Soil samples from 4 defined city zones of Nanjing were randomly collected at 0-5 cm and 5-20 cm intervals and size fractions of soil particles were separated from undisturbed bulk soils by low energy dispersion proced...Soil samples from 4 defined city zones of Nanjing were randomly collected at 0-5 cm and 5-20 cm intervals and size fractions of soil particles were separated from undisturbed bulk soils by low energy dispersion procedure. The total contents of Cu and Pb in the different particle size fractions of the urban soils were analyzed by HNO3-HF-HClO4 digestion and flame atomic absorption spectrophotometer determination. The total content of Cu and Pb in soil particle size fractions varied with their size and with city zones as well. Both the content and variation with the size fractions of Pb was bigger than of Cu supporting our previous finding that there was Pb pollution to different degrees in the urban soils although the two elements were generally enriched in clay-sized fraction. Contaminated Pb tended to be preferentially enriched in the size fraction of 2000-250 μm and clay-sized fraction. While the size fractions of the soils from newly developed and preserved area contained smaller amount of Cu and Pb, the partitioning of them in coarse and fine particle size fractions were insignificant compared to that from inner residence and commercial area. The very high Pb level over 150 mg/kg of the fine particle fractions from the soils of the inner city could be a cause of high blood Pb level reported of children from the city as acute exposure to Pb of fine particles of the urban soil might occur by soil ingestion and inhalation by young children. Thus, much attention should be paid to the partitioning of toxic metals in fine soil particles of the urban soils and countermeasures against high health risk of Pb exposure by soil ingestion and dust inhalation should be practiced against the health problem of blood Pb for young children from the cities.展开更多
In this project, we will present the findings of a study using Tensiometer systems designed to investigate the water flow path pattern in shallow vadose zone. The purpose of this paper is to evaluate water flow path i...In this project, we will present the findings of a study using Tensiometer systems designed to investigate the water flow path pattern in shallow vadose zone. The purpose of this paper is to evaluate water flow path in shallow vadose zone and to calculate the infiltration rate and hydraulic conductivity of a soil using Tensiometer. We have measured the subsurface water flow paths in sandy clay loam soil following infiltration experiment using Tensiometers. The matric potential and hydraulic conductivity measurements show that subsequent infiltration and water movement in unsaturated (vadose) zone are vertical, but it can have large lateral component under steady condition. This shows that water moves generally from high water content to lower water content region. Average pressure head for the percolation test conduction locations EB and HB was -30 and -80 cm respectively. Hysteresis produces another interesting situation when the soil is drained. We found that the wetter portion of the soil in vadose zone could be at a lower potential (head) than the dryer portions, resulting in lateral driving force for a preferential flow of water from the dryer to the wet soil. The infiltration rate for the 5 cm ponded water was calculated at 5.45 cm/hr. The infiltration rate curve shows that the rate of infiltration decreases with the time. When infiltration first starts, the wetting front is steep and very close to the surface. Similarly, due to the pressure head gradient, large value for infiltration is recorded. Under these conditions, we believe that the gradient in pressure head is responsible for the rapid movement of water into the dry soil. The effect of gravity is less on water during the initial stages of infiltration;however, it is more effective for preferential flow pattern. In the latter infiltration event, the wetting front has moved deeper into the soil. As a result, the pressure head gradient at the surface is much smaller and consequently has little effect. When the pressure head is equal zero, infiltration展开更多
Dwarka River Basin is one of the fluoride affected river basin in Birbhum, West Bengal. In the present research work, various controlling factors for fluoride contamination in groundwater i.e., geology, aquifer type, ...Dwarka River Basin is one of the fluoride affected river basin in Birbhum, West Bengal. In the present research work, various controlling factors for fluoride contamination in groundwater i.e., geology, aquifer type, groundwater table, soil, rainfall, geomorphology, drainage density, land use land cover, lineament and fault density, slope and elevation were considered to delineate the potential fluoride contamination zones within Dwarka River Basin in Birbhum. Assigning weights and ranks to various inputs factor class and their sub-class respectively was carried out on the basis of knowledge driven method. Weighted overlay analysis was carried out to generate the final potential fluoride contamination zones which are classified into two broad classes i.e., 'high' and 'low', and it is observed that major portion of the study area falls under low fluoride contamination category encompassing 88.61% of the total area which accounts for 759.48 km^2 and high fluoride contaminated region accounts for 11.40% of the total study area encompassing an area of about 97.67 km^2. Majority of high fluoride areas fall along the flood plain of Dwarka River Basin. Finally, for validation 197 reported points within Dwarka having fluoride in underground water are overlaid and an overall accuracy of 92.15% is observed. An accuracy of 83.21% and84.24% is obtained for success and prediction rate curve respectively.展开更多
基金The Key Research Project of Ministry of Education of China(No. 2002012)
文摘Soil samples from 4 defined city zones of Nanjing were randomly collected at 0-5 cm and 5-20 cm intervals and size fractions of soil particles were separated from undisturbed bulk soils by low energy dispersion procedure. The total contents of Cu and Pb in the different particle size fractions of the urban soils were analyzed by HNO3-HF-HClO4 digestion and flame atomic absorption spectrophotometer determination. The total content of Cu and Pb in soil particle size fractions varied with their size and with city zones as well. Both the content and variation with the size fractions of Pb was bigger than of Cu supporting our previous finding that there was Pb pollution to different degrees in the urban soils although the two elements were generally enriched in clay-sized fraction. Contaminated Pb tended to be preferentially enriched in the size fraction of 2000-250 μm and clay-sized fraction. While the size fractions of the soils from newly developed and preserved area contained smaller amount of Cu and Pb, the partitioning of them in coarse and fine particle size fractions were insignificant compared to that from inner residence and commercial area. The very high Pb level over 150 mg/kg of the fine particle fractions from the soils of the inner city could be a cause of high blood Pb level reported of children from the city as acute exposure to Pb of fine particles of the urban soil might occur by soil ingestion and inhalation by young children. Thus, much attention should be paid to the partitioning of toxic metals in fine soil particles of the urban soils and countermeasures against high health risk of Pb exposure by soil ingestion and dust inhalation should be practiced against the health problem of blood Pb for young children from the cities.
文摘In this project, we will present the findings of a study using Tensiometer systems designed to investigate the water flow path pattern in shallow vadose zone. The purpose of this paper is to evaluate water flow path in shallow vadose zone and to calculate the infiltration rate and hydraulic conductivity of a soil using Tensiometer. We have measured the subsurface water flow paths in sandy clay loam soil following infiltration experiment using Tensiometers. The matric potential and hydraulic conductivity measurements show that subsequent infiltration and water movement in unsaturated (vadose) zone are vertical, but it can have large lateral component under steady condition. This shows that water moves generally from high water content to lower water content region. Average pressure head for the percolation test conduction locations EB and HB was -30 and -80 cm respectively. Hysteresis produces another interesting situation when the soil is drained. We found that the wetter portion of the soil in vadose zone could be at a lower potential (head) than the dryer portions, resulting in lateral driving force for a preferential flow of water from the dryer to the wet soil. The infiltration rate for the 5 cm ponded water was calculated at 5.45 cm/hr. The infiltration rate curve shows that the rate of infiltration decreases with the time. When infiltration first starts, the wetting front is steep and very close to the surface. Similarly, due to the pressure head gradient, large value for infiltration is recorded. Under these conditions, we believe that the gradient in pressure head is responsible for the rapid movement of water into the dry soil. The effect of gravity is less on water during the initial stages of infiltration;however, it is more effective for preferential flow pattern. In the latter infiltration event, the wetting front has moved deeper into the soil. As a result, the pressure head gradient at the surface is much smaller and consequently has little effect. When the pressure head is equal zero, infiltration
基金中国科学院优秀博士学位论文院长奖获得者科研启动专项资金(AJ0809xx-035+3 种基金AJ0809xx-036)国家海洋局近岸海域生态环境重点实验室开放基金(200907)The CAS/SAFEA International Partnership Program for Creative ResearchTeams国家自然科学基金(40806048)
基金the DST (project No.SB/ES-687/2013 dated 11.11.2014), India for assisting with the financial supportCentral Ground Water Board+1 种基金Survey of IndiaGeological Survey of India for their help and support
文摘Dwarka River Basin is one of the fluoride affected river basin in Birbhum, West Bengal. In the present research work, various controlling factors for fluoride contamination in groundwater i.e., geology, aquifer type, groundwater table, soil, rainfall, geomorphology, drainage density, land use land cover, lineament and fault density, slope and elevation were considered to delineate the potential fluoride contamination zones within Dwarka River Basin in Birbhum. Assigning weights and ranks to various inputs factor class and their sub-class respectively was carried out on the basis of knowledge driven method. Weighted overlay analysis was carried out to generate the final potential fluoride contamination zones which are classified into two broad classes i.e., 'high' and 'low', and it is observed that major portion of the study area falls under low fluoride contamination category encompassing 88.61% of the total area which accounts for 759.48 km^2 and high fluoride contaminated region accounts for 11.40% of the total study area encompassing an area of about 97.67 km^2. Majority of high fluoride areas fall along the flood plain of Dwarka River Basin. Finally, for validation 197 reported points within Dwarka having fluoride in underground water are overlaid and an overall accuracy of 92.15% is observed. An accuracy of 83.21% and84.24% is obtained for success and prediction rate curve respectively.
