Experiments were carried out by adding CaF2 and NaF as catalysts in an Ar atmosphere to study the isothermal reduction kinetics of vanadium titano-magnetite carbon composite pellets under high temperature in the range...Experiments were carried out by adding CaF2 and NaF as catalysts in an Ar atmosphere to study the isothermal reduction kinetics of vanadium titano-magnetite carbon composite pellets under high temperature in the range from 1 473 to 1 673 K. The scanning electron microscope （SEM） was used to characterize the microstructure of product. By analyzing reduction mechanism, it was found that the rate controlling step was gas diffusion, and the activation energy was 178.39 kJ/mol without adding any catalysts. Adding CaF2 or NaF of 3% to vanadium titano-magnetite carbon composite pellets can decrease the apparent activation energy of reduction, and the decrease extent was 14.95 and 15.79 kJ/mol, respectively. In addition, temperature was an important factor influencing on reaction rate.展开更多
Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting...Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting separation mechanism of boron-bearing iron concentrate/coal composite pellet was systematically investigated. The reduction and melting separation test of small size pellet was performed to reveal the evolution of slag and iron in the melting separation process. The isothermal reduction experiment showed the relationship between reduction stage and melting separation stage, and the step reduction and melting separation was perfectly achieved. Coal particles existed through the reduction and melting separation process and finally formed brown residue around the separated product. The pellet could not realize melting separation when the B2O3 content in the concentrate was lower than 6.00 wt%.展开更多
Mass loss and direct reduction characteristics of iron ore-coal composite pellets under different technological parameters were investigated. Meanwhile, changes of iron phase at different temperatures were analyzed by...Mass loss and direct reduction characteristics of iron ore-coal composite pellets under different technological parameters were investigated. Meanwhile, changes of iron phase at different temperatures were analyzed by using X-ray diffraction （XRD）, and characteristics of crushed products were studied by using a scanning electron microscope （SEM）. The results showed that heating rate had little influence on the reduction, but the temperature played an important role in the reduction process. The mass loss rate increased rapidly from 800 to 1 100 ℃. The reduction process can be divided into three steps which correspond to different temperature ranges. Fe2 03 began to transform into Fe304 below 500 ℃, and FeO was reduced into Fe from 900 ℃. At 900 ℃, the reduction product showed a clear porous structure, which promoted the reduction progress. At 1000 ℃, the metallic Fe dominated the sample, and the reduction reached a very high degree.展开更多
基金Item Sponsored by National Key Technology Research and Development Program of China(2008BAB32B05)
文摘Experiments were carried out by adding CaF2 and NaF as catalysts in an Ar atmosphere to study the isothermal reduction kinetics of vanadium titano-magnetite carbon composite pellets under high temperature in the range from 1 473 to 1 673 K. The scanning electron microscope （SEM） was used to characterize the microstructure of product. By analyzing reduction mechanism, it was found that the rate controlling step was gas diffusion, and the activation energy was 178.39 kJ/mol without adding any catalysts. Adding CaF2 or NaF of 3% to vanadium titano-magnetite carbon composite pellets can decrease the apparent activation energy of reduction, and the decrease extent was 14.95 and 15.79 kJ/mol, respectively. In addition, temperature was an important factor influencing on reaction rate.
基金The authors would like to express their gratitude for the financial support of the China Postdoctoral Science Foundation （No. 2016M600919） and National Natural Science Foundation of China （No. 51274033）.
文摘Realizing the boron and iron separation through selective reduction and melting separation of boron-bearing iron con- centrate is of great significance for the utilization of crude ludwigite. The reduction and melting separation mechanism of boron-bearing iron concentrate/coal composite pellet was systematically investigated. The reduction and melting separation test of small size pellet was performed to reveal the evolution of slag and iron in the melting separation process. The isothermal reduction experiment showed the relationship between reduction stage and melting separation stage, and the step reduction and melting separation was perfectly achieved. Coal particles existed through the reduction and melting separation process and finally formed brown residue around the separated product. The pellet could not realize melting separation when the B2O3 content in the concentrate was lower than 6.00 wt%.
基金Sponsored by Fundamental Research Funds for the Central Universities of China(FRF-SD-12-007B)National Science and Technology Support Plan in the 12th Five-year of China(2011BAE13B09)
文摘Mass loss and direct reduction characteristics of iron ore-coal composite pellets under different technological parameters were investigated. Meanwhile, changes of iron phase at different temperatures were analyzed by using X-ray diffraction （XRD）, and characteristics of crushed products were studied by using a scanning electron microscope （SEM）. The results showed that heating rate had little influence on the reduction, but the temperature played an important role in the reduction process. The mass loss rate increased rapidly from 800 to 1 100 ℃. The reduction process can be divided into three steps which correspond to different temperature ranges. Fe2 03 began to transform into Fe304 below 500 ℃, and FeO was reduced into Fe from 900 ℃. At 900 ℃, the reduction product showed a clear porous structure, which promoted the reduction progress. At 1000 ℃, the metallic Fe dominated the sample, and the reduction reached a very high degree.
