The effects of the introduction of silica glass and silica ceramic into Ca-Al-B-Si-O glass/ Al2O3 composites on decreasing the shrinkage and the dielectric constant of samples were investigated by FTIR, DSC, XRD and S...The effects of the introduction of silica glass and silica ceramic into Ca-Al-B-Si-O glass/ Al2O3 composites on decreasing the shrinkage and the dielectric constant of samples were investigated by FTIR, DSC, XRD and SEM. The results show that silica ceramic filler can better improve the formation of Si- O-Si network in the composites under high temperature, which leads to increased continuity of glass network at high temperature, and deduces the increase of viscosity of composites and further results in the decrease in the shrinkage of samples. Densification, three-point strength, and dielectric constant of samples decrease with the increase of silica glass or silica ceramic content. By contrast, Ca-Al-B-Si-O glass/Al2O3 composites with 4 wt% silica ceramic exhibit better properties of a bulk density of 2.81 g.cm-3, a porosity of 0.3%, a 3dp value of 202 MPa, a er value of 7.41 , a tan d value of 8.3 ×10^-4 at 10 MHz and a well matching with Ag electrodes. This material is suitable to be used as the LTCC material for the application in wireless communications.展开更多
基金Supported by the National High Technology Research and Development Program("863"Program)of China(No.2007AA03Z0455)the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institution,Changjiang Scholars and Innovative Research Team in University(PCSIRT)(No.IRT1146)
文摘The effects of the introduction of silica glass and silica ceramic into Ca-Al-B-Si-O glass/ Al2O3 composites on decreasing the shrinkage and the dielectric constant of samples were investigated by FTIR, DSC, XRD and SEM. The results show that silica ceramic filler can better improve the formation of Si- O-Si network in the composites under high temperature, which leads to increased continuity of glass network at high temperature, and deduces the increase of viscosity of composites and further results in the decrease in the shrinkage of samples. Densification, three-point strength, and dielectric constant of samples decrease with the increase of silica glass or silica ceramic content. By contrast, Ca-Al-B-Si-O glass/Al2O3 composites with 4 wt% silica ceramic exhibit better properties of a bulk density of 2.81 g.cm-3, a porosity of 0.3%, a 3dp value of 202 MPa, a er value of 7.41 , a tan d value of 8.3 ×10^-4 at 10 MHz and a well matching with Ag electrodes. This material is suitable to be used as the LTCC material for the application in wireless communications.
