In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with...In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with Nafion material to prepare a new type of membrane for DMFC and its ionic conductivity and the methanol permeability was investigated.PVDF was used here to regulate the ratio between hydrophilic group and the hydrophobic group exist in the blend membranes according to the hydrophilic hydrophobic balance theory proposed in pervaporation.The adding of PVDF lead to a great improvement of the membrane’s MeOH rejection.When PVDF content was increased from 25% to 75%,the MeOH permeability was reduced from～10 -7 to ～10 -9 cm 2/s,1 to 3 orders of magnitude lower than that of Nafion117.The membrane conductivity decreased,although remaining at high value(～10 -4 S/cm),with the increase of PVDF content.Compared with the Nafion117 membrane,the PVDF Nafion blend membrane with only 25% of Nafion showed an improvement in performance by about 40 times,if the ratio( σ/P ) was adopted to characterize the performance of a membrane for DMFC.Percolation theory,cocontinuous morphology features and phase transition model were applied to explain the behavior of membrane conduction.展开更多
A copolymer of poly（acrylonitrile-co-styrene） （SAN） was synthesized via an emulsion polymerization method. Novel polymer electrolyte membranes cast from the blends of poly（vinylidene fluoride-co-hexafluoropropyl...A copolymer of poly（acrylonitrile-co-styrene） （SAN） was synthesized via an emulsion polymerization method. Novel polymer electrolyte membranes cast from the blends of poly（vinylidene fluoride-co-hexafluoropropylene） （PVDF- HFP）, SAN and fumed silica （SIO2） are microporous and can be used in polymer lithium-ion batteries. The membrane shows excellent characteristics such as high ionic conductivity and good mechanical strength when the mass ratio between SAN and PVDF-HFP and SiO2 is 3.5/31.5/5. The ionic conductivity of the membrane soaked in a liquid electrolyte of 1 mol/L LiPF6/EC/DMC/DEC is 4.9 × 10^-3 S cm^-1 at 25℃. The membrane is electrochemical stable up to 5.5 V versus Li^＋/Li in the liquid electrolyte. The influences of SiO2 content on the porosity and mechanical strength of the membranes were studied. Polymer lithium-ion batteries based on the membranes were assembled and their performances were also studied.展开更多
文摘In order to solve the methanol crossover problem caused by the poor alcohol rejecting ability of the Nafion TM membranes currently used in direct methanol fuel cell (DMFC),polyvinylidene fluoride(PVDF)was blended with Nafion material to prepare a new type of membrane for DMFC and its ionic conductivity and the methanol permeability was investigated.PVDF was used here to regulate the ratio between hydrophilic group and the hydrophobic group exist in the blend membranes according to the hydrophilic hydrophobic balance theory proposed in pervaporation.The adding of PVDF lead to a great improvement of the membrane’s MeOH rejection.When PVDF content was increased from 25% to 75%,the MeOH permeability was reduced from～10 -7 to ～10 -9 cm 2/s,1 to 3 orders of magnitude lower than that of Nafion117.The membrane conductivity decreased,although remaining at high value(～10 -4 S/cm),with the increase of PVDF content.Compared with the Nafion117 membrane,the PVDF Nafion blend membrane with only 25% of Nafion showed an improvement in performance by about 40 times,if the ratio( σ/P ) was adopted to characterize the performance of a membrane for DMFC.Percolation theory,cocontinuous morphology features and phase transition model were applied to explain the behavior of membrane conduction.
文摘A copolymer of poly（acrylonitrile-co-styrene） （SAN） was synthesized via an emulsion polymerization method. Novel polymer electrolyte membranes cast from the blends of poly（vinylidene fluoride-co-hexafluoropropylene） （PVDF- HFP）, SAN and fumed silica （SIO2） are microporous and can be used in polymer lithium-ion batteries. The membrane shows excellent characteristics such as high ionic conductivity and good mechanical strength when the mass ratio between SAN and PVDF-HFP and SiO2 is 3.5/31.5/5. The ionic conductivity of the membrane soaked in a liquid electrolyte of 1 mol/L LiPF6/EC/DMC/DEC is 4.9 × 10^-3 S cm^-1 at 25℃. The membrane is electrochemical stable up to 5.5 V versus Li^＋/Li in the liquid electrolyte. The influences of SiO2 content on the porosity and mechanical strength of the membranes were studied. Polymer lithium-ion batteries based on the membranes were assembled and their performances were also studied.
