Shear behavior of granular soil with fines is investigated using the discrete element method (DEM) and particle arrangements and inter-particle contacts during shear are examined. The DEM simulation reveals that fin...Shear behavior of granular soil with fines is investigated using the discrete element method (DEM) and particle arrangements and inter-particle contacts during shear are examined. The DEM simulation reveals that fine particles play a vital role in the overall response of granular soil to shearing. The occurrence of liquefaction and temporary reduction of strength is ascribed mainly to the loss of support from the fine particle contacts (S-S) and fine particle-to-large particle contacts (S-L) as a consequence of the removal of fine particles from the load-carrying skeleton. The dilative strain-hardening response following the strain-softening response is associated with the migration of fine particles back into the load-carrying skeleton, which is thought to enhance the stiffness of the soil skeleton. During shear, the unit normal vector of the large particle-to-large particle (L-L) contact has the strongest fabric anisotropy, and the S-S contact unit normal vector possesses the weakest anisotropy, suggesting that the large particles play a dominant role in carrying the shear load. It is also found that, during shear, fine particles are prone to rolling at contacts while the large particles are prone to sliding, mainly at the S-L and L-L contacts.展开更多
The self-assembly of 1H-benzimidazole-5,6-dicarboxylic acid with barium chloride under hydrothermal conditions afforded a new 2D coordination polymer,[Ba2(L)(HL)Cl]n(1,L = 1H-benzimidazole-5,6-dicarboxylate),whi...The self-assembly of 1H-benzimidazole-5,6-dicarboxylic acid with barium chloride under hydrothermal conditions afforded a new 2D coordination polymer,[Ba2(L)(HL)Cl]n(1,L = 1H-benzimidazole-5,6-dicarboxylate),which was characterized by elemental analysis,infrared spectroscopy,thermogravimetric analysis,and single-crystal X-ray diffraction.Compound 1 is of monoclinic system,space group P21/c with a = 10.0145(6),b=25.6854(15),c=7.3116(4) ?,β = 99.4980(10)°,V = 1854.95(19)3,C18H9Ba2ClN4O8,Z = 4,Mr=719.42,Dc = 2.576 g/cm3,μ(MoKα) = 4.427 mm-1,F(000) = 1352,the final R = 0.0202 and wR=0.0465 for 3051 observed reflections with I 2σ(I).It exhibits an interesting two-dimensional network structure and high thermal stability(up to 420 ℃).展开更多
The purpose of this study was to determine if the Drums Alive Kids Beats intervention could improve behavior in children with developmental delays (DD). The original pilot study that this study on behavior is linked t...The purpose of this study was to determine if the Drums Alive Kids Beats intervention could improve behavior in children with developmental delays (DD). The original pilot study that this study on behavior is linked to is titled, “The Effects of a Drums Alive<sup> </sup>Kids Beats Intervention on the Physical Performance and Motor Skills of Children with Developmental Delays,” which was published in the December edition of the Open Journal of Pediatrics (OJPED, Vol.11 No.4 2021). During the facilitation of said intervention on physical and motor skills, the facilitators noticed unanticipated improvements in behavior, both individually and as a community through better awareness, self-control, self-efficacy, social interaction, and positive energy. Therefore, while maintaining the integrity of the MOT 4 - 6 testing protocols and Drums Alive intervention, a parallel study was conducted to objectively measure six behavioral domains, namely, motivation, impulse control, coordination, concentration, implementation of tasks, and creativity using a self-designed measurement tool with three elements for each domain that was approved by Dr. Heiner Lagenkamp, Department of Sports and Physical Activities, Teaching and Research, Ruhr University, Germany. The 20 participants were German students between 5.10 and 10.2 years of age with no inclusion or exclusion characteristics who were divided into two intervention groups, IG Kindergarten (IG Kinder) and IG Elementary (IG Elem), with varied DD, i.e., transgressive behavior, ADHD, ADD, autism, anger management, visual acuity, self-control, and self-esteem. During the MOT 4 - 6 study and Drums Alive Kids Beats intervention, the facilitators monitored and assessed each participant for pre- and post-performance vis a vis behavior concurrently with physical and motoric skills. As the original study provided statistically significant improvements of between 14% - 24% in physical and motor skill performance with regards to overall scoring and 7 subdivisions of tasks, the results 展开更多
基金the University of Hong Kong for its financial support under the Seed Funding for Basic Research Scheme(20121159028)the National Natural Science Foundation of China(No.51209237)the Fundamental Research Funds for the Central Universities(No.131gpy05)
文摘Shear behavior of granular soil with fines is investigated using the discrete element method (DEM) and particle arrangements and inter-particle contacts during shear are examined. The DEM simulation reveals that fine particles play a vital role in the overall response of granular soil to shearing. The occurrence of liquefaction and temporary reduction of strength is ascribed mainly to the loss of support from the fine particle contacts (S-S) and fine particle-to-large particle contacts (S-L) as a consequence of the removal of fine particles from the load-carrying skeleton. The dilative strain-hardening response following the strain-softening response is associated with the migration of fine particles back into the load-carrying skeleton, which is thought to enhance the stiffness of the soil skeleton. During shear, the unit normal vector of the large particle-to-large particle (L-L) contact has the strongest fabric anisotropy, and the S-S contact unit normal vector possesses the weakest anisotropy, suggesting that the large particles play a dominant role in carrying the shear load. It is also found that, during shear, fine particles are prone to rolling at contacts while the large particles are prone to sliding, mainly at the S-L and L-L contacts.
文摘The self-assembly of 1H-benzimidazole-5,6-dicarboxylic acid with barium chloride under hydrothermal conditions afforded a new 2D coordination polymer,[Ba2(L)(HL)Cl]n(1,L = 1H-benzimidazole-5,6-dicarboxylate),which was characterized by elemental analysis,infrared spectroscopy,thermogravimetric analysis,and single-crystal X-ray diffraction.Compound 1 is of monoclinic system,space group P21/c with a = 10.0145(6),b=25.6854(15),c=7.3116(4) ?,β = 99.4980(10)°,V = 1854.95(19)3,C18H9Ba2ClN4O8,Z = 4,Mr=719.42,Dc = 2.576 g/cm3,μ(MoKα) = 4.427 mm-1,F(000) = 1352,the final R = 0.0202 and wR=0.0465 for 3051 observed reflections with I 2σ(I).It exhibits an interesting two-dimensional network structure and high thermal stability(up to 420 ℃).
文摘The purpose of this study was to determine if the Drums Alive Kids Beats intervention could improve behavior in children with developmental delays (DD). The original pilot study that this study on behavior is linked to is titled, “The Effects of a Drums Alive<sup> </sup>Kids Beats Intervention on the Physical Performance and Motor Skills of Children with Developmental Delays,” which was published in the December edition of the Open Journal of Pediatrics (OJPED, Vol.11 No.4 2021). During the facilitation of said intervention on physical and motor skills, the facilitators noticed unanticipated improvements in behavior, both individually and as a community through better awareness, self-control, self-efficacy, social interaction, and positive energy. Therefore, while maintaining the integrity of the MOT 4 - 6 testing protocols and Drums Alive intervention, a parallel study was conducted to objectively measure six behavioral domains, namely, motivation, impulse control, coordination, concentration, implementation of tasks, and creativity using a self-designed measurement tool with three elements for each domain that was approved by Dr. Heiner Lagenkamp, Department of Sports and Physical Activities, Teaching and Research, Ruhr University, Germany. The 20 participants were German students between 5.10 and 10.2 years of age with no inclusion or exclusion characteristics who were divided into two intervention groups, IG Kindergarten (IG Kinder) and IG Elementary (IG Elem), with varied DD, i.e., transgressive behavior, ADHD, ADD, autism, anger management, visual acuity, self-control, and self-esteem. During the MOT 4 - 6 study and Drums Alive Kids Beats intervention, the facilitators monitored and assessed each participant for pre- and post-performance vis a vis behavior concurrently with physical and motoric skills. As the original study provided statistically significant improvements of between 14% - 24% in physical and motor skill performance with regards to overall scoring and 7 subdivisions of tasks, the results