Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including ...Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including the upper reaches of the Huangpu River and the rivers in the Chongming Island. The results show that the CH4 concentration in river water ranged from 0.30±0.03 to 6.66±0.14 μmol.L-1, and N2O concentration ranged from 13.8±2.33 to 435±116 nmol.L-1. River surface water had a very high satura- tion level of CH4 (from 468±49.0% to 11560±235%) and that of N2O (from 175±29.5% to 4914±1304%). Dissolved oxygen (DO) was the primary factor controlling the CH4 concentration in water. N2O concentration had significant negative correlation with salinity and a significant positive correlation with nitrate (NO3-), nitrite (NO2-), chemical oxygen demand (CODcr) concentration and pH of river water. CH4 and N2O of river water were brought about mainly by methanogenesis and denitrification in river bottom sediment that diffused through sediment-water interface into the water body and then into atmosphere through the gas-water interface. The emission flux of CH4 and N2O at river gas-water interface reached 778±59.8 and 236±63.6 μmol.m-2.h-1, respectively in summer. The river net was a potential source of atmospheric CH4 and N2O because of eutrophication of the water body.展开更多
The fluxes of CO2 and CH4 emission of the two types of primary swamp were measured in Sanjiang Plain using the opaque chamber and gas chromatogram technique. The mean value of ecosystem respiration flux in continuousl...The fluxes of CO2 and CH4 emission of the two types of primary swamp were measured in Sanjiang Plain using the opaque chamber and gas chromatogram technique. The mean value of ecosystem respiration flux in continuously inundated swamp ecosystem is 548.04 mg·m-2·h-1, lower than that of the seasonal inundated swamp (713.08 mg· m-2·h-1). The peaks concentrated on July and August which are the growing period of the vegetation. CH4 emission was different from the respiration flux of ecosystem. The CH4 flux of continuously inundated swamp was 12.80 mg·m-2· h-1, larger than that of the seasonal inundated swamp (8.56 mg·m-2·h-1), and they were varied at different periods, the continuously inundated swamp emitted CH4 mainly from July to September, whereas from last August to middle Sep-tember in the seasonal inundated swamp. The ecosystem respiration flux of the swamp has the significantly positive correlation with the soil temperature (0—10 cm depth) and the water temperature, but CH4 emission was associated with the soil temperature in a certain degree. The CH4 emission from swamp depends on the integral function of water table and soil temperature.展开更多
The static closed chamber technique is used in the study on the CH4 and N2O fluxes from the soils of primeval Abies fabri forest, the succession Abies fabri forest and the clear-cut areas of mid-aged Abies fabri fores...The static closed chamber technique is used in the study on the CH4 and N2O fluxes from the soils of primeval Abies fabri forest, the succession Abies fabri forest and the clear-cut areas of mid-aged Abies fabri forest in the Gongga Mountain from May 1998 to September 1999. The results indicate the following: (i) The forest soil serves as the source of atmospheric N2O at the three measurement sites, while the fluxes of CH4 are all negative, and soil is the sink of atmospheric CH4. The comparative relations of N2O emissions between the three sites are expressed as primeval Abies fabri forest > clear-cut areas > succession Abies fabri forest, and those of CH4 consumption fluxes are primeval Abies fabri forest > succession Abies fabri forest > clear-cut areas. (ii) Signifi-cant seasonal variations of N2O emission at various sites were observed, and two emission peaks of N2O occurr during summer (July—August) and spring (February—March), whereas N2O emission is relatively low in winter and spring (mid March—April). Seasonal variations of CH4 consumption at each measurement site fluctuate drastically with unclear regularities. Generally, CH4 consumption fluxes of succession Abies fabri forest and clear-cut areas are higher from mid May to late July but lower in the rest of sampling time, while the CH4 flux keeps a relatively high value even up to Sep-tember in primeval Abies fabri forest. In contrast to primeval Abies fabri forest, the CH4 absorbabili-ties of succession Abies fabri forest and clear-cut areas of mid-aged Abies fabri forest are weaker. Particularly, the absorbability of the clear-cut areas is even weaker as compared with the other two sites, for the deforestation reduces the soil absorbability of atmospheric CH4. (iii) Evident diurnal variation regularity exists in the N2O emissions of primeval Abies fabri forest, and there is a statistic positive correlation between the fluxes of N2O and air temperature (R=0.95, n=11, <0.01), and also the soil temperature of 5-cm layer (R=0.81, n=11, < 0.01), whe展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 40730526)the Science & Technology Department of Shanghai (Grant No. 07DZ12037)+1 种基金the National Great Water Issue Project of China (Grant No. 2008ZX07317-006)China Postdoctoral Science Foundation (Grant No. 20060400635)
文摘Methane (CH4) and nitrous oxide (N2O) saturation concentration and gas-water interface emission flux in surface water of the Yangtze Delta plain river net were investigated in summer at representative sites including the upper reaches of the Huangpu River and the rivers in the Chongming Island. The results show that the CH4 concentration in river water ranged from 0.30±0.03 to 6.66±0.14 μmol.L-1, and N2O concentration ranged from 13.8±2.33 to 435±116 nmol.L-1. River surface water had a very high satura- tion level of CH4 (from 468±49.0% to 11560±235%) and that of N2O (from 175±29.5% to 4914±1304%). Dissolved oxygen (DO) was the primary factor controlling the CH4 concentration in water. N2O concentration had significant negative correlation with salinity and a significant positive correlation with nitrate (NO3-), nitrite (NO2-), chemical oxygen demand (CODcr) concentration and pH of river water. CH4 and N2O of river water were brought about mainly by methanogenesis and denitrification in river bottom sediment that diffused through sediment-water interface into the water body and then into atmosphere through the gas-water interface. The emission flux of CH4 and N2O at river gas-water interface reached 778±59.8 and 236±63.6 μmol.m-2.h-1, respectively in summer. The river net was a potential source of atmospheric CH4 and N2O because of eutrophication of the water body.
基金supported by the Knowledge Innovation Program of the Chinese Academy of Sciences(Grant Nos.KZCX1-SW-01 and KZCX3-SW-332)the LAPC National Lab of Institute of Atmosphere Physics,the Chinese Academy of Sciences
文摘The fluxes of CO2 and CH4 emission of the two types of primary swamp were measured in Sanjiang Plain using the opaque chamber and gas chromatogram technique. The mean value of ecosystem respiration flux in continuously inundated swamp ecosystem is 548.04 mg·m-2·h-1, lower than that of the seasonal inundated swamp (713.08 mg· m-2·h-1). The peaks concentrated on July and August which are the growing period of the vegetation. CH4 emission was different from the respiration flux of ecosystem. The CH4 flux of continuously inundated swamp was 12.80 mg·m-2· h-1, larger than that of the seasonal inundated swamp (8.56 mg·m-2·h-1), and they were varied at different periods, the continuously inundated swamp emitted CH4 mainly from July to September, whereas from last August to middle Sep-tember in the seasonal inundated swamp. The ecosystem respiration flux of the swamp has the significantly positive correlation with the soil temperature (0—10 cm depth) and the water temperature, but CH4 emission was associated with the soil temperature in a certain degree. The CH4 emission from swamp depends on the integral function of water table and soil temperature.
基金This work was supported by the National Natural Sciences Foundation of China (Grant No. 49971005) and the Key Innovational Program of Chinese Academy of Sciences (Grant No. KZCX1-SW-01-04) together with the Innovational Project of the Institute of Geogra
文摘The static closed chamber technique is used in the study on the CH4 and N2O fluxes from the soils of primeval Abies fabri forest, the succession Abies fabri forest and the clear-cut areas of mid-aged Abies fabri forest in the Gongga Mountain from May 1998 to September 1999. The results indicate the following: (i) The forest soil serves as the source of atmospheric N2O at the three measurement sites, while the fluxes of CH4 are all negative, and soil is the sink of atmospheric CH4. The comparative relations of N2O emissions between the three sites are expressed as primeval Abies fabri forest > clear-cut areas > succession Abies fabri forest, and those of CH4 consumption fluxes are primeval Abies fabri forest > succession Abies fabri forest > clear-cut areas. (ii) Signifi-cant seasonal variations of N2O emission at various sites were observed, and two emission peaks of N2O occurr during summer (July—August) and spring (February—March), whereas N2O emission is relatively low in winter and spring (mid March—April). Seasonal variations of CH4 consumption at each measurement site fluctuate drastically with unclear regularities. Generally, CH4 consumption fluxes of succession Abies fabri forest and clear-cut areas are higher from mid May to late July but lower in the rest of sampling time, while the CH4 flux keeps a relatively high value even up to Sep-tember in primeval Abies fabri forest. In contrast to primeval Abies fabri forest, the CH4 absorbabili-ties of succession Abies fabri forest and clear-cut areas of mid-aged Abies fabri forest are weaker. Particularly, the absorbability of the clear-cut areas is even weaker as compared with the other two sites, for the deforestation reduces the soil absorbability of atmospheric CH4. (iii) Evident diurnal variation regularity exists in the N2O emissions of primeval Abies fabri forest, and there is a statistic positive correlation between the fluxes of N2O and air temperature (R=0.95, n=11, <0.01), and also the soil temperature of 5-cm layer (R=0.81, n=11, < 0.01), whe
