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三种南方典型水稻土长期试验下有机碳积累机制研究 Ⅲ.两种水稻土颗粒有机质结构特征的变化 被引量:29
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作者 周萍 Alessandro Piccolo +1 位作者 潘根兴 Daniela Smejkalova 《土壤学报》 CAS CSCD 北大核心 2009年第3期398-405,共8页
采用固体交叉极化魔角自旋^(13)C核磁共振(CPMAS^(13)C-NMR)波谱技术对长期不同施肥处理下红壤性水稻土和太湖地区黄泥土本体土壤以及水稳性团聚体中颗粒有机质(POM)的化学结构特征进行了研究。结果表明,不同施肥处理下本体土壤和不同... 采用固体交叉极化魔角自旋^(13)C核磁共振(CPMAS^(13)C-NMR)波谱技术对长期不同施肥处理下红壤性水稻土和太湖地区黄泥土本体土壤以及水稳性团聚体中颗粒有机质(POM)的化学结构特征进行了研究。结果表明,不同施肥处理下本体土壤和不同粒径水稳性团聚体中POM的结构组成相似,主要由烷氧C、烷基C和芳香C组成,其中以烷氧C含量最高。施肥改变了本体土壤POM中各类C原子的相对百分含量,有机肥以及化肥配施有机肥条件下烷氧C含量明显降低,芳香C和酚基C含量有不同程度的增加,表明POM的稳定性增强;单施化肥下烷氧C含量最高,而烷基C、芳香C和芳香度均最低,POM的稳定性减弱,不利于POM的积累。施肥改变了黄泥土不同粒径水稳性团聚体中POM各类C原子的相对百分含量,从而使得不同粒径中POM对其团聚体的稳定性作用发生变化;而红壤性水稻土不同粒径水稳性团聚体POM各类C原子的相对百分含量并未明显受到施肥措施的影响。 展开更多
关键词 水稻土 颗粒有机质 结构特征 cpmas ~13c-nmr 施肥
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Changes in soil organic carbon contents and fractionations of forests along a climatic gradient in China 被引量:4
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作者 Xiaolu Sun Zuoxin Tang +2 位作者 Michael G.Ryan Yeming You Osbert Jianxin Sun 《Forest Ecosystems》 SCIE CSCD 2019年第1期1-12,共12页
Background: Soil organic carbon(SOC) is a large reservoir of terrestrial carbon(C); it consists of different fractions of varying complexity and stability. Partitioning SOC into different pools of decomposability help... Background: Soil organic carbon(SOC) is a large reservoir of terrestrial carbon(C); it consists of different fractions of varying complexity and stability. Partitioning SOC into different pools of decomposability help better predict the trend of changes in SOC dynamics under climate change. Information on how physical fractions and chemical structures of SOC are related to climate and vegetation types is essential for spatial model ing of SOC processes and responses to global change factors.Method: Soil samples were col ected from multiple representative forest sites of three contrasting climatic zones(i.e. cool temperate, warm temperate, and subtropical) in eastern China. Measurements were made on SOC contents and physical fractions of the 0–20 cm soil layer, and the chemical composition of SOC of the 0–5 cm soil layer, along with measurements and compilation of the basic site and forest stand variables. The long-term effects of temperature, litter inputs, soil characteristics and vegetation type on the SOC contents and factions were examined by means of "space for time substitution" approach and statistical analysis.Result: Mean annual temperature(MAT) varied from 2.1 °C at the cool temperate sites to 20.8 °C at the subtropical sites. Total SOC of the 0–20 cm soil layer decreased with increasing MAT, ranging from 89.2 g·kg^(-1) in cool temperate forests to 57.7 g·kg^(-1) in subtropical forests, at an average rate of 1.87% reduction in SOC with a 1 °C increase in MAT.With increasing MAT, the proportions of aromatic C and phenolic C displayed a tendency of decreases, whereas the proportion of alkyl C and A/O-A value(the ratio of alkyl C to the sum of O-alkyl C and acetal C) displayed a tendency of increases. Overall, there were no significant changes with MAT and forest type in either the physical fractions or the chemical composition. Based on the relationship between the SOC content and MAT, we estimate that SOC in the top 20 soil layer of forests potentially contribute 6.58–26.3 Pg C globally to t 展开更多
关键词 carb on FRAcTIONS FOREST soil Global WARMING SOLID-STATE 13c-cpmas nmr
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