为了分析和评估500 k V交联聚乙烯(XLPE)电力电缆线路的绝缘状况并开展电缆绝缘诊断,基于超高压电力电缆的局部放电机理和局部放电信号衰减特性,首次提出了应用分布式局部放电监测技术进行500 k V电力电缆在线监测的新模式。实践中发现...为了分析和评估500 k V交联聚乙烯(XLPE)电力电缆线路的绝缘状况并开展电缆绝缘诊断,基于超高压电力电缆的局部放电机理和局部放电信号衰减特性,首次提出了应用分布式局部放电监测技术进行500 k V电力电缆在线监测的新模式。实践中发现有3种现场局部放电提取信号方式可以满足500 k V电力电缆在线监测的实际需要。通过采用分布式时频分析技术,有效地解决了500 k V电力电缆绝缘缺陷的识别问题,提高了绝缘缺陷定位的精度。应用局部放电图谱库大数据分析技术及3图谱局部放电识别法,首次成功实现了500 k V电力电缆的绝缘诊断。开发了局部放电信号智能式进阶报警策略,提高了局部放电报警的可靠性。研究成果在国内首条长距离敷设的500 k V交联聚乙烯(XLPE)电力电缆线路上得到了成功应用。研究认为综合应用分布式时频分析、3图谱局部放电识别法和智能式进阶报警策略等分布式局部放电在线监测新技术,可以实现500 k V电力电缆绝缘缺陷的识别、定位和诊断;将对国内后续500 k V电力电缆开展局部放电监测和缺陷识别具有积极的指导意义。展开更多
Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobili...Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.展开更多
文摘为了分析和评估500 k V交联聚乙烯(XLPE)电力电缆线路的绝缘状况并开展电缆绝缘诊断,基于超高压电力电缆的局部放电机理和局部放电信号衰减特性,首次提出了应用分布式局部放电监测技术进行500 k V电力电缆在线监测的新模式。实践中发现有3种现场局部放电提取信号方式可以满足500 k V电力电缆在线监测的实际需要。通过采用分布式时频分析技术,有效地解决了500 k V电力电缆绝缘缺陷的识别问题,提高了绝缘缺陷定位的精度。应用局部放电图谱库大数据分析技术及3图谱局部放电识别法,首次成功实现了500 k V电力电缆的绝缘诊断。开发了局部放电信号智能式进阶报警策略,提高了局部放电报警的可靠性。研究成果在国内首条长距离敷设的500 k V交联聚乙烯(XLPE)电力电缆线路上得到了成功应用。研究认为综合应用分布式时频分析、3图谱局部放电识别法和智能式进阶报警策略等分布式局部放电在线监测新技术,可以实现500 k V电力电缆绝缘缺陷的识别、定位和诊断;将对国内后续500 k V电力电缆开展局部放电监测和缺陷识别具有积极的指导意义。
基金supported by the Nature Science Foundation of Heilongjiang Province (No. B201410)the Postdoctoral Foundation Project of Heilongjiang Province (No. LBH-Z13128)+3 种基金the Science and Technology Research Program of Education Bureau of Heilongjiang Province (No. 12531206)the Special Scientific Research Projects of Harbin Normal University (12XQXG02)the National Nature Science Foundation of China (No. 41030743)the National Nature Science Foundation of China (No. 42171217)
文摘Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.
