A hypercrosslinked polymeric adsorbent （ZH-03） for adsorbing and removing chlorophenolic compounds from their aqueous solutions was studied, including the static adsorption. The equilibrium adsorption data were fit ...A hypercrosslinked polymeric adsorbent （ZH-03） for adsorbing and removing chlorophenolic compounds from their aqueous solutions was studied, including the static adsorption. The equilibrium adsorption data were fit to Freundlich adsorption isothermic models to evaluate the model parameters. Thermodynamic studies on the adsorption of chlorophenolic compounds on ZH-03 indicated that there were chemisorption transitions for 2,4,6-trichlorophenol and physical adsorption processes for 2-chlorophenol and 2,6-chlorophenol, and ZH-03 showed the homogeneous nature of the adsorbent surface. Column adsorption for chlorophenols wastewater shows the advantages of the ZH-03 adsorbent for adsorbing the following chlorophenolic compounds as 2-chlorophenol, 2,6-dichlorophenol and 2,4,6-trichlorophenol. Sodium hydroxide was used for desorpting chlorophenols from ZH-03 and showed excellent performance.展开更多
Laboratory bleaching effluents from the chlorination and caustic extraction stages of mixed wood kraft pulp processing have been analysed both qualitatively and quantitatively for various chlorophenolics by using GC.A...Laboratory bleaching effluents from the chlorination and caustic extraction stages of mixed wood kraft pulp processing have been analysed both qualitatively and quantitatively for various chlorophenolics by using GC.A number of chlorinated derivaties of phenols,catechols,guaiacols and syringaldehydes have been detected and their concentrations are estimated.The results are compared with that of different agriculture residue/hardwood pulps,which were reported in literature.The concentrations of various compounds detected have also been compared with their reported 96LC50 values.展开更多
The determination of 2 chlorophenol, 24 dichlorophenol, 2,3,4 trichlorophenol, 2,3,4,6 tetrachlorophenol and pentachlorophenol in the water environment was studied by the high performance liquid chromatography with ...The determination of 2 chlorophenol, 24 dichlorophenol, 2,3,4 trichlorophenol, 2,3,4,6 tetrachlorophenol and pentachlorophenol in the water environment was studied by the high performance liquid chromatography with solid phase extraction in this paper.展开更多
基金This work was funded by the Educational Bureau of Jiangsu Province, China (Grant Code 04KJB150153 and 05KJD610250).
文摘A hypercrosslinked polymeric adsorbent （ZH-03） for adsorbing and removing chlorophenolic compounds from their aqueous solutions was studied, including the static adsorption. The equilibrium adsorption data were fit to Freundlich adsorption isothermic models to evaluate the model parameters. Thermodynamic studies on the adsorption of chlorophenolic compounds on ZH-03 indicated that there were chemisorption transitions for 2,4,6-trichlorophenol and physical adsorption processes for 2-chlorophenol and 2,6-chlorophenol, and ZH-03 showed the homogeneous nature of the adsorbent surface. Column adsorption for chlorophenols wastewater shows the advantages of the ZH-03 adsorbent for adsorbing the following chlorophenolic compounds as 2-chlorophenol, 2,6-dichlorophenol and 2,4,6-trichlorophenol. Sodium hydroxide was used for desorpting chlorophenols from ZH-03 and showed excellent performance.
文摘Laboratory bleaching effluents from the chlorination and caustic extraction stages of mixed wood kraft pulp processing have been analysed both qualitatively and quantitatively for various chlorophenolics by using GC.A number of chlorinated derivaties of phenols,catechols,guaiacols and syringaldehydes have been detected and their concentrations are estimated.The results are compared with that of different agriculture residue/hardwood pulps,which were reported in literature.The concentrations of various compounds detected have also been compared with their reported 96LC50 values.
文摘The determination of 2 chlorophenol, 24 dichlorophenol, 2,3,4 trichlorophenol, 2,3,4,6 tetrachlorophenol and pentachlorophenol in the water environment was studied by the high performance liquid chromatography with solid phase extraction in this paper.
基金supported by Jiangsu Province Institution of Higher Learning Natural Science Foundation (No.05KJDl50221)Xuzhou Normal University Natural Science Education Foundation (No.05PLY04).
