A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectro...A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectroscopy. Compared with the polymer electrolyte without Al 2O 3 particles, the glass transition temperature and the degree of crystallinity were decreased, and the room temperature conductivity of PEO LiClO 4 Al 2O 3 composite polymer electrolyte was considerably enhanced. Moreover, the equivalent circuits and the effect of dc potential on impedance spectroscopy were discussed.展开更多
An environment friendly chemical conversion coating for magnesium was obtained by using a phytic acid solution. The effect of post-coating 1heat treatment on the microstructures and corrosion properties of phytic acid...An environment friendly chemical conversion coating for magnesium was obtained by using a phytic acid solution. The effect of post-coating 1heat treatment on the microstructures and corrosion properties of phytic acid conversion coated magnesium was investigated. It was observed that the microstructure and corrosion resistive properties were improved for the heat treated samples. The corrosion current density for bare magnesium, phytic acid conversion coated magnesium, and post-coating heat treated magnesium was calculated to be 2.48 ×10^-5, 1.18×10^-6, and 9.27 × 10^7 A/cm^2, respectively. The lowest corrosion current density for the heat treated sample indicated its highest corrosion resistive effect for the magnesium. The maximum corrosion protective nature of the heat treated sample was further confirmed by the largest value of impedance in electrochemical impedance spectroscopy studies.展开更多
文摘A composite polymer electrolyte of Polyethylene oxide (PEO) LiClO 4 containing fine Al 2O 3 particles was studied by using differential scanning calorimetry, infrared spectroscopy and electrochemical impedance spectroscopy. Compared with the polymer electrolyte without Al 2O 3 particles, the glass transition temperature and the degree of crystallinity were decreased, and the room temperature conductivity of PEO LiClO 4 Al 2O 3 composite polymer electrolyte was considerably enhanced. Moreover, the equivalent circuits and the effect of dc potential on impedance spectroscopy were discussed.
基金supported by the National Science Foundation through ERC-RMB at NCAT
文摘An environment friendly chemical conversion coating for magnesium was obtained by using a phytic acid solution. The effect of post-coating 1heat treatment on the microstructures and corrosion properties of phytic acid conversion coated magnesium was investigated. It was observed that the microstructure and corrosion resistive properties were improved for the heat treated samples. The corrosion current density for bare magnesium, phytic acid conversion coated magnesium, and post-coating heat treated magnesium was calculated to be 2.48 ×10^-5, 1.18×10^-6, and 9.27 × 10^7 A/cm^2, respectively. The lowest corrosion current density for the heat treated sample indicated its highest corrosion resistive effect for the magnesium. The maximum corrosion protective nature of the heat treated sample was further confirmed by the largest value of impedance in electrochemical impedance spectroscopy studies.
