被动桩对侧向位移的土层起到遮拦作用的机制主要是土拱效应。采用土工有限元软件Plaxis Tunnel 3D 1.2,对堆载荷载作用下邻近桩基中的土拱效应产生机制和性状进行三维数值分析,指出目前被动桩中土拱效应二维有限元分析存在的问题。考虑...被动桩对侧向位移的土层起到遮拦作用的机制主要是土拱效应。采用土工有限元软件Plaxis Tunnel 3D 1.2,对堆载荷载作用下邻近桩基中的土拱效应产生机制和性状进行三维数值分析,指出目前被动桩中土拱效应二维有限元分析存在的问题。考虑桩土侧移与相对位移,再利用土工有限元软件Plaxis2D 8.2详细地研究了侧向土体位移大小、桩身水平位移大小、土体性质以及桩土接触面性质等影响因素对土拱效应性态和桩土荷载分担比的影响。展开更多
Palladium-exchanged chabazite(Pd-CHA) zeolites as passive NO_x adsorbers(PNAs) enable efficient purification of nitrogen oxides(NO_x) in cold-start diesel exhausts. Their commercial application, however,is limited by ...Palladium-exchanged chabazite(Pd-CHA) zeolites as passive NO_x adsorbers(PNAs) enable efficient purification of nitrogen oxides(NO_x) in cold-start diesel exhausts. Their commercial application, however,is limited by the lack of facile preparation method. Here, high-performance CHA-type Pd-SAPO-34 zeolite was synthesized by a modified solid-state ion exchange(SSIE) method using PdO as Pd precursor,and demonstrated superior PNA performance as compared to Pd-SAPO-34 prepared by conventional wetchemistry strategies. Structural characterization using Raman spectroscopy and X-ray diffraction revealed that the SSIE method avoided water-induced damage to the zeolite framework during Pd loading. Mechanistic investigations on the SSIE process by in situ infrared spectroscopy and X-ray photoelectron spectroscopy disclosed that, while PdO precursor was mainly converted to Pd^(2+) cations coordinated to the zeolite framework by consuming the-OH groups of the zeolite, a portion of PdO could also undergo thermal decomposition to form highly dispersed Pd~0 clusters in the pore channels. This simplified and scalable SSIE method paves a new way for the cost-effective synthesis of defect-free high-performance Pd-SAPO-34 zeolites as PNA catalysts.展开更多
文摘被动桩对侧向位移的土层起到遮拦作用的机制主要是土拱效应。采用土工有限元软件Plaxis Tunnel 3D 1.2,对堆载荷载作用下邻近桩基中的土拱效应产生机制和性状进行三维数值分析,指出目前被动桩中土拱效应二维有限元分析存在的问题。考虑桩土侧移与相对位移,再利用土工有限元软件Plaxis2D 8.2详细地研究了侧向土体位移大小、桩身水平位移大小、土体性质以及桩土接触面性质等影响因素对土拱效应性态和桩土荷载分担比的影响。
基金supported by the National Natural Science Foundation of China (No.21976058)the Natural Science Foundation of Guangdong Province (No.2023A1515011682)+3 种基金the Fundamental Research Funds for the Central Universities (No.2022ZYGXZR018)the National Engineering Laboratory for Mobile Source Emission Control Technology (No.NELMS2020A10)the funding from the Pearl River Talent Recruitment Program of Guangdong Province (No.2019QN01L170)the Innovation & Entrepreneurship Talent Program of Shaoguan City。
文摘Palladium-exchanged chabazite(Pd-CHA) zeolites as passive NO_x adsorbers(PNAs) enable efficient purification of nitrogen oxides(NO_x) in cold-start diesel exhausts. Their commercial application, however,is limited by the lack of facile preparation method. Here, high-performance CHA-type Pd-SAPO-34 zeolite was synthesized by a modified solid-state ion exchange(SSIE) method using PdO as Pd precursor,and demonstrated superior PNA performance as compared to Pd-SAPO-34 prepared by conventional wetchemistry strategies. Structural characterization using Raman spectroscopy and X-ray diffraction revealed that the SSIE method avoided water-induced damage to the zeolite framework during Pd loading. Mechanistic investigations on the SSIE process by in situ infrared spectroscopy and X-ray photoelectron spectroscopy disclosed that, while PdO precursor was mainly converted to Pd^(2+) cations coordinated to the zeolite framework by consuming the-OH groups of the zeolite, a portion of PdO could also undergo thermal decomposition to form highly dispersed Pd~0 clusters in the pore channels. This simplified and scalable SSIE method paves a new way for the cost-effective synthesis of defect-free high-performance Pd-SAPO-34 zeolites as PNA catalysts.
