An amphipathic Schiff base complex with Cu(Ⅱ) was synthesized from p-cresol a nd dodecanoyl chloride with total yield of 36 8%. The structure and amphipathic property of the ligand and Cu complex have been invest iga...An amphipathic Schiff base complex with Cu(Ⅱ) was synthesized from p-cresol a nd dodecanoyl chloride with total yield of 36 8%. The structure and amphipathic property of the ligand and Cu complex have been invest igated. The oxidation of benzyl alcohol catalyzed by the complex in alkali solution gave benzaldehyde in yield of 57 8%.展开更多
Salicylaldehyde thiodiacylhydrazone(STZ), 5-bromosalicylaldehyde thiodiacyl hydrazone(BSTZ) and their Cu(Ⅱ) complexes: STZ(Cu) 2 and BSTZ(Cu) 2 were synthesized. The structures of the ligands and complexes were chara...Salicylaldehyde thiodiacylhydrazone(STZ), 5-bromosalicylaldehyde thiodiacyl hydrazone(BSTZ) and their Cu(Ⅱ) complexes: STZ(Cu) 2 and BSTZ(Cu) 2 were synthesized. The structures of the ligands and complexes were characterized by elemental analysis, IR, 1H NMR and UV spectroscopy. The bacteriostatic test showed that the ligands were more bioactive than the complexes.展开更多
文摘An amphipathic Schiff base complex with Cu(Ⅱ) was synthesized from p-cresol a nd dodecanoyl chloride with total yield of 36 8%. The structure and amphipathic property of the ligand and Cu complex have been invest igated. The oxidation of benzyl alcohol catalyzed by the complex in alkali solution gave benzaldehyde in yield of 57 8%.
文摘Salicylaldehyde thiodiacylhydrazone(STZ), 5-bromosalicylaldehyde thiodiacyl hydrazone(BSTZ) and their Cu(Ⅱ) complexes: STZ(Cu) 2 and BSTZ(Cu) 2 were synthesized. The structures of the ligands and complexes were characterized by elemental analysis, IR, 1H NMR and UV spectroscopy. The bacteriostatic test showed that the ligands were more bioactive than the complexes.
