Microbiologically influenced corrosion (MIC) is a major cause of corrosion damages, facility failures, and financial losses, making MIC an important research topic. Due to complex microbiological activities and a la...Microbiologically influenced corrosion (MIC) is a major cause of corrosion damages, facility failures, and financial losses, making MIC an important research topic. Due to complex microbiological activities and a lack of deep understanding of the interactions between biofilms and metal surfaces, MIC occurrences and mechanisms are difficult to predict and interpret. Many theories and mechanisms have been pro- posed to explain MIC. In this review, the mechanisms of MIC are discussed using hioenergetics, microbial respiration types, and biofilm extracellular electron transfer (EET). Two main MIC types, namely EET-MIC and metabolite MIC (M-ME), are discussed. This brief review provides a state of the art insight into MIC mechanisms and it helps the diagnosis and prediction of occurrences of MIC under anaerobic conditions in the oil and gas industry.展开更多
Multi-walled carbon nanotubes (MWCNTs) were coated with ZnO by a hydrothermal method. The resulting nanocomposites were mixed with the Nation solution to form a composite matrix for the fabrication of hemoglobin (H...Multi-walled carbon nanotubes (MWCNTs) were coated with ZnO by a hydrothermal method. The resulting nanocomposites were mixed with the Nation solution to form a composite matrix for the fabrication of hemoglobin (Hb) biosensor. To prevent the leak of Hb molecules of the biosensor, silica sol-gel film was coated on the surface of the Hb/ZnO-MWCNTs/Nafion electrode. The silica sol-gel/Hb/ZnO-MWCNTs/Nafion film exhibited a pair of well-defined, quasi-reversible redox peaks. This biosensor showed excellent electrocataiytic activity to H2O2. The sensitivity and apparent Michaelis-Menten constant of this Hb biosensor to H2O2 were 1.31 A/(M cm^2) and 82.8 μmol/L, respectively, which indicated that Hb had high affinity to H2O2.展开更多
Carbon fibers(CFs)demonstrate a range of excellent properties including(but not limited to)microscale diameter,high hardness,high strength,light weight,high chemical resistance,and high temperature resistance.Therefor...Carbon fibers(CFs)demonstrate a range of excellent properties including(but not limited to)microscale diameter,high hardness,high strength,light weight,high chemical resistance,and high temperature resistance.Therefore,it is necessary to summarize the application market of CFs.CFs with good physical and chemical properties stand out among many materials.It is believed that highly fibrotic CFs will play a crucial role.This review first introduces the precursors of CFs,such as polyacrylonitrile,bitumen,and lignin.Then this review introduces CFs used in BESs,such as electrode materials and modification strategies of MFC,MEC,MDC,and other cells in a large space.Then,CFs in biosensors including enzyme sensor,DNA sensor,immune sensor and implantable sensor are summarized.Finally,we discuss briefly the challenges and research directions of CFs application in BESs,biosensors and more fields.展开更多
基金supported by Science Foundation of China University of Petroleum,Beijing(Nos.2462017YJRC038 and 2462018BJC005)supported by the National Natural Science Foundation of China(Grant U1660118)+1 种基金the National Basic Research Program of China(973 Program,No.2014CB643300)the National Environmental Corrosion Platform(NECP)
文摘Microbiologically influenced corrosion (MIC) is a major cause of corrosion damages, facility failures, and financial losses, making MIC an important research topic. Due to complex microbiological activities and a lack of deep understanding of the interactions between biofilms and metal surfaces, MIC occurrences and mechanisms are difficult to predict and interpret. Many theories and mechanisms have been pro- posed to explain MIC. In this review, the mechanisms of MIC are discussed using hioenergetics, microbial respiration types, and biofilm extracellular electron transfer (EET). Two main MIC types, namely EET-MIC and metabolite MIC (M-ME), are discussed. This brief review provides a state of the art insight into MIC mechanisms and it helps the diagnosis and prediction of occurrences of MIC under anaerobic conditions in the oil and gas industry.
文摘Multi-walled carbon nanotubes (MWCNTs) were coated with ZnO by a hydrothermal method. The resulting nanocomposites were mixed with the Nation solution to form a composite matrix for the fabrication of hemoglobin (Hb) biosensor. To prevent the leak of Hb molecules of the biosensor, silica sol-gel film was coated on the surface of the Hb/ZnO-MWCNTs/Nafion electrode. The silica sol-gel/Hb/ZnO-MWCNTs/Nafion film exhibited a pair of well-defined, quasi-reversible redox peaks. This biosensor showed excellent electrocataiytic activity to H2O2. The sensitivity and apparent Michaelis-Menten constant of this Hb biosensor to H2O2 were 1.31 A/(M cm^2) and 82.8 μmol/L, respectively, which indicated that Hb had high affinity to H2O2.
基金supported by the National Key R&D Program of China(2019YFC1804102)the National Natural Science Foundation of China(32171615,41877372).
文摘Carbon fibers(CFs)demonstrate a range of excellent properties including(but not limited to)microscale diameter,high hardness,high strength,light weight,high chemical resistance,and high temperature resistance.Therefore,it is necessary to summarize the application market of CFs.CFs with good physical and chemical properties stand out among many materials.It is believed that highly fibrotic CFs will play a crucial role.This review first introduces the precursors of CFs,such as polyacrylonitrile,bitumen,and lignin.Then this review introduces CFs used in BESs,such as electrode materials and modification strategies of MFC,MEC,MDC,and other cells in a large space.Then,CFs in biosensors including enzyme sensor,DNA sensor,immune sensor and implantable sensor are summarized.Finally,we discuss briefly the challenges and research directions of CFs application in BESs,biosensors and more fields.