In order to reduce the curing temperature, shorten the curing time of phenol-formaldehyde(PF) resin adhesive, and ensure the good water-solubility, NaOH and Ba(OH)_2 were used as compound catalysts. The influences of ...In order to reduce the curing temperature, shorten the curing time of phenol-formaldehyde(PF) resin adhesive, and ensure the good water-solubility, NaOH and Ba(OH)_2 were used as compound catalysts. The influences of the adding time of Ba(OH)_2, the adding amount of NaOH, Ba(OH)_2 and resorcinol on the properties of adhesives were studied. The properties of NaOH catalyzed phenol-formaldehyde(PF) adhesive, NaOH and Ba(OH)_2 compound catalyzed PF adhesive, NaOH and Ba(OH)_2 compound catalyzed phenol-resorcinol-formaldehyde(PRF) adhesive, and the prepared recombinant bamboo with three kinds of adhesives were compared. The experimental results show that NaOH and Ba(OH)_2 compound catalyst not only shortens the curing time of PF adhesive, but also guarantees the suitable water solubility of adhesive. After copolycondensation with resorcinol, the curing time of adhesive is further shortened, the water solubility is improved obviously, and the highest bonding strength is obtained. Infrared spectrum analysis shows that the reaction activity point of NaOH and Ba(OH)_2 compound catalyzed PRF adhesive will increase, so that both the curing temperature and curing enthalpy decrease.展开更多
设计了一种具有辅助电加热和均流孔板的水/相变材料复合蓄热式水箱,该水箱以封装有复合八水氢氧化钡的相变蓄热球作为储热单元。理论分析了相变蓄热球应用于复合蓄热式水箱中的可行性,实验研究了水箱中有无相变蓄热球、恒定流量下的直...设计了一种具有辅助电加热和均流孔板的水/相变材料复合蓄热式水箱,该水箱以封装有复合八水氢氧化钡的相变蓄热球作为储热单元。理论分析了相变蓄热球应用于复合蓄热式水箱中的可行性,实验研究了水箱中有无相变蓄热球、恒定流量下的直接和恒温蓄放热特性,结果表明:均流孔板的应用,可使冷热水在水箱底部均匀混合,使高温热水出水量达到最大;在热水出水流量为3.3 L/min时,添加60个相变蓄热球的复合蓄热式水箱比纯水箱可多制得10 L 60℃以上的热水;在热水出水流量为1.6 L/min时,添加120个相变蓄热球的复合蓄热式水箱比纯水箱可多制得40 L 40℃的恒温热水。展开更多
基金Funded by the China Postdoctoral Science Foundation Funded Project(2015M572276)the Natural Science Foundation of Hunan Province,China(2016JJ3184)the Hunan Major Science and Technology Projects(2011FJ1006)
文摘In order to reduce the curing temperature, shorten the curing time of phenol-formaldehyde(PF) resin adhesive, and ensure the good water-solubility, NaOH and Ba(OH)_2 were used as compound catalysts. The influences of the adding time of Ba(OH)_2, the adding amount of NaOH, Ba(OH)_2 and resorcinol on the properties of adhesives were studied. The properties of NaOH catalyzed phenol-formaldehyde(PF) adhesive, NaOH and Ba(OH)_2 compound catalyzed PF adhesive, NaOH and Ba(OH)_2 compound catalyzed phenol-resorcinol-formaldehyde(PRF) adhesive, and the prepared recombinant bamboo with three kinds of adhesives were compared. The experimental results show that NaOH and Ba(OH)_2 compound catalyst not only shortens the curing time of PF adhesive, but also guarantees the suitable water solubility of adhesive. After copolycondensation with resorcinol, the curing time of adhesive is further shortened, the water solubility is improved obviously, and the highest bonding strength is obtained. Infrared spectrum analysis shows that the reaction activity point of NaOH and Ba(OH)_2 compound catalyzed PRF adhesive will increase, so that both the curing temperature and curing enthalpy decrease.
文摘设计了一种具有辅助电加热和均流孔板的水/相变材料复合蓄热式水箱,该水箱以封装有复合八水氢氧化钡的相变蓄热球作为储热单元。理论分析了相变蓄热球应用于复合蓄热式水箱中的可行性,实验研究了水箱中有无相变蓄热球、恒定流量下的直接和恒温蓄放热特性,结果表明:均流孔板的应用,可使冷热水在水箱底部均匀混合,使高温热水出水量达到最大;在热水出水流量为3.3 L/min时,添加60个相变蓄热球的复合蓄热式水箱比纯水箱可多制得10 L 60℃以上的热水;在热水出水流量为1.6 L/min时,添加120个相变蓄热球的复合蓄热式水箱比纯水箱可多制得40 L 40℃的恒温热水。
