of 393 K, 1.1 MPa, 5 h and gas space velocity of 510 h 1 , the selectivity and yield of DMC were higher than 86.0 % and 5.0 %, respectively.
文摘Cu-Ni alloy nanoparticles were prepared by a microwave combustion method with the molar ratios of CU2＋ to Ni2＋ as 3：7, 4：6, 5：5, 6：4 and 7：3. The as-prepared samples were characterized by XRD, HR-SEM, EDX and VSM. XRD and EDX analyses suggest the formation of pure alloy powders. The average crystallite sizes were found to be in the range of 21.56-33.25 nm. HR-SEM images show the clustered/agglomerated particle-like morphology structure. VSM results reveal that for low Ni content （CusNis, Cu6Ni4 and Cu7Ni3）, the system shows paramagnetic behaviors, whereas for high Ni content （Cu3Ni7 and Cu4Ni6）, it becomes ferromagnetic.
文摘The most common and serious defect in Cu-Ni alloy casting is porosity. To solve the problem, accurate casting design and proper design of gating system are necessary. It can be predicted and designed by means of computer simulation of casting solidification. Based on the casting process of the Cu-Ni alloy, the simulation software of diathermanous—flowing—stress coupling ProCAST was used to simulate the Cu-Ni alloy solidification process about the defects and temperature field. By combining experimental results with the simulation results, the quality of casting on some cooling conditions were analyzed. Furthermore, a better cooling condition for solidification process of the Cu-Ni alloy was chosen to improve the quality of the casting. The simulation results indicate that the quality of Cu-Ni alloy casting is the best when it is on the cooling condition of the permanent mold with the insulated riser system.
基金Naval Research Board(NRB), Govt.of IndiaRajiv Gandhi National Fellowship(RGNF),UGC,Govt.of India
文摘Electrochemical studies of the effect of hydrodynamic conditions on corrosion inhibition of Cu-Ni （90/10） alloy in synthetic seawater and sulphide containing synthetic seawater by 1,2,3-benzotriazole （BTAH） are presented. Impedance, potentiodynamic polarization and cyclic voltammetric （CV） studies are employed in the present investigation. The studies are carried out by using Cu-Ni （90/10） alloy rotating disc electrode at different rotation speeds and at different immersion periods. Reynolds numbers at each rotation speed infer that the flow of seawater is laminar. With increasing rotation speed of the electrode immersed in seawater without sulphide and BTAH, both the charge transfer resistance （Rot） and film resistance （Rf^lm） are increased. However, in the presence of sulphide ions and without BTAH, both the Rot and Rf,m are found to decrease with increasing rotation speed at identical immersion periods. Interestingly, when BTAH is added to seawater or seawater containing sulphide, both the Rot and Rf,m are increased to such a great extent that an inhibition efficiency of 99.99% is obtained. In the presence of BTAH, the phase angle Bode plots are more broadened and the maximum values of phase angle are increased to a value close to 90~ as the rotation speed is increased. The BTAH film is highly protective even under hydrodynamic condition also. Potentiodynamic polarization studies infer that BTAH functions as a mixed inhibitor under hydrodynamic conditions also. CV studies reveal that the protective BTAH film is stable even at anodic potentials of ＋850 mV vs Ag/AgCI.
基金financially supported by the National Natural Science Foundation of China(No.52075072)the Fundamental Research Funds for the Central Universities(No.DUT20JC46)。
文摘A novel solid-liquid interdiffusion(SLID)bonding method with the assistance of temperature gradient(TG)was carried out to bonding Cu and Ni substrates with Sn as interlayer.The element distribution and grain morphology of interfacial intermetallic compound(IMC)in Cu/Sn/Ni micro-joints during both SLID and TG-SLID bonding and in the final Cu/(Cu,Ni)_(6)Sn_(5)/Ni full IMC micro-joints were analyzed.Under the effect of Cu-Ni cross-interaction,interfacial(Cu,Ni)_(6)Sn_(5) dominated the IMC growth at all the interfaces.The morphology of the(Cu,Ni)_(6)Sn_(5) grains was closely related to Ni content with three levels of low,medium and high.The full IMC micro-joints consisted of L-(Cu,Ni)_(6) Sn_(5),M-(Cu,Ni)_(6)Sn_(5) and H-(Cu,Ni)_(6)Sn_(5) grains after SLID bonding or TG-SLID bonding with Ni as hot end,while only L-(Cu,Ni)_(6)Sn_(5) grains after TG-SLID bonding with Cu as hot end,showing that the direction of TG had a remarkably effect on the growth and morphology of the interfacial(Cu,Ni)_(6)Sn_(5) during TG-SLID bonding.Thermodynamic analysis revealed the key molar latent heat and critical Ni content between fine-rounded-like(Cu,Ni)_(6)Sn_(5) and block-like(Cu,Ni)_(6)Sn_(5) were 17,725.4 J and 11.0 at.%at 260℃,respectively.Moreover,the growth kinetic of the interfacial IMC was analyzed in detail during bonding with and without TG.Under the combination of TG and Cu-Ni cross-interaction,void-free full IMC micro-joints were fast formed by TG-SLID bonding with Cu as hot end.This bonding method may present a feasible solution to solve the problems of low formation efficiency and inevitable Cu_(3) Sn growth of full IMC joints for 3 D packaging applications.
基金supported by the Geological Exploration Foundation Project of Xinjiang(grants No.Y15-1-LQ05 and No.T15-2-LQ13)Special Project of National Geological Mineral Investigation and Evaluation(grant No.DD20160345-04)
文摘Objective The East Tianshan mafic-ultramafic rocks belt mainly produced in the eastern Jueluotage belt is an important part of the Central Asia Orogenic Belt （CAOB）. The well- known deposits including Huangshan, Huangshandong, Tulaergen, Hulu, Xiangshan were have been consecutively discovered in this belt （Duan Xingxing et al., 2016）. The new discovery of the Lubei Cu-Ni sulfide deposit in recent years, which locates in the west of Jueluotage belt, has great significance to the westward extension of the East Tianshan Cu-Ni metallogenic belt. To determine whether the mineralization age of the Lubei Cu-Ni sulfide deposit is consistent with other typical deposits, this study conducted zircon U-Pb geochronology on the diorite from the Lubei Cu-Ni sulfide deposit in order to provide new information for further exploring direction of Cu-Ni prospecting in East Tianshan.
