A new effecient catalyst system(FeCl 3/2PPh 3) for the “living”/controlled radical polymerization of butyl methacrylate by a reverse ATRP process was reported in this paper.With the presence of this catalyst system,...A new effecient catalyst system(FeCl 3/2PPh 3) for the “living”/controlled radical polymerization of butyl methacrylate by a reverse ATRP process was reported in this paper.With the presence of this catalyst system,the number average molecular weights of the obtained polymer increased in direct proportion with monomer conversion,and the MWDs (molecular weight disctributions) were narrow throughout the reactions(1 17< w/ n<1 22).This reaction system did not include the conventional initiators which were used to generate the primary radicals.展开更多
文摘A new effecient catalyst system(FeCl 3/2PPh 3) for the “living”/controlled radical polymerization of butyl methacrylate by a reverse ATRP process was reported in this paper.With the presence of this catalyst system,the number average molecular weights of the obtained polymer increased in direct proportion with monomer conversion,and the MWDs (molecular weight disctributions) were narrow throughout the reactions(1 17< w/ n<1 22).This reaction system did not include the conventional initiators which were used to generate the primary radicals.
文摘以α 溴代丙酸乙酯为小分子引发剂、氯化亚铜和联二吡啶组成的混合体系为催化剂,引发苯乙烯单体聚合,得到端基为卤原子的单分散PS X预聚体。并以此为大分子引发剂、氯化亚铜和N,N,N′,N″,N 五甲基二亚乙基三胺/联二吡啶组成的混合体系为催化剂,引发聚合甲基丙烯酸叔丁酯,得到相对分子质量可控、分子质量分布狭窄的聚苯乙烯 b 聚甲基丙烯酸叔丁酯嵌段共聚物.最后使该共聚物在酸性条件下水解,从而得到了两亲性的嵌段共聚物聚苯乙烯 b 聚甲基丙烯酸.用红外光谱仪、核磁共振仪、凝胶色谱仪等对产物的结构与性能进行了表征.
