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铋系化合物改性的新型三元弛豫铁电体的性能研究
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作者 黄江峰 王涛 +4 位作者 王凤华 何志兴 陈哲 黄音博 吴文娟 《人工晶体学报》 CAS 北大核心 2022年第3期411-418,共8页
钛酸钡(BaTiO_(3))陶瓷作为传统的介质电容器材料,其强铁电性会导致储能密度低下,但通过掺杂可以削弱铁电性来获得弛豫铁电体,提高储能性能。利用铋系化合物可增强弛豫特性,本文设计了BiScO_(3)和(Sr_(0.7)Bi_(0.2))TiO_(3)取代改性的Ba... 钛酸钡(BaTiO_(3))陶瓷作为传统的介质电容器材料,其强铁电性会导致储能密度低下,但通过掺杂可以削弱铁电性来获得弛豫铁电体,提高储能性能。利用铋系化合物可增强弛豫特性,本文设计了BiScO_(3)和(Sr_(0.7)Bi_(0.2))TiO_(3)取代改性的BaTiO_(3)基三元陶瓷材料:(0.99-x)Ba(Zr_(0.1)Ti_(0.9))O_(3)-x(Sr_(0.7)Bi_(0.2))TiO_(3)-0.01BiScO_(3)(缩写为BZT-xSBT-BS)。采用传统固相法制备的BZT-xSBT-BS陶瓷,相结构没有因为掺杂发生改变,在室温下均为纯的三方相钙钛矿结构。介电和铁电的测试与分析表明,BZT-xSBT-BS陶瓷具有典型的弛豫铁电特性。由于不等价离子Sr^(2+)、Bi^(3+)的掺杂导致界面松弛极化,可以增大BZT-xSBT-BS陶瓷的介电常数,但是受制于其慢的响应速度,陶瓷的介电损耗也显著增加。适量(Sr_(0.7)Bi_(0.2))TiO_(3)可以提升BZT-xSBT-BS陶瓷的介电、铁电、应变和储能性能,x=0.015时的BZT-xSBT-BS陶瓷的综合性能较优:ε_(r)~10372,tanδ~0.019,P_(max)=16.42μC/cm^(2),E_(c)=1.41 kV/cm,S^(+)_(max)=0.12%(@40 kV/cm),W_(D)=0.181 J/cm^(3),η=80.4%(@60 kV/cm)。 展开更多
关键词 Batio_(3)基陶瓷 (sr_(0.7)bi_(0.2))tio_(3) 固相法 弛豫铁电体 介质电容器 介电性能 铁电性能 储能
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Structure,dielectric and relaxor properties of Sr_(0.7)Bi_(0.2)TiO_(3)—K_(0.5)Bi_(0.5)TiO_(3)lead-free ceramics for energy storage applications 被引量:1
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作者 Peng Zhao Bin Tang +4 位作者 Zixuan Fang Feng Si Chengtao Yang Gang Liu Shuren Zhang 《Journal of Materiomics》 SCIE EI 2021年第1期195-207,共13页
Sr_(0.7)Bi_(0.2)TiO_(3)(SBT)by increasing the proportion and size of polar nano-region.Meanwhile,the BDS remains a high level with x<0.38 attributed to the addition of KBT with a large band gap.As a result,the 0.62... Sr_(0.7)Bi_(0.2)TiO_(3)(SBT)by increasing the proportion and size of polar nano-region.Meanwhile,the BDS remains a high level with x<0.38 attributed to the addition of KBT with a large band gap.As a result,the 0.62SBT-0.38KBT exhibits a high energy storage density of 2.21 J/cm^(3)with high h of 91.4%at 220 kV/cm and superior temperature stability(-55~150℃),frequency stability(10~500 Hz)and fatigue resistance(105 cycles).Moreover,high pulsed discharge energy density(1.81 J/cm^(3)),high power density(49.5 MW/cm3)and great thermal stability(20~160℃)are achieved in 0.62SBT-0.38KBT.Based on these excellent properties,the 0.62SBT-0.38KBT are suitable for pulsed power systems.This work provides a novel strategy and systematic study for improving energy storage properties of SBT. 展开更多
关键词 Energy storage (sr_(0.7)bi_(0.2))tio_(3) K_(0.5)bi_(0.5)tio_(3) LEAD-FREE Relaxor ferroelectrics Maximum polarization
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