With the sublattice model, equilibrium compositions of ferrite (a) and austenite (7 ) phases, as well as the volume percent of austenite (7) at 780℃ in different TRIP steels were calculated. Concentration profiles of...With the sublattice model, equilibrium compositions of ferrite (a) and austenite (7 ) phases, as well as the volume percent of austenite (7) at 780℃ in different TRIP steels were calculated. Concentration profiles of carbon, Mn, Al and Si in the steels were also estimated under the lattice fixed frame of reference so as to understand the complex mechanical behavior of TRIP steels after different isothermal bainitic transformation treatments. The effect of Si and Mn on transformation induced plasticity (TRIP) was discussed according to thermodynamic and kinetic analyses. It is recognized that Al also induces phase transformation in the steels but its TRIP effect is not as strong as that of Si.展开更多
The calcite dissolution rates at 50-250 ℃ and 20 MPa in deionized water with flow rate varying from 0.2 to 5 mL/min were experimentally measured in a continuous flow column pressure vessel reactor. Equilibrium concen...The calcite dissolution rates at 50-250 ℃ and 20 MPa in deionized water with flow rate varying from 0.2 to 5 mL/min were experimentally measured in a continuous flow column pressure vessel reactor. Equilibrium concentration （Ceq） of calcite dissolution in deionized water at 20 MPa was determined using dissolution data according to the iterative method presented by Jeschke and Dreybrodt. The equilibrium concentrations at 50, 100, 150, 200 and 250 ℃ are 1.84×10^-4, 2.23×10^-4, 2.25×10^-4, 2.31×10^-4 and 2.24×10^-4 mol/L, respectively. The Ceq increases first and then decreases with temperature varying from 50 to 250 ℃ at 20 MPa, and the same variation trend occurs at 10 MPa with lower values. The maximum value （or extremum） of Ceq would increase with temperature at constant pressures. The dissolution reaction of calcite in this experiment is approaching the calcite equilibrium, and the reaction order doesn＇t keep a constant at different temperatures, which could imply that a change of the reac- tion mechanism was occurring. The Arrhenius equation shouldn＇t be used to calculate apparent activation energy using rate constant data at different temperatures when the reaction order or reaction mechanism changed.展开更多
TiClx （x=2.17） was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two para...TiClx （x=2.17） was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two parallel crude titanium plates and one high-purity titanium plate were used as the anode and cathode, respectively. A series of electrochemical tests were performed to investigate the influence of electrolytic parameters on the current efficiency and quality of cathodic products. The results indicated that the quality of cathodic products was related to the current efficiency, which is significantly dependent on the current density and the initial concentration of titanium ions. The significance of this study is the attainment of high-purity titanium with a low oxygen content of 30× 10^-6.展开更多
Elimination of phosphorus vaporizing from silicon was investigated. Si-P alloy made from electronic grade silicon was used. All the samples were analyzed by GD-MS. Theory calculation determines that phosphorus evapora...Elimination of phosphorus vaporizing from silicon was investigated. Si-P alloy made from electronic grade silicon was used. All the samples were analyzed by GD-MS. Theory calculation determines that phosphorus evaporates from molten silicon as gas species P and P2 at a finite reduced pressure. The experimental results show that phosphorus mass fraction can be decreased from 0.046% （460ppmw） to around 0.001% （10ppmw） under the condition of temperature 1 873 K, chamber pressure 0.6-0.8 Pa, holding time 1 h. Both experimental data and calculation results agree that at high phosphorus concentration, phosphorus removal is quite dependent on high chamber pressure while it becomes independent on low chamber pressure. The reason is that phosphorus evaporates from molten silicon as gas species P2 at a relatively high phosphorus concentration, while gas species P will be dominated in its vapour at low phosphorus content.展开更多
Thermodynamic and kinetic study on TRIP （transformation induced plasticity） steels, cemented carbides and mold steel for plastics were carried out in order to design modern advanced materials. With the sublattice mo...Thermodynamic and kinetic study on TRIP （transformation induced plasticity） steels, cemented carbides and mold steel for plastics were carried out in order to design modern advanced materials. With the sublattice model, equilibrium compositions of ferrite and austenite phases in TRIP steels, as well as volume fraction of austenite at inter-critical temperatures for different time were calculated. Concentration profiles of carbon, manganese, aluminum and silicon in the steels were also estimated in the lattice fixed frame of reference. The effect of Si and Mn on TRIP was discussed according to thermodynamic and kinetic analyses. In order to understand and produce the graded nanophase structure of cemented carbides, miscellaneous phases in the M-Co-C （M= Ti, Ta, Nh） systems and Co-V-C system were modeled. Solution parameters and thermodynamic： properties were listed in detail. The improvement of machining behavior of prehardened mould steel for plastics was obtained by computer-aided composition design. The results showed that the matrix composition of large-section prehardened mould steel for plastic markedly influences the precipitation of non-metallic inclusion and the composition control by the aid of Thermo-Calc software package minimizes the amount of detrimental oxide inclusion. In addition, the modification of calcium was optimized in composition design.展开更多
运用GIS空间分析和环境指标测试方法,探讨嵩山周边的颍河上中游地区(龙山晚期,约4.2~4.0 ka B.P.)、双洎河上游地区(新砦时期,约4.0~3.8 ka B.P.)和洛阳盆地的伊河—洛河中游地区(二里头时期,约3.8~3.5 ka B.P.)的3个遗址群的时空特征...运用GIS空间分析和环境指标测试方法,探讨嵩山周边的颍河上中游地区(龙山晚期,约4.2~4.0 ka B.P.)、双洎河上游地区(新砦时期,约4.0~3.8 ka B.P.)和洛阳盆地的伊河—洛河中游地区(二里头时期,约3.8~3.5 ka B.P.)的3个遗址群的时空特征。结果表明:(1)标准差椭圆分析和核密度分析结果显示,颍河上游聚落群和二里头聚落群的空间集聚特征显著,集聚度分别为0.21,0.66;而新砦聚落群的集聚度仅为0.04,聚落呈显著的离散特征。(2)Voronoi资源域分析显示,从龙山晚期到二里头时期聚落的资源域逐渐减小,由6.83 km 2减少至0.36 km 2,表明单位土地的农业效率显著提高。(3)聚落的位序-规模拟合结果显示,颍河上游聚落和二里头聚落的首位度突出,核心聚落规模较大,空间集聚维数大于1,反映两个时期聚落规模的两极分化较为显著。(4)集聚是史前聚落空间均衡的一般模式,随着生产力发展而表现出不同的空间格局。展开更多
基金This work was financially supported by the National Natural Science Foundation of China(No.50171038)the China-Belgium bilateral project(2001-242).
文摘With the sublattice model, equilibrium compositions of ferrite (a) and austenite (7 ) phases, as well as the volume percent of austenite (7) at 780℃ in different TRIP steels were calculated. Concentration profiles of carbon, Mn, Al and Si in the steels were also estimated under the lattice fixed frame of reference so as to understand the complex mechanical behavior of TRIP steels after different isothermal bainitic transformation treatments. The effect of Si and Mn on transformation induced plasticity (TRIP) was discussed according to thermodynamic and kinetic analyses. It is recognized that Al also induces phase transformation in the steels but its TRIP effect is not as strong as that of Si.
基金supported by the National Basic Research Program of China (973 Program) (No. 2009CB421006)the State Key Laboratory of Geological Processes and Mineral Resources (No. GPMR200843)
文摘The calcite dissolution rates at 50-250 ℃ and 20 MPa in deionized water with flow rate varying from 0.2 to 5 mL/min were experimentally measured in a continuous flow column pressure vessel reactor. Equilibrium concentration （Ceq） of calcite dissolution in deionized water at 20 MPa was determined using dissolution data according to the iterative method presented by Jeschke and Dreybrodt. The equilibrium concentrations at 50, 100, 150, 200 and 250 ℃ are 1.84×10^-4, 2.23×10^-4, 2.25×10^-4, 2.31×10^-4 and 2.24×10^-4 mol/L, respectively. The Ceq increases first and then decreases with temperature varying from 50 to 250 ℃ at 20 MPa, and the same variation trend occurs at 10 MPa with lower values. The maximum value （or extremum） of Ceq would increase with temperature at constant pressures. The dissolution reaction of calcite in this experiment is approaching the calcite equilibrium, and the reaction order doesn＇t keep a constant at different temperatures, which could imply that a change of the reac- tion mechanism was occurring. The Arrhenius equation shouldn＇t be used to calculate apparent activation energy using rate constant data at different temperatures when the reaction order or reaction mechanism changed.
基金the National Science Foundation of China(Nos.50934001 and 51322402)the National High-Tech Research and Development Program of China (No.2012AA062302)+2 种基金the Program of the Co-construction with Beijing Municipal Commission of Education of China (Nos.00012047 and 00012085)the Program for New Century Excellent Talents in Universities(NCET-11-0577)the Fundamental Research Funds for the Central Universities(No.FRF-AS-11-003A)
文摘TiClx （x=2.17） was prepared by using titanium sponge to reduce the concentration of TiCl4 in a NaCl-KCl melt under negative pressure. The as-prepared NaCl-KCl-TiClx melt was employed as the electrolyte, and two parallel crude titanium plates and one high-purity titanium plate were used as the anode and cathode, respectively. A series of electrochemical tests were performed to investigate the influence of electrolytic parameters on the current efficiency and quality of cathodic products. The results indicated that the quality of cathodic products was related to the current efficiency, which is significantly dependent on the current density and the initial concentration of titanium ions. The significance of this study is the attainment of high-purity titanium with a low oxygen content of 30× 10^-6.
基金Project (2007J0012) supported by the Natural Science Foundation of Fujian Province, ChinaProject (2007HZ0005-2) supported by the Key Technological Program of Fujian Province, ChinaProject (BASIC-10341702) supported by Norwegian Research Council
文摘Elimination of phosphorus vaporizing from silicon was investigated. Si-P alloy made from electronic grade silicon was used. All the samples were analyzed by GD-MS. Theory calculation determines that phosphorus evaporates from molten silicon as gas species P and P2 at a finite reduced pressure. The experimental results show that phosphorus mass fraction can be decreased from 0.046% （460ppmw） to around 0.001% （10ppmw） under the condition of temperature 1 873 K, chamber pressure 0.6-0.8 Pa, holding time 1 h. Both experimental data and calculation results agree that at high phosphorus concentration, phosphorus removal is quite dependent on high chamber pressure while it becomes independent on low chamber pressure. The reason is that phosphorus evaporates from molten silicon as gas species P2 at a relatively high phosphorus concentration, while gas species P will be dominated in its vapour at low phosphorus content.
文摘Thermodynamic and kinetic study on TRIP （transformation induced plasticity） steels, cemented carbides and mold steel for plastics were carried out in order to design modern advanced materials. With the sublattice model, equilibrium compositions of ferrite and austenite phases in TRIP steels, as well as volume fraction of austenite at inter-critical temperatures for different time were calculated. Concentration profiles of carbon, manganese, aluminum and silicon in the steels were also estimated in the lattice fixed frame of reference. The effect of Si and Mn on TRIP was discussed according to thermodynamic and kinetic analyses. In order to understand and produce the graded nanophase structure of cemented carbides, miscellaneous phases in the M-Co-C （M= Ti, Ta, Nh） systems and Co-V-C system were modeled. Solution parameters and thermodynamic： properties were listed in detail. The improvement of machining behavior of prehardened mould steel for plastics was obtained by computer-aided composition design. The results showed that the matrix composition of large-section prehardened mould steel for plastic markedly influences the precipitation of non-metallic inclusion and the composition control by the aid of Thermo-Calc software package minimizes the amount of detrimental oxide inclusion. In addition, the modification of calcium was optimized in composition design.
文摘运用GIS空间分析和环境指标测试方法,探讨嵩山周边的颍河上中游地区(龙山晚期,约4.2~4.0 ka B.P.)、双洎河上游地区(新砦时期,约4.0~3.8 ka B.P.)和洛阳盆地的伊河—洛河中游地区(二里头时期,约3.8~3.5 ka B.P.)的3个遗址群的时空特征。结果表明:(1)标准差椭圆分析和核密度分析结果显示,颍河上游聚落群和二里头聚落群的空间集聚特征显著,集聚度分别为0.21,0.66;而新砦聚落群的集聚度仅为0.04,聚落呈显著的离散特征。(2)Voronoi资源域分析显示,从龙山晚期到二里头时期聚落的资源域逐渐减小,由6.83 km 2减少至0.36 km 2,表明单位土地的农业效率显著提高。(3)聚落的位序-规模拟合结果显示,颍河上游聚落和二里头聚落的首位度突出,核心聚落规模较大,空间集聚维数大于1,反映两个时期聚落规模的两极分化较为显著。(4)集聚是史前聚落空间均衡的一般模式,随着生产力发展而表现出不同的空间格局。
